Products for given reactions has to be drawn. Concept introduction: Given reactions are alkylation at the β carbon of the α , β − unsaturated compound. An α , β − unsaturated compound can react with a β -diketone, β -diester, β -keto nitrile, or β -ketoester. The reaction is called Michael reaction.

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Answer 1

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Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

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A student proposes the transformation below in one step of an organic synthesis. There may be one or more reactants missing from the left-hand side, but there are no products missing from the right-hand side. There may also be catalysts, small inorganic reagents, and other important reaction conditions missing from the arrow. • Is the student's transformation possible? If not, check the box under the drawing area. . If the student's transformation is possible, then complete the reaction by adding any missing reactants to the left-hand side, and adding required catalysts, inorganic reagents, or other important reaction conditions above and below the arrow. • You do not need to balance the reaction, but be sure every important organic reactant or product is shown. + T X O O лет-ле HO OH HO OH This transformation can't be done in one step.

Determine the structures of the missing organic molecules in the following reaction: X+H₂O H* H+ Y OH OH Note: Molecules that share the same letter have the exact same structure. In the drawing area below, draw the skeletal ("line") structures of the missing organic molecules X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. X S

Predict the major products of this organic reaction. If there aren't any products, because nothing will happen, check the box under the drawing area instead. No reaction. HO. O :☐ + G Na O.H Click and drag to start drawing a structure. XS xs H₂O

Answer 2

Question

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

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Answer 3

Question

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

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Answer 4

Question

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

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Answer 5

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 6

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 7

Chapter 18.9, Problem 18P

(a)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation: Products for given reactions has to be drawn.

Concept introduction: Given reactions are alkylation at the β carbon of the α,β− unsaturated compound. An α,β− unsaturated compound can react with a β-diketone, β-diester, β-keto nitrile, or β-ketoester. The reaction is called Michael reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18.1 - Prob. 1P Ch. 18.1 - Prob. 2P Ch. 18.1 - Prob. 3P Ch. 18.1 - Prob. 4P Ch. 18.1 - PROBLEM 5♦ List the compounds in each of the...Ch. 18.2 - Explain why 92% of 2,4-pemtanedione exists as the...Ch. 18.3 - Draw the enol tautomers for each of the following...Ch. 18.3 - Prob. 8P Ch. 18.4 - Prob. 9P Ch. 18.4 - Prob. 10P

Solution Summary: The author explains that products for given reactions have to be drawn.

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Chapter 18 Solutions