
Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
4th Edition
ISBN: 9780134162430
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 19, Problem 4SAQ
Interpretation Introduction
Interpretation: Amongst the given statements, the true statement regarding the given voltaic cell is to be identified.
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LTS
Solid:
AT=Te-Ti
Trial 1
Trial 2
Trial 3
Average
ΔΗ
Mass water, g
24.096
23.976
23.975
Moles of solid, mol
0.01763
001767
0101781
Temp. change, °C
2.9°C
11700
2.0°C
Heat of reaction, J
-292.37J -170.473
-193.26J
AH, kJ/mole
16.58K 9.647 kJ 10.85 kr
16.58K59.64701
KJ
mol
12.35k
Minimum AS,
J/mol K
41.582
mol-k
Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn &
Show your calculations for:
AH in J and then in kJ/mole for Trial 1:
qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J
qsin =
qrxn =
292.35 292.37J
AH in J = 292.375 0.2923kJ
0.01763m01
=1.65×107
AH in kJ/mol =
=
16.58K
0.01763mol
mol
qrx
Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con
Kelvin.)
AS=AHIT
(1.65×10(9.64×103) + (1.0
Jimai
For the compound: C8H17NO2
Use the following information to come up with a plausible structure:
8
This compound has "carboxylic acid amide" and ether functional groups.
The peaks at 1.2ppm are two signals that are overlapping one another.
One of the two signals is a doublet that represents 6 hydrogens; the
other signal is a quartet that represents 3 hydrogens.
Vnk the elements or compounds in the table below in decreasing order of their boiling points. That is, choose 1 next to the substance with the highest bolling
point, choose 2 next to the substance with the next highest boiling point, and so on.
substance
C
D
chemical symbol,
chemical formula
or Lewis structure.
CH,-N-CH,
CH,
H
H 10: H
C-C-H
H H H
Cale
H 10:
H-C-C-N-CH,
Bri
CH,
boiling point
(C)
Сен
(C) B
(Choose
Chapter 19 Solutions
Modified Mastering Chemistry with Pearson eText -- Standalone Access Card -- for Chemistry: A Molecular Approach (4th Edition)
Ch. 19 - Prob. 1SAQCh. 19 - Q2. Which statement is true for voltaic cells?
a)...Ch. 19 - Prob. 3SAQCh. 19 - Prob. 4SAQCh. 19 - Prob. 5SAQCh. 19 - Prob. 6SAQCh. 19 - Prob. 7SAQCh. 19 - Prob. 8SAQCh. 19 - Prob. 9SAQCh. 19 - Prob. 10SAQ
Ch. 19 - Prob. 11SAQCh. 19 - Prob. 12SAQCh. 19 - Prob. 13SAQCh. 19 - Prob. 14SAQCh. 19 - Q15. Which metal can be used as a sacrificial...Ch. 19 - 1. In electrochemistry, spontaneous redox...Ch. 19 - Prob. 2ECh. 19 - Prob. 3ECh. 19 - Prob. 4ECh. 19 - Prob. 5ECh. 19 - Prob. 6ECh. 19 - Prob. 7ECh. 19 - Prob. 8ECh. 19 - Prob. 9ECh. 19 - Prob. 10ECh. 19 - Prob. 11ECh. 19 - Prob. 12ECh. 19 - Prob. 13ECh. 19 - Prob. 14ECh. 19 - 15. Is a spontaneous redox reaction obtained by...Ch. 19 - 16. How can Table 19.1 be used to predict whether...Ch. 19 - 17. Explain why , , and K are all interrelated.
Ch. 19 - Prob. 18ECh. 19 - Prob. 19ECh. 19 - Prob. 20ECh. 19 - Prob. 21ECh. 19 - Prob. 22ECh. 19 - 23. What are the anode and cathode reactions in a...Ch. 19 - Prob. 24ECh. 19 - 25. What is a fuel cell? What is the most common...Ch. 19 - Prob. 26ECh. 19 - 27. List some applications of electrolysis.
Ch. 19 - Prob. 28ECh. 19 - 29. What species is oxidized, and what species is...Ch. 19 - Prob. 30ECh. 19 - Prob. 31ECh. 19 - Prob. 32ECh. 19 - Prob. 33ECh. 19 - Prob. 34ECh. 19 - Prob. 35ECh. 19 - Prob. 36ECh. 19 - Balance each redox reaction occurring in acidic...Ch. 19 - 38. Balance each redox reaction occurring in...Ch. 19 - 39. Balance each redox reaction occurring in...Ch. 19 - 40. Balance each redox reaction occurring in...Ch. 19 - 41. Balance each redox reaction occurring in basic...Ch. 19 - Prob. 42ECh. 19 - 43. Sketch a voltaic cell for each redox reaction....Ch. 19 - 44. Sketch a voltaic cell for each redox reaction....Ch. 19 - Prob. 45ECh. 19 - Prob. 46ECh. 19 - 47. Consider the voltaic cell:
a. Determine the...Ch. 19 - 48. Consider the voltaic cell:
a. Determine the...Ch. 19 - 49. Use line notation to represent each...Ch. 19 - 50. Use line notation to represent each...Ch. 19 - Prob. 51ECh. 19 - Prob. 52ECh. 19 - 53. Determine whether or not each redox reaction...Ch. 19 - 54. Determine whether or not each redox reaction...Ch. 19 - 55. Which metal could you use to reduce Mn2+ ions...Ch. 19 - Prob. 56ECh. 19 - Prob. 57ECh. 19 - Prob. 58ECh. 19 - Prob. 59ECh. 19 - Prob. 60ECh. 19 - Prob. 61ECh. 19 - 62. Calculate for each balanced redox reaction...Ch. 19 - Prob. 63ECh. 19 - 64. Which metal is the best reducing agent?
