Glycine dissolved in pure water whether will have a protonated C O O H group and an unprotonated N H 2 group has to be determined. Concept Introduction: Dissociation constant of acid: An acid dissociation constant ( K a ) is a quantitative measure of the strength of an acid in solution. Dissociation constant of base: A base dissociation constant ( K b ) is a quantitative measure of the strength of a base in solution. Zwitterion: This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups , of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Question

Want to see the full answer?

Answer 1

Question

Chapter 19, Problem 19.120P

(a)

Interpretation Introduction

Interpretation:

Glycine dissolved in pure water whether will have a protonated $COOH$ group and an unprotonated $NH2$ group has to be determined.

Concept Introduction:

Dissociation constant of acid:

An acid dissociation constant $(Ka)$ is a quantitative measure of the strength of an acid in solution.

Dissociation constant of base:

A base dissociation constant $(Kb)$ is a quantitative measure of the strength of a base in solution.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(b)

Interpretation Introduction

Interpretation:

$[+NH3CH2COO−]/[+NH3CH2COOH]$ ratio has to be determined at $pH 5.5.$

Concept Introduction:

Henderson-Hasselbalch Equation:

The Henderson-Hasselbalch Equation can be written for any conjugate acid–base pair as given bellow,

$pH=pKa+log([Base][Acid])$

Where,

$pH = -log[H3O+]pKa= -logKaKa= Dissociation constant of acid[Base]= Concentration of base[Acid]= Concentration of acid$

(c)

Interpretation Introduction

Interpretation:

Structure of lysine at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be determined.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This word is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(d)

Interpretation Introduction

Interpretation:

The structure of glutamic acid at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be identified from the given options.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

1/2 - 51% + » GAY Organic Reactions Assignment /26 Write the type of reaction that is occurring on the line provided then complete the reaction. Only include the major products and any byproducts (e.g. H₂O) but no minor products. Please use either full structural diagrams or the combination method shown in the lesson. Skeletal/line diagrams will not be accepted. H3C 1. 2. CH3 A Acid OH Type of Reaction: NH Type of Reaction: + H₂O Catalyst + HBr 3. Type of Reaction: H3C 4. Type Reaction: 5. H3C CH2 + H2O OH + [0] CH3 Type of Reaction: 6. OH CH3 HO CH3 + Type of Reaction: 7. Type of Reaction: + [H]

humbnai Concentration Terms[1].pdf ox + New Home Edit Sign in Comment Convert Page Fill & Sign Protect Tools Batch +WPS A Free Trial Share Inter Concreting Concentration forms. Hydrogen peroxide is a powerful oxidizing agent wed in concentrated solution in rocket fuels and in dilute solution as a hair bleach. An aqueous sulation of H2O2 is 30% by mass and has density of #liligime calculat the Ⓒmolality ⑥mole fraction of molarity. 20 9. B. A sample of Commercial Concentrated hydrochloric ET

If a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.

Answer 2

Question

Chapter 19, Problem 19.120P

(a)

Interpretation Introduction

Interpretation:

Glycine dissolved in pure water whether will have a protonated $COOH$ group and an unprotonated $NH2$ group has to be determined.

Concept Introduction:

Dissociation constant of acid:

An acid dissociation constant $(Ka)$ is a quantitative measure of the strength of an acid in solution.

Dissociation constant of base:

A base dissociation constant $(Kb)$ is a quantitative measure of the strength of a base in solution.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(b)

Interpretation Introduction

Interpretation:

$[+NH3CH2COO−]/[+NH3CH2COOH]$ ratio has to be determined at $pH 5.5.$

Concept Introduction:

Henderson-Hasselbalch Equation:

The Henderson-Hasselbalch Equation can be written for any conjugate acid–base pair as given bellow,

$pH=pKa+log([Base][Acid])$

Where,

$pH = -log[H3O+]pKa= -logKaKa= Dissociation constant of acid[Base]= Concentration of base[Acid]= Concentration of acid$

(c)

Interpretation Introduction

Interpretation:

Structure of lysine at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be determined.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This word is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(d)

Interpretation Introduction

Interpretation:

The structure of glutamic acid at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be identified from the given options.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 19, Problem 19.120P

(a)

Interpretation Introduction

Interpretation:

Glycine dissolved in pure water whether will have a protonated $COOH$ group and an unprotonated $NH2$ group has to be determined.

