Exploring Chemical Analysis
Exploring Chemical Analysis
5th Edition
ISBN: 9781429275033
Author: Daniel C. Harris
Publisher: Macmillan Higher Education
Question
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Chapter 19, Problem 19.4P

(a)

Interpretation Introduction

Interpretation:

Number of lines per cm has to be calculated.

Concept Introduction:

Principle behind diffraction in reflection grating can be stated with the expression as follows:

  nλ=d(sinθ+sinϕ)

Formula to compute number of lines per cm is as follows:

  Number of lines/cm=1d(lines/m)(1 m100 cm)

Here,

d denotes repeat distance between closely spaced lines.

n denotes order of diffraction.

θ denotes angle made by emergent line.

ϕ denotes angle made by incident line.

(b)

Interpretation Introduction

Interpretation:

Number of lines per cm when wavenumber is 1000 cm1 has to be calculated.

Concept Introduction:

Refer to part (a).

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Q1: For each molecule, assign each stereocenter as R or S. Circle the meso compounds. Label each compound as chiral or achiral. + CI Br : Н OH H wo་ཡིག་ཐrow HO 3 D ။။ဂ CI Br H, CI Br Br H₂N OMe R IN I I N S H Br ជ័យ CI CI D OH
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