a....Ch. 19 - 65. Use tabulated electrode potentials to...Ch. 19 - Prob. 66ECh. 19 - 67. Calculate the equilibrium constant for each of...Ch. 19 - 68. Calculate the equilibrium constant for each of...Ch. 19 - Prob. 69ECh. 19 - Prob. 70ECh. 19 - Prob. 71ECh. 19 - Prob. 72ECh. 19 - 73. A voltaic cell employs the following redox...Ch. 19 - 74. A voltaic cell employs the redox reaction:
2...Ch. 19 - 75. An electrochemical cell is based on these two...Ch. 19 - Prob. 76ECh. 19 - 77. A voltaic cell consists of a Zn/Zn2+ half-cell...Ch. 19 - 78. A voltaic cell consists of a Pb/Pb2+ half-cell...Ch. 19 - Prob. 79ECh. 19 - Prob. 80ECh. 19 - 81. A concentration cell consists of two Sn/Sn2+...Ch. 19 - Prob. 82ECh. 19 - 83. Determine the optimum mass ratio of Zn to MnO2...Ch. 19 - 84. What mass of lead sulfate is formed in a...Ch. 19 - 85. Refer to the tabulated values of in Appendix...Ch. 19 - Prob. 86ECh. 19 - Prob. 87ECh. 19 - Prob. 88ECh. 19 - Prob. 89ECh. 19 - Prob. 90ECh. 19 - 91. Write equations for the half-reactions that...Ch. 19 - Prob. 92ECh. 19 - 93. Write equations for the half-reactions that...Ch. 19 - 94. What products are obtained in the electrolysis...Ch. 19 - 95. Write equations for the half-reactions that...Ch. 19 - Prob. 96ECh. 19 - 97. Make a sketch of an electrolysis cell that...Ch. 19 - Prob. 98ECh. 19 - Prob. 99ECh. 19 - Prob. 100ECh. 19 - Prob. 101ECh. 19 - Prob. 102ECh. 19 - Prob. 103ECh. 19 - Prob. 104ECh. 19 - Prob. 105ECh. 19 - Prob. 106ECh. 19 - 107. Consider the molecular views of an Al strip...Ch. 19 - Prob. 108ECh. 19 - Prob. 109ECh. 19 - Prob. 110ECh. 19 - Prob. 111ECh. 19 - Prob. 112ECh. 19 - Prob. 113ECh. 19 - Prob. 114ECh. 19 - Prob. 115ECh. 19 - Prob. 116ECh. 19 - Prob. 117ECh. 19 - Prob. 118ECh. 19 - 119. The Ksp of CuI is 1.1 × 10–12. Find Ecell for...Ch. 19 - 120. The Ksp of Zn(OH)2 is 1.8 × 10–14. Find Ecell...Ch. 19 - 121. Calculate and K for each reaction.
a. The...Ch. 19 - Prob. 122ECh. 19 - Prob. 123ECh. 19 - Prob. 124ECh. 19 - Prob. 125ECh. 19 - Prob. 126ECh. 19 - Prob. 127ECh. 19 - Prob. 128ECh. 19 - Prob. 129ECh. 19 - 130. To what pH should you adjust a standard...Ch. 19 - 131. Suppose a hydrogen–oxygen fuel-cell generator...Ch. 19 - 132. A voltaic cell designed to measure [Cu2+] is...Ch. 19 - 133. The surface area of an object to be gold...Ch. 19 - Prob. 134ECh. 19 - Prob. 135ECh. 19 - Prob. 136ECh. 19 - Prob. 137ECh. 19 - Prob. 138ECh. 19 - Prob. 139ECh. 19 - 140. A redox reaction employed in an...Ch. 19 - 141. A redox reaction has an equilibrium constant...Ch. 19 - Prob. 142QGWCh. 19 - Prob. 143DIACh. 19 - Prob. 144DIACh. 19 - 145. Design a device that uses an electrochemical...Ch. 19 - Prob. 146DIACh. 19 - Prob. 147DIA
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