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Interpretation: Basic feature of galvanic cell and the separated component should be briefly described.
Concept Introduction:
Salt bridge: A salt bridge is an inverted U- tube that contains an electrolyte and connects the two half-cells in a galvanic cell.
OR
A tube containing an electrolyte, providing electrical contact between two solutions.
OR
A link between electrically charged acidic and basic groups, especially on different parts of a large molecule such as a protein.
Electrolyte:
An electrolyte is a compound which forms ions when dissolved in an aqueous solution.
Electrolyte may be acid base and salts. The most common electrolyte used is calcium, chloride, magnesium, etc.
Anode: Where oxidation occurs, gives off electrons.
Cathode: Where the reduction take place.
Cell voltage: The voltage experienced across the electrodes of a galvanic cell.
Electromotive force: It is the special kind of force which can measure the voltage.
Standard reduction potential: The voltages associate with the reduction reaction at an electrode when all solute are 1M and all gases are at 1atm.
The purpose of salt bridge is not to move electrons from the electrolyte; rather it’s to maintain charge balance because the electrons are moving from one half cell to the other.
The electron flow from anode to cathode.
Some example of galvanic cell are given below,
1) Concentration cell
2) Galvanic cell
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Chapter 19 Solutions
General Chemistry
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- Write the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.arrow_forwardNonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward
- 9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward
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