Concept Introduction:

Dissociation constant of acid:

An acid dissociation constant $(Ka)$ is a quantitative measure of the strength of an acid in solution.

Dissociation constant of base:

A base dissociation constant $(Kb)$ is a quantitative measure of the strength of a base in solution.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(b)

Interpretation Introduction

Interpretation:

$[+NH3CH2COO−]/[+NH3CH2COOH]$ ratio has to be determined at $pH 5.5.$

Concept Introduction:

Henderson-Hasselbalch Equation:

The Henderson-Hasselbalch Equation can be written for any conjugate acid–base pair as given bellow,

$pH=pKa+log([Base][Acid])$

Where,

$pH = -log[H3O+]pKa= -logKaKa= Dissociation constant of acid[Base]= Concentration of base[Acid]= Concentration of acid$

(c)

Interpretation Introduction

Interpretation:

Structure of lysine at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be determined.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This word is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(d)

Interpretation Introduction

Interpretation:

The structure of glutamic acid at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be identified from the given options.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 19, Problem 19.120P

(a)

Interpretation Introduction

Interpretation:

Glycine dissolved in pure water whether will have a protonated $COOH$ group and an unprotonated $NH2$ group has to be determined.

Concept Introduction:

Dissociation constant of acid:

An acid dissociation constant $(Ka)$ is a quantitative measure of the strength of an acid in solution.

Dissociation constant of base:

A base dissociation constant $(Kb)$ is a quantitative measure of the strength of a base in solution.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(b)

Interpretation Introduction

Interpretation:

$[+NH3CH2COO−]/[+NH3CH2COOH]$ ratio has to be determined at $pH 5.5.$

Concept Introduction:

Henderson-Hasselbalch Equation:

The Henderson-Hasselbalch Equation can be written for any conjugate acid–base pair as given bellow,

$pH=pKa+log([Base][Acid])$

Where,

$pH = -log[H3O+]pKa= -logKaKa= Dissociation constant of acid[Base]= Concentration of base[Acid]= Concentration of acid$

(c)

Interpretation Introduction

Interpretation:

Structure of lysine at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be determined.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This word is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(d)

Interpretation Introduction

Interpretation:

The structure of glutamic acid at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be identified from the given options.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 19, Problem 19.120P

(a)

Interpretation Introduction

Interpretation:

Glycine dissolved in pure water whether will have a protonated $COOH$ group and an unprotonated $NH2$ group has to be determined.

Concept Introduction:

Dissociation constant of acid:

An acid dissociation constant $(Ka)$ is a quantitative measure of the strength of an acid in solution.

Dissociation constant of base:

A base dissociation constant $(Kb)$ is a quantitative measure of the strength of a base in solution.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(b)

Interpretation Introduction

Interpretation:

$[+NH3CH2COO−]/[+NH3CH2COOH]$ ratio has to be determined at $pH 5.5.$

Concept Introduction:

Henderson-Hasselbalch Equation:

The Henderson-Hasselbalch Equation can be written for any conjugate acid–base pair as given bellow,

$pH=pKa+log([Base][Acid])$

Where,

$pH = -log[H3O+]pKa= -logKaKa= Dissociation constant of acid[Base]= Concentration of base[Acid]= Concentration of acid$

(c)

Interpretation Introduction

Interpretation:

Structure of lysine at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be determined.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This word is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

(d)

Interpretation Introduction

Interpretation:

The structure of glutamic acid at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be identified from the given options.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Answer 6

Chapter 19, Problem 19.120P

(a)

Interpretation Introduction

Interpretation:

Glycine dissolved in pure water whether will have a protonated $COOH$ group and an unprotonated $NH2$ group has to be determined.

