Student Study Guide and Solutions Manual T/A Organic Chemistry
2nd Edition
ISBN: 9781118647950
Author: David R. Klein
Publisher: WILEY
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Chapter 18.2, Problem 5ATS
Interpretation Introduction
Interpretation: Structure of meta-chloroperoxybenzoic acid (MCPBA) should be drawn and a systematic name for the compound formed by replacing the chlorine atom in MCPBA with a methyl group should be provided.
Concept introduction:
For naming and drawing the structure of polysubstituted benzene ring, following steps should be followed.
- 1. Identify and name the parent
- 2. Identify and name the substituent
- 3. Assign a locant to each substituent
- 4. Arrange the substituent alphabetically
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Consider the reaction of 2-methylpropane with a halogen. With which halogen will the product be almost exclusively 2-halo-2-methylpropane? 1. F2 2. Cl2 3. Br2 4. I2
None
Chapter 18 Solutions
Student Study Guide and Solutions Manual T/A Organic Chemistry
Ch. 18.2 - Prob. 1LTSCh. 18.2 - Prob. 1PTSCh. 18.2 - Prob. 2ATSCh. 18.2 - Prob. 3ATSCh. 18.2 - Prob. 4ATSCh. 18.2 - Prob. 5ATSCh. 18.4 - Prob. 6CCCh. 18.4 - Prob. 8CCCh. 18.4 - Prob. 9CCCh. 18.5 - Prob. 10CC
Ch. 18.5 - Prob. 2LTSCh. 18.5 - Prob. 11PTSCh. 18.5 - Prob. 12ATSCh. 18.5 - Prob. 13ATSCh. 18.5 - Prob. 14ATSCh. 18.5 - Prob. 3LTSCh. 18.5 - Prob. 15PTSCh. 18.5 - Prob. 16ATSCh. 18.5 - Prob. 17ATSCh. 18.5 - Prob. 18CCCh. 18.6 - Prob. 19CCCh. 18.6 - Prob. 4LTSCh. 18.6 - Prob. 20PTSCh. 18.6 - Prob. 21ATSCh. 18.6 - Prob. 22ATSCh. 18.6 - Prob. 23ATSCh. 18.7 - Prob. 5LTSCh. 18.7 - Prob. 24PTSCh. 18.7 - Prob. 25ATSCh. 18.8 - Prob. 26CCCh. 18.8 - Prob. 27CCCh. 18 - Prob. 28PPCh. 18 - Prob. 29PPCh. 18 - Prob. 30PPCh. 18 - Prob. 31PPCh. 18 - Prob. 32PPCh. 18 - Prob. 33PPCh. 18 - Prob. 34PPCh. 18 - Prob. 35PPCh. 18 - Prob. 36PPCh. 18 - Prob. 37PPCh. 18 - Prob. 38PPCh. 18 - Prob. 39PPCh. 18 - Prob. 40PPCh. 18 - Prob. 41PPCh. 18 - Prob. 42PPCh. 18 - Prob. 43PPCh. 18 - Prob. 44PPCh. 18 - Prob. 45PPCh. 18 - Prob. 46PPCh. 18 - Prob. 47PPCh. 18 - Prob. 48PPCh. 18 - Prob. 49PPCh. 18 - Prob. 50PPCh. 18 - Prob. 51PPCh. 18 - Prob. 52PPCh. 18 - Prob. 53IPCh. 18 - Prob. 54IPCh. 18 - Prob. 55IPCh. 18 - Prob. 56IPCh. 18 - Prob. 57IPCh. 18 - Prob. 58IPCh. 18 - Prob. 59IPCh. 18 - Prob. 60IPCh. 18 - Prob. 61IPCh. 18 - Prob. 62IPCh. 18 - Prob. 63IPCh. 18 - Prob. 64IPCh. 18 - Prob. 65IPCh. 18 - Prob. 66IPCh. 18 - Prob. 67IP
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