Products for given reactions has to be drawn. Concept introduction: Given reactions are alkylation at the β carbon of the α , β − unsaturated compound. An α , β − unsaturated compound can react with a β -diketone, β -diester, β -keto nitrile, or β -ketoester. The reaction is called Michael reaction.

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Answer 1

Question

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

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Naming the Alkanes a) Write the IUPAC nomenclature of the compound below b) Draw 4-isopropyl-2,4,5-trimethylheptane, identify the primary, secondary, tertiary, and quaternary carbons. c) Rank pentane, neopentane and isopentane for boiling point. pentane: H3C-CH2-CH2-CH2-CH3 neopentane: CH3 H3C-Ċ-CH3 I CH3 isopentane: CH3 H3C-CH2-CH-CH3

Which will evaporate faster, 1-Butanol or Pentane? Explain your choice.

Using the equation below, what is the rate of this reaction if the rate of disappearance of H2 is 0.44 M/sec? H2 + Br2 → 2HBr

Answer 2

Question

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

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Answer 3

Question

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

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Answer 4

Question

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

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Answer 5

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 6

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 7

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18.1 - Prob. 1P Ch. 18.1 - Prob. 2P Ch. 18.1 - Prob. 3P Ch. 18.1 - Prob. 4P Ch. 18.1 - PROBLEM 5♦ List the compounds in each of the...Ch. 18.2 - Explain why 92% of 2,4-pemtanedione exists as the...Ch. 18.3 - Draw the enol tautomers for each of the following...Ch. 18.3 - Prob. 8P Ch. 18.4 - Prob. 9P Ch. 18.4 - Prob. 10P

Solution Summary: The author explains that products for given reactions have to be drawn.

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