The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified. Concept introduction: Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions. Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions. Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

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Answer 1

Question

Chapter 19, Problem 19.73QP

(a)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(b)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(c)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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Answer 2

Question

Chapter 19, Problem 19.73QP

(a)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(b)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(c)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

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Answer 3

Question

Chapter 19, Problem 19.73QP

(a)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(b)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(c)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

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Answer 4

Question

Chapter 19, Problem 19.73QP

(a)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(b)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(c)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

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Answer 5

Chapter 19, Problem 19.73QP

(a)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(b)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

(c)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

Answer 6

Chapter 19, Problem 19.73QP

(a)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

Answer 7

Chapter 19, Problem 19.73QP

(a)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given elementary reactions as unimolecualar, bimolecular, or termolecualar have to be classified.

Concept introduction:

Unimolecular: A molecule undergoes rearrangement itself to give one or more products is said to be unimolecuar reactions.

Bimolecular: Two molecules undergo collision to give one or more products is said to be bimolecular reactions.

Termolecular: Three molecules undergo collision to give one or more products is said to be termolecular reactions.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 19.3 - Prob. 19.1WE Ch. 19.3 - Write the rate expressions for each of the...Ch. 19.3 - Write the balanced equation corresponding to the...Ch. 19.3 - The diagrams represent a system that initially...Ch. 19.3 - Consider the reaction 4NO2(g)+O2(g)2N2O5(g) At a...Ch. 19.3 - Consider the reaction 4PH3(g)P4(g)+6H2(g) At a...Ch. 19.3 - Prob. 2PPB Ch. 19.3 - Prob. 2PPC Ch. 19.3 - Prob. 19.3.1SR Ch. 19.3 - Prob. 19.3.2SR

Solution Summary: The author explains that the elementary reactions are unimolecular, bimol, or termolecualar — a molecule undergoes rearrangement to give one or more products.

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