The amine and carbonyl compound that will combine to provide the given derivative are to be stated. Concept introduction: The reaction between ketone / aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.15, Problem 18.23P

(a)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <

2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.15, Problem 18.23P

(a)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.15, Problem 18.23P

(a)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18.15, Problem 18.23P

(a)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

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Answer 5

Chapter 18.15, Problem 18.23P

(a)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(b)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(c)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(d)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(e)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

(f)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 6

Chapter 18.15, Problem 18.23P

(a)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 7

Chapter 18.15, Problem 18.23P

(a)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 8

(b)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 9

(b)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 10

(c)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 11

(c)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 12

(d)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 13

(d)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 14

(e)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 15

(e)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 16

(f)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 17

(f)

Interpretation Introduction

Interpretation:

The amine and carbonyl compound that will combine to provide the given derivative are to be stated.

Concept introduction:

The reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps. First is the acid catalyzed addition of the amine to the carbonyl group. Second is acid catalyzed dehydration to get the desired product (an imine).

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 18.3 - Give the IUPAC name and (if possible) a common...Ch. 18.5D - NMR spectra for two compounds are given here,...Ch. 18.5D - Why were no products from the McLafferty...Ch. 18.5D - Use equations to show the fragmentation leading to...Ch. 18.5E - Prob. 18.5P Ch. 18.7D - Show how you would synthesize each compound from...Ch. 18.8 - Prob. 18.7P Ch. 18.9 - Predict the products of the following reactions....Ch. 18.9 - Show how the following transformations may be...Ch. 18.10 - Prob. 18.10P

Solution Summary: The author explains that the reaction between ketone/aldehyde and ammonia derivatives in mild acidic condition comprises two steps: acid catalyzed addition of the amine to the carbonyl group

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Chapter 18 Solutions