Reactants required to prepare the given enamine has to be identified. Concept introduction: Enamine reaction: Carbonyl compound ( ketone or aldehyde ) reaction with secondary amine in the presence of acid which gives enamine . An enamine is a compound where the lone pair of electrons in the nitrogen atom of C − N bond gets delocalized by the presence of nearby C = C bond. It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule. Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Question

Want to see the full answer?

Answer 1

Question

Chapter 19, Problem 60PP

(a)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(b)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(c)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Determine if the following salt is neutral, acidic or basic. If acidic or basic, write the appropriate equilibrium equation for the acid or base that exists when the salt is dissolved in aqueous solution. If neutral, simply write only NR. Be sure to include the proper phases for all species within the reaction. NaN₃

Can I please get help with this?

Answer 2

Question

Chapter 19, Problem 60PP

(a)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(b)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(c)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 19, Problem 60PP

(a)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(b)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(c)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 19, Problem 60PP

(a)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(b)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(c)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 19, Problem 60PP

(a)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(b)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

(c)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Answer 6

Chapter 19, Problem 60PP

(a)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Answer 7

Chapter 19, Problem 60PP

(a)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Answer 8

(b)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Answer 9

(b)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Answer 10

(c)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Answer 11

(c)

Interpretation Introduction

Interpretation: Reactants required to prepare the given enamine has to be identified.

Concept introduction:

Enamine reaction:

Carbonyl compound (ketone or aldehyde) reaction with secondary amine in the presence of acid which gives enamine.

An enamine is a compound where the lone pair of electrons in the nitrogen atom of C−N bond gets delocalized by the presence of nearby C=C bond.

It is formed by the reaction of a ketone or aldehyde and a secondary amine under acidic conditions with the elimination of water molecule.

Retro synthesis: It is a technique of planning an organic synthesis by the reverse approach. In this technique, the starting materials are obtained by cleaving the target molecule into logical synthons. Synthons are precursor fragments of the target compound when it is cleaved. Depending on the stability, the synthons are classified as logical and illogical synthons. Logical synthons are highly stable precursor fragments, and illogical synthons are less stable precursor fragments of the target compound.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 19.2 - Prob. 1LTS Ch. 19.2 - Prob. 1PTS Ch. 19.2 - Prob. 2PTS Ch. 19.2 - APPLY the skill Compounds with two ketone groups...Ch. 19.2 - Prob. 4ATS Ch. 19.3 - Prob. 5CC Ch. 19.4 - Prob. 6CC Ch. 19.5 - Prob. 7CC Ch. 19.5 - Prob. 2LTS Ch. 19.5 - Prob. 8PTS

Concept explainers

Want to see the full answer?

Chapter 19 Solutions