Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 18.4, Problem 18.2QC
Problem 19-2
Complete the equation for each hydrolysis reaction. Draw all products as they are ionized under these experimental conditions.
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3. Refer to the data below to answer the following questions:
Isoelectric point
Amino Acid
Arginine
10.76
Glutamic Acid
3.22
Tryptophan
5.89
A. Define isoelectric point.
B. The most basic amino acid is
C. The most acidic amino acid is
sidizo zo
3. A gas mixture contains 50 mol% H2 and 50 mol% He.
1.00-L samples of this gas mixture are mixed with
variable volumes of O2 (at 0 °C and 1 atm). A spark is
introduced to allow the mixture to undergo complete
combustion. The final volume is measured at 0 °C and 1
atm. Which graph best depicts the final volume as a
function of the volume of added O2?
(A)
2.00
1.75
Final Volume, L
1.50
1.25
1.00
0.75
0.50
0.25
0.00
0.00
0.25
0.50
2.00
(B)
1.75
1.50
Final Volume, L
1.25
1.00
0.75
0.50-
0.25
0.00
0.75
1.00
0.00
0.25
Volume O₂ added, L
2
0.50
0.75
1.00
Volume O₂ added, L
2
2.00
2.00
(C)
(D)
1.75
1.75
1.50
1.50
Final Volume, L
1.25
1.00
0.75
0.50
Final Volume, L
1.25
1.00
0.75
0.50
0.25
0.25
0.00
0.00
0.00
0.25
0.50
0.75
1.00
0.00
0.25
Volume O₂ added, L
0.50
0.75
1.00
Volume O₂ added, L
2
Leucine is an essential amino acid with the systematic name 2-amino-3-methylpentanoic acid. It has pai
2.36 and pKa2 = 9.60.
H2N-C(R)H-COOH and R is -CH2-CH(CH3)2
A. Draw the condensed structure for leucine, and label all chirality centers with an asterisk.
B. How many possible stereoisomers of leucine are there?
C. Draw a Fischer projection of L-leucine and label the chirality center(s) as R or S.
D. What is the p/ of leucine?
E. Draw the structure of the predominant form of leucine at 10.00.
F.
Draw the structure of the predominant form of leucine at pH = 1.50.
G. Leucine is described as an essential amino acid. What does this mean?
H. Show the alkyl halide you would use to prepare leucine by the amidomalonate method.
=
Chapter 18 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 18.1 - Prob. 18.1QCCh. 18.4 - Problem 19-2 Complete the equation for each...Ch. 18.4 - Prob. 18.3QCCh. 18 - Prob. 1PCh. 18 - Write the IUPAC name for each compound.Ch. 18 - Prob. 3PCh. 18 - Prob. 4PCh. 18 - Prob. 5PCh. 18 - Prob. 6PCh. 18 - 0 Complete the equations for these reactions.
Ch. 18 - Prob. 8PCh. 18 - Prob. 9PCh. 18 - Prob. 10PCh. 18 - Prob. 11PCh. 18 - Prob. 12PCh. 18 - 6 Why are Dacron and Mylar referred to as...Ch. 18 - 7 What type of structural feature do the...Ch. 18 - Prob. 15PCh. 18 - Prob. 16PCh. 18 - 0 Show how triphosphoric acid can form from three...Ch. 18 - 1 Write an equation for the hydrolysis of...Ch. 18 - Prob. 19PCh. 18 - (The Pyrethrins-Natural Insecticides of Plant...Ch. 18 - Prob. 21PCh. 18 - Prob. 22PCh. 18 - Prob. 23PCh. 18 - Prob. 24PCh. 18 - Prob. 25PCh. 18 - Prob. 26PCh. 18 - Prob. 27PCh. 18 - Prob. 28PCh. 18 - Prob. 29PCh. 18 - Prob. 30PCh. 18 - Prob. 31PCh. 18 - Prob. 32PCh. 18 - Prob. 33PCh. 18 - Prob. 34PCh. 18 - Prob. 35PCh. 18 - Prob. 36PCh. 18 - Prob. 37PCh. 18 - Prob. 38PCh. 18 - Prob. 39PCh. 18 - Prob. 40PCh. 18 - Prob. 41PCh. 18 - Prob. 42PCh. 18 - Prob. 43PCh. 18 - Prob. 44PCh. 18 - Prob. 45PCh. 18 - Prob. 46P
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