EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 19, Problem 19.21P
Interpretation Introduction

(a)

Interpretation:

The role of metal ion in enzymatic conversion reaction of acetaldehyde into ethanol is to be stated.

Concept introduction:

Enzymes are the biological catalyst. They are used to increase the rate of reactions which are occurring in a biological system.

The coenzyme nicotinamide adenine dinucleotide NAD+ is used in biological systems for oxidation of compounds. This NAD+ is reduced to NADH by transferring hydride ion.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanism for conversion reaction of acetaldehyde into ethanol is to be predicted.

Concept introduction:

Enzymes are the biological catalyst. They are used to increase the rate of reactions which are occurring in a biological system.

The coenzyme nicotinamide adenine dinucleotide NAD+ is used in biological systems for oxidation of compounds. This NAD+ is reduced to NADH by transferring hydride ion.

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Part II. two unbranched ketone have molecular formulla (C8H100). El-ms showed that both of them have a molecular ion peak at m/2 =128. However ketone (A) has a fragment peak at m/2 = 99 and 72 while ketone (B) snowed a fragment peak at m/2 = 113 and 58. 9) Propose the most plausible structures for both ketones b) Explain how you arrived at your conclusion by drawing the Structures of the distinguishing fragments for each ketone, including their fragmentation mechanisms.

Chapter 19 Solutions

EBK ORGANIC CHEMISTRY

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