Concept Introduction:

Dissociation constant of acid:

An acid dissociation constant $(Ka)$ is a quantitative measure of the strength of an acid in solution.

Dissociation constant of base:

A base dissociation constant $(Kb)$ is a quantitative measure of the strength of a base in solution.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Answer 7

Chapter 19, Problem 19.120P

(a)

Interpretation Introduction

Interpretation:

Glycine dissolved in pure water whether will have a protonated $COOH$ group and an unprotonated $NH2$ group has to be determined.

Concept Introduction:

Dissociation constant of acid:

An acid dissociation constant $(Ka)$ is a quantitative measure of the strength of an acid in solution.

Dissociation constant of base:

A base dissociation constant $(Kb)$ is a quantitative measure of the strength of a base in solution.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Answer 8

(b)

Interpretation Introduction

Interpretation:

$[+NH3CH2COO−]/[+NH3CH2COOH]$ ratio has to be determined at $pH 5.5.$

Concept Introduction:

Henderson-Hasselbalch Equation:

The Henderson-Hasselbalch Equation can be written for any conjugate acid–base pair as given bellow,

$pH=pKa+log([Base][Acid])$

Where,

$pH = -log[H3O+]pKa= -logKaKa= Dissociation constant of acid[Base]= Concentration of base[Acid]= Concentration of acid$

Answer 9

(b)

Interpretation Introduction

Interpretation:

$[+NH3CH2COO−]/[+NH3CH2COOH]$ ratio has to be determined at $pH 5.5.$

Concept Introduction:

Henderson-Hasselbalch Equation:

The Henderson-Hasselbalch Equation can be written for any conjugate acid–base pair as given bellow,

$pH=pKa+log([Base][Acid])$

Where,

$pH = -log[H3O+]pKa= -logKaKa= Dissociation constant of acid[Base]= Concentration of base[Acid]= Concentration of acid$

Answer 10

(c)

Interpretation Introduction

Interpretation:

Structure of lysine at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be determined.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This word is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Structure of lysine at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be determined.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This word is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structure of glutamic acid at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be identified from the given options.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structure of glutamic acid at $pH 1$ , physiological $pH$ $(∼ 7)$ and $pH 13$ has to be identified from the given options.

Concept Introduction:

Acidic $pH$ means $H+$ ions are available. In other words, the concentration of $H+$ ion is more. So the base present in the system will be protonated.

Basic $pH$ means the concentration of $H+$ ion is less, the concentration of $OH−$ ion is more. So the acid present in the system will be deprotonated.

Physiological $pH$ $(∼ 7)$ means neutral. The concentration of $H+$ ion and $OH−$ ion are same. At such condition zwitterion will be formed.

Zwitterion:

This term is used mostly in case of amino acids. Zwitterion is a molecule with two or more functional groups, of which at least one has a positive and one has a negative electrical charge and the net charge of the entire molecule is zero.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 17

Ch. 19.1 - Calculate the pH of a buffer consisting of 0.50 M...Ch. 19.1 - Prob. 19.1BFP Ch. 19.1 - Prob. 19.2AFP Ch. 19.1 - The molecular scenes below show three samples of a...Ch. 19.1 - Prob. 19.3AFP Ch. 19.1 - What is the component concentration ratio, [NH3]/...Ch. 19.2 - A chemist titrates 20.00 mL of 0.2000 M HBrO (Ka =...Ch. 19.2 - For the titration of 30.00 mL of 0.1000 M benzoic...Ch. 19.3 - Write the ion-product expression at equilibrium...Ch. 19.3 - Prob. 19.5BFP

Want to see the full answer?

Chapter 19 Solutions