
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
4th Edition
ISBN: 9781119659525
Author: Klein
Publisher: WILEY CONS
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Question
Chapter 18.10, Problem 17ATS
Interpretation Introduction
Interpretation:
From the following compound, the aromatic ring that is more reactive towards aromatic electrophilic substitution reaction has to be identified.
Concept Introduction:
- The activation or deactivation of an aromatic ring towards electrophilic substitution reactions depend upon the electronic effects that the substituents produce.
- If the substituents enhance the electron density of the ring then the ring becomes activated towards the electrophilic substitution reactions.
- If the substituents present causes electron drain in the aromatic ring then the ring becomes deactivated towards electrophilic substitution reactions.
- Usually electron donating groups increase the electron density around the aromatic ring and activate the aromatic ring towards electrophilic substitution reactions. Hence they are known as activators.
- Depending upon the strength of activation there are strong, moderate or weak activators.
- Electron withdrawing groups decrease the electron density around the aromatic ring and deactivate the aromatic ring towards electrophilic substitution reactions. Hence they are known as deactivators.
- Depending upon the strength of deactivation there are strong, moderate or weak deactivators.
- The classification can be summarized as follows –
Activators | Deactivators | ||||
Strong |
Moderate |
Weak |
Strong |
Moderate |
Weak |
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Chapter 18 Solutions
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
Ch. 18.2 - Prob. 1CCCh. 18.3 - Prob. 2CCCh. 18.3 - Prob. 3CCCh. 18.4 - Prob. 4CCCh. 18.5 - Prob. 5CCCh. 18.5 - Prob. 6CCCh. 18.5 - Prob. 7CCCh. 18.6 - Prob. 8CCCh. 18.6 - Prob. 9CCCh. 18.6 - Prob. 10CC
Ch. 18.7 - Prob. 11CCCh. 18.7 - Prob. 12CCCh. 18.8 - Prob. 13CCCh. 18.9 - Prob. 14CCCh. 18.9 - Prob. 15CCCh. 18.10 - Prob. 1LTSCh. 18.10 - Prob. 16PTSCh. 18.10 - Prob. 17ATSCh. 18.11 - Prob. 2LTSCh. 18.11 - Prob. 18PTSCh. 18.12 - Prob. 24CCCh. 18.12 - Prob. 25CCCh. 18.12 - Prob. 5LTSCh. 18.12 - Prob. 26PTSCh. 18.12 - Prob. 6LTSCh. 18.12 - Prob. 28PTSCh. 18.13 - Prob. 30CCCh. 18.13 - Prob. 31CCCh. 18.13 - Prob. 32CCCh. 18.14 - Prob. 33CCCh. 18.14 - Prob. 34CCCh. 18.15 - Prob. 7LTSCh. 18.15 - Prob. 35PTSCh. 18.15 - Prob. 36PTSCh. 18 - Prob. 38PPCh. 18 - Prob. 39PPCh. 18 - Prob. 40PPCh. 18 - Prob. 41PPCh. 18 - Prob. 42PPCh. 18 - Prob. 43PPCh. 18 - Prob. 45PPCh. 18 - Prob. 46PPCh. 18 - Prob. 47PPCh. 18 - Prob. 48PPCh. 18 - Prob. 49PPCh. 18 - Prob. 50PPCh. 18 - Prob. 51PPCh. 18 - Prob. 52PPCh. 18 - Prob. 53PPCh. 18 - Prob. 54PPCh. 18 - Prob. 55PPCh. 18 - Prob. 56PPCh. 18 - Prob. 57PPCh. 18 - Prob. 58PPCh. 18 - Prob. 59PPCh. 18 - Prob. 60PPCh. 18 - Prob. 61PPCh. 18 - Prob. 62PPCh. 18 - Prob. 63PPCh. 18 - Prob. 64PPCh. 18 - Prob. 80IPCh. 18 - Prob. 81IPCh. 18 - Prob. 82IPCh. 18 - Prob. 83IPCh. 18 - Prob. 84IPCh. 18 - Prob. 85IPCh. 18 - Prob. 86IPCh. 18 - Prob. 87IPCh. 18 - Prob. 88IPCh. 18 - Prob. 89IP
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