EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
6th Edition
ISBN: 8220103151757
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 19, Problem 19.13P
Interpretation Introduction

(a)

Interpretation:

The product that is formed if the given diol undergoes pinacol rearrangement is to be predicted.

Concept introduction:

The method in which the conversion of 1,2diol into a carbonyl compound takes place is known as pinacol-pinacolone rearrangement. This rearrangement is carried out in the acidic medium. In this reaction a carbocation is formed.

Interpretation Introduction

(b)

Interpretation:

The product that is formed if the given diol undergoes pinacol rearrangement is to be predicted.

Concept introduction:

The method in which the conversion of 1,2diol into a carbonyl compound takes place is known as pinacol-pinacolone rearrangement. This rearrangement is carried out in the acidic medium. In this reaction a carbocation is formed.

Interpretation Introduction

(c)

Interpretation:

The product that is formed if the given diol undergoes pinacol rearrangement is to be predicted.

Concept introduction:

The method in which the conversion of 1,2diol into a carbonyl compound takes place is known as pinacol-pinacolone rearrangement. This rearrangement is carried out in the acidic medium. In this reaction a carbocation is formed.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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Chapter 19 Solutions

EBK ORGANIC CHEMISTRY

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