![Organic Chemistry](https://www.bartleby.com/isbn_cover_images/9781119316152/9781119316152_largeCoverImage.jpg)
(a)
Interpretation:
The target molecule should be drawn for the given statements by using its molecular structure.
Concept introduction:
The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of
For
For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol’
Root word represents the longest continuous carbon skeleton of the organic molecule.
Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.
To identify: The systematic structure for the given molecule
(b)
Interpretation:
The target molecule should be drawn for the given statements by using its molecular structure.
Concept introduction:
The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.
IUPAC Nomenclature Method
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...
For alkynes molecules, suffix will be ‘yne’.
For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol’
Root word represents the longest continuous carbon skeleton of the organic molecule.
Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.
To identify: The systematic structure for the given molecule
(c)
Interpretation:
The target molecule should be drawn for the given statements by using its molecular structure.
Concept introduction:
The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.
IUPAC Nomenclature Method
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...
For alkynes molecules, suffix will be ‘yne’.
For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol’
Root word represents the longest continuous carbon skeleton of the organic molecule.
Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.
To identify: The systematic structure for the given molecule
(d)
Interpretation:
The target molecule should be drawn for the given statements by using its molecular structure.
Concept introduction:
The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.
IUPAC Nomenclature Method
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...
For alkynes molecules, suffix will be ‘yne’.
For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol’
Root word represents the longest continuous carbon skeleton of the organic molecule.
Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.
To identify: The systematic structure for the given molecule
(e)
Interpretation:
The target molecule should be drawn for the given statements by using its molecular structure.
Concept introduction:
The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.
IUPAC Nomenclature Method
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...
For alkynes molecules, suffix will be ‘yne’.
For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol’
Root word represents the longest continuous carbon skeleton of the organic molecule.
Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.
To identify: The systematic structure for the given molecule
(f)
Interpretation:
The target molecule should be drawn for the given statements by using its molecular structure.
Concept introduction:
The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.
IUPAC Nomenclature Method
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...
For alkynes molecules, suffix will be ‘yne’.
For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol’
Root word represents the longest continuous carbon skeleton of the organic molecule.
Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.
To identify: The systematic structure for the given molecule
(g)
Interpretation:
The target molecule should be drawn for the given statements by using its molecular structure.
Concept introduction:
The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.
IUPAC Nomenclature Method
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...
For alkynes molecules, suffix will be ‘yne’.
For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol’
Root word represents the longest continuous carbon skeleton of the organic molecule.
Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.
To identify: The systematic structure for the given molecule
(h)
Interpretation:
The target molecule should be drawn for the given statements by using its molecular structure.
Concept introduction:
The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.
IUPAC Nomenclature Method
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...
For alkynes molecules, suffix will be ‘yne’.
For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol’
Root word represents the longest continuous carbon skeleton of the organic molecule.
Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.
To identify: The systematic structure for the given molecule
(i)
Interpretation:
The target molecule should be drawn for the given statements by using its molecular structure.
Concept introduction:
The structure the carbon atoms and the hydrogen atoms which are attached to that carbon atom are not to show, rather the bonds in between carbon atoms and to the hetero atoms are drawn as line segments. For acyclic, linear carbon chains it draws as in a zig-zag fashion and for cyclic chains of carbon it draws as a cyclic polygon. For representing a heteroatom attached to the carbon, use a line segment and label the heteroatom at the end of their line segment.
IUPAC Nomenclature Method
Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry). IUPAC name consists of three parts in major namely Prefix suffix and root word.
Prefix represents the substituent present in the molecule and its position in the root name.
Suffix denotes the presence of functional group if any in the molecule. It can be an alkane, alkene, alkyne, alcohol, aldehyde, carboxylic acid etc...
For alkynes molecules, suffix will be ‘yne’.
For example alkane molecule, suffix will be ‘ane’, compound presence of carbonyl group ‘one’ and presence of alcohol group suffix will be ‘ol’
Root word represents the longest continuous carbon skeleton of the organic molecule.
Two stereoisomers are there for an saturated alkane molecule. It depends upon the location of bulky group (or high molecular weight) on the triple bonded carbon atoms. If the bulky groups are in same side then it is cis-isomer. If the bulky groups are in opposite side then it is trans-isomer.
To identify: The systematic structure for the given molecule
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Chapter 19 Solutions
Organic Chemistry
- Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. + CI Br : Н OH H wo་ཡིག་ཐrow HO 3 D ။။ဂ CI Br H, CI Br Br H₂N OMe R IN I I N S H Br ជ័យ CI CI D OHarrow_forwardPlease correct answer and don't use hand ratingarrow_forwardNonearrow_forward
- %Reflectance 95 90- 85 22 00 89 60 55 50 70 65 75 80 50- 45 40 WA 35 30- 25 20- 4000 3500 Date: Thu Feb 06 17:21:21 2025 (GMT-05:0(UnknownD Scans: 8 Resolution: 2.000 3000 2500 Wavenumbers (cm-1) 100- 2981.77 1734.25 2000 1500 1000 1372.09 1108.01 2359.09 1469.82 1181.94 1145.20 1017.01 958.45 886.97 820.49 668.25 630.05 611.37arrow_forwardNonearrow_forwardCH3 CH H3C CH3 H OH H3C- -OCH2CH3 H3C H -OCH3 For each of the above compounds, do the following: 1. List the wave numbers of all the IR bands in the 1350-4000 cm-1 region. For each one, state what bond or group it represents. 2. Label equivalent sets of protons with lower-case letters. Then, for each 1H NMR signal, give the 8 value, the type of splitting (singlet, doublet etc.), and the number protons it represents. of letter δ value splitting # of protons 3. Redraw the compound and label equivalent sets of carbons with lower-case letters. Then for each set of carbons give the 5 value and # of carbons it represents. letter δ value # of carbonsarrow_forward
- Nonearrow_forwardCarbohydrates- Draw out the Hawthorne structure for a sugar from the list given in class. Make sure to write out all atoms except for carbons within the ring. Make sure that groups off the carbons in the ring are in the correct orientation above or below the plane. Make sure that bonds are in the correct orientation. Include the full name of the sugar. You can draw out your curve within the text box or upload a drawing below.arrow_forwardHow many milliliters of 97.5(±0.5) wt% H2SO4 with a density of 1.84(±0.01) g/mL will you need to prepare 2.000 L of 0.110 M H2SO4? If the uncertainty in delivering H2SO4 is ±0.01 mL, calculate the absolute uncertainty in the molarity (0.110 M). Assume there is negligible uncertainty in the formula mass of H2SO4 and in the final volume (2.000 L) and assume random error.arrow_forward
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