a) Interpretation: The name of the compound given is to be stated. Concept introduction: Thioalcohols are named as derivatives of the parent alkane using the suffix – thiol . The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with – thiol . The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded. To give: The name of the compound shown.

Question

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Answer 1

Question

Chapter 18.8, Problem 16P

Interpretation Introduction

a)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thiol. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

b)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –al. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

c)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

In naming cyclic thioalcohols the parent name is derived from the cycloalkene ring by replacing –e of the cycloalkene with –thiol. The ring is numbered from the carbon with –SH in such a way that lowest number possible is given to the other functional groups present.

To give:

The name of the compound shown.

Interpretation Introduction

d)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the sulfide shown.

Interpretation Introduction

e)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the disulfide shown.

Interpretation Introduction

f)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the compound shown.

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Consider the following Figure 2 and two atoms that are initially an infinite distance apart, x =00, at which point the potential energy of the system is U = 0. If they are brought together to x = x, the potential energy is related to the total force P by dU dx = P Given this, qualitatively sketch the variation of U with x. What happens at x=x? What is the significance of x = x, in terms of the potential energy? 0 P, Force 19 Attraction Total Repulsion x, Distance Figure 2. Variation with distance of the attractive, repulsive, and total forces between atoms. The slope dP/dx at the equilibrium spacing xe is proportional to the elastic modulus E; the stress σb, corresponding to the peak in total force, is the theoretical cohesive strength.

Answer 2

Question

Chapter 18.8, Problem 16P

Interpretation Introduction

a)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thiol. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

b)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –al. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

c)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

In naming cyclic thioalcohols the parent name is derived from the cycloalkene ring by replacing –e of the cycloalkene with –thiol. The ring is numbered from the carbon with –SH in such a way that lowest number possible is given to the other functional groups present.

To give:

The name of the compound shown.

Interpretation Introduction

d)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the sulfide shown.

Interpretation Introduction

e)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the disulfide shown.

Interpretation Introduction

f)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the compound shown.

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Answer 3

Question

Chapter 18.8, Problem 16P

Interpretation Introduction

a)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thiol. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

b)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –al. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

c)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

In naming cyclic thioalcohols the parent name is derived from the cycloalkene ring by replacing –e of the cycloalkene with –thiol. The ring is numbered from the carbon with –SH in such a way that lowest number possible is given to the other functional groups present.

To give:

The name of the compound shown.

Interpretation Introduction

d)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the sulfide shown.

Interpretation Introduction

e)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the disulfide shown.

Interpretation Introduction

f)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the compound shown.

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Answer 4

Question

Chapter 18.8, Problem 16P

Interpretation Introduction

a)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thiol. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

b)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –al. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

c)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

In naming cyclic thioalcohols the parent name is derived from the cycloalkene ring by replacing –e of the cycloalkene with –thiol. The ring is numbered from the carbon with –SH in such a way that lowest number possible is given to the other functional groups present.

To give:

The name of the compound shown.

Interpretation Introduction

d)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the sulfide shown.

Interpretation Introduction

e)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the disulfide shown.

Interpretation Introduction

f)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the compound shown.

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Answer 5

Chapter 18.8, Problem 16P

Interpretation Introduction

a)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thiol. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

b)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –al. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

c)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

In naming cyclic thioalcohols the parent name is derived from the cycloalkene ring by replacing –e of the cycloalkene with –thiol. The ring is numbered from the carbon with –SH in such a way that lowest number possible is given to the other functional groups present.

To give:

The name of the compound shown.

Interpretation Introduction

d)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the sulfide shown.

Interpretation Introduction

e)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the disulfide shown.

Interpretation Introduction

f)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the compound shown.

Answer 6

Chapter 18.8, Problem 16P

Interpretation Introduction

a)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thiol. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Answer 7

Chapter 18.8, Problem 16P

Interpretation Introduction

a)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thiol. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Answer 8

Interpretation Introduction

b)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –al. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Answer 9

Interpretation Introduction

b)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –al. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Answer 10

Interpretation Introduction

c)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

In naming cyclic thioalcohols the parent name is derived from the cycloalkene ring by replacing –e of the cycloalkene with –thiol. The ring is numbered from the carbon with –SH in such a way that lowest number possible is given to the other functional groups present.

To give:

The name of the compound shown.

Answer 11

Interpretation Introduction

c)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

In naming cyclic thioalcohols the parent name is derived from the cycloalkene ring by replacing –e of the cycloalkene with –thiol. The ring is numbered from the carbon with –SH in such a way that lowest number possible is given to the other functional groups present.

To give:

The name of the compound shown.

Answer 12

Interpretation Introduction

d)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the sulfide shown.

Answer 13

Interpretation Introduction

d)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the sulfide shown.

Answer 14

Interpretation Introduction

e)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the disulfide shown.

Answer 15

Interpretation Introduction

e)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the disulfide shown.

Answer 16

Interpretation Introduction

f)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the compound shown.

Answer 17

Interpretation Introduction

f)

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the compound shown.

Answer 18

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Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 18.1 - Name the following ethers:Ch. 18.2 - Why do you suppose only symmetrical ethers are...Ch. 18.2 - How would you prepare the following ethers using a...Ch. 18.2 - Review the mechanism of oxymercuration shown in...Ch. 18.2 - How would you prepare the following ethers? Use...Ch. 18.2 - Prob. 6P Ch. 18.3 - Prob. 7P Ch. 18.3 - Write the mechanism of the acid-induced cleavage...Ch. 18.3 - Why are HI and HBr more effective than HCl in...Ch. 18.4 - What product would you expect from Claisen...

Solution Summary: The name of the compound shown is 2,2,6-trimethylheptane-4 - thiol.

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