
Interpretation: The compounds A and B should be determined and also the major product under given set of conditions should be determined.
Concept Introduction:
Electrophile: It is positively charged species which seeks for negative charge and hence accepts pair of electrons from negatively charged species (Nucleophiles) which results in the formation of
Electrophilic
Benzene becomes fewer reactive in EAS when deactivating groups are present on it.
Deactivating groups are often fine electron-withdrawing groups.
Electrophilic substitution
IR spectral studies: It is a spectroscopic technique which is used to determine the
Wavenumber: It is defined as the number of waves in one centimeter. The wavenumber indicates the location of each signal with respect to the functional group in the molecule and its unit is
Molecular formula: It represents the types of atoms with their total number present in a given molecule.
The Hydrogen Deficiency Index (HDI): It is used to measure the number of degrees of unsaturation (double and triple bonds) present in a given molecule. It is determined by using the formula

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Chapter 18 Solutions
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
- (a) Sketch the 'H NMR of the following chemical including the approximate chemical shifts, the multiplicity (splitting) of all signals and the integration (b) How many signals would you expect in the 13C NMR? CH3arrow_forwardDraw the Show the major and minor product(s) for the following reaction mechanisms for both reactions and show all resonance structures for any Explain why the major product is favoured? intermediates H-Brarrow_forwardChoose the right answerarrow_forward
- 8. What is the major product of the following reaction? KMnO4 b a TOH OH OH C d OH "OH HO OH OHarrow_forwardChoose the right answerarrow_forward3. Draw ALL THE POSSBILE PRODUCTS AND THE MECHANISMS WITH ALL RESONANCE STRUCTURES. Explain using the resonance structures why the major product(s) are formed over the minor product(s). H₂SO4, HONO CHarrow_forward
- 7. Provide the product(s), starting material(s) and/or condition(s) required for the No mechanisms required. below reaction HO + H-I CI FO Br2, FeBr3 O I-Oarrow_forward6. Design the most efficient synthesis of the following product starting from phenot Provide the reaction conditions for each step (more than one step is required) and explain the selectivity of each reaction. NO MECHANISMS ARE REQUIRED. OH step(s) CIarrow_forwardWhat is the skeletal structure of the product of the following organic reaction?arrow_forward
- If a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.arrow_forwardWhat is the major organic product of the following nucleophilic acyl substitution reaction of an acid chloride below?arrow_forwardWould the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forward
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