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Interpretation: The compounds A and B should be determined and also the major product under given set of conditions should be determined.
Concept Introduction:
Electrophile: It is positively charged species which seeks for negative charge and hence accepts pair of electrons from negatively charged species (Nucleophiles) which results in the formation of
Electrophilic
Benzene becomes fewer reactive in EAS when deactivating groups are present on it.
Deactivating groups are often fine electron-withdrawing groups.
Electrophilic substitution
IR spectral studies: It is a spectroscopic technique which is used to determine the
Wavenumber: It is defined as the number of waves in one centimeter. The wavenumber indicates the location of each signal with respect to the functional group in the molecule and its unit is
Molecular formula: It represents the types of atoms with their total number present in a given molecule.
The Hydrogen Deficiency Index (HDI): It is used to measure the number of degrees of unsaturation (double and triple bonds) present in a given molecule. It is determined by using the formula
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Chapter 18 Solutions
EBK ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG
- Balance the following equations Synthesis Ca 1. Mg + Cl₂ → MgCl2Syn 2. Al + 302 -> 2A1203Com 3. P4 + 502 4. Bi + + Cl₂ 5. H2 + N2 ↑ 6. Zn + 02 7. Cu + 02 8. Sn + 9. Na 10. 11. AR Ag + Cl₂ S8 I2 ↑ ↑ ↑ ↑ Pb + 12. Al + Br₂ 13. Fe + F2 ↑ 14. Sn + 15. Sb + 16. Ca + 17. Ba + 02 ↑ ↑ ↑ P4010 Com BiCl, Syn NH3 Syn Zno Com Cu2O com SnCl4 Syn Na2S Syn Agl Syn Pbo Com AlBr, yn FeF3 Syn Sno com Sb₂Ss Syn Cao cơm Bao cơm 18. Mg + P4 -> Mg3P2 Syn 19. K + K&N Syn ZnS Syn 20. Znarrow_forwardNonearrow_forwardConsidering the important roles of biothiols in lysosomes of live organisms, and unique photophysical / photochemical properties of ruthenium(II) complexes, a novel ruthenium(II) complex, Ru-2, has been developed as a molecular probe for phosphorescence and time-gated luminescence assay of biothiols in human sera, live cells, and in vivo. Ru-2 is weakly luminescent due to the effective photoinduced electron transfer (PET) from Ru(II) luminophore to electron acceptor, 2,4-dinitrobenzene-sulfonyl (DNBS). In the presence of biothiols, such as glutathione (GSH), cysteine (Cys), and homocysteine (Hcy), the emission of Ru-2 solution was switched ON, as a result of the cleavage of quencher to form the product, Ru-1. Ru-2 showed high selectivity and sensitivity for the detection of biothiols under physiological conditions, with detection limits of 62 nM, 146 nM, and 115 nM for GSH, Cys, and Hcy, respectively. The emission lifetimes of Ru-1 and Ru-2 were measured to be 405 and 474 ns,…arrow_forward
- In an effort to reduce costs and increase the accessibility of instruments that utilize spectrophotometric detection, some researchers are beginning to experiment with 3D-printed parts. One example of this is the 3D-printed flow cell, shown at right. This device was made using polylactic acid and accommodates a LED at one end and a detector at the other. It can be used for standalone flow injection spectrophotometry or coupled to a chromatographic separation to be used as a detector. Explain why the sensitivity varies with the length of the flow cell, as shown in the data below. Could this setup be used for fluorescence analysis? Why or why not?arrow_forwardThe dark lines in the solar spectrum were discovered by Wollaston and cataloged by Fraunhofer in the early days of the 19th century. Some years later, Kirchhoff explained the appearance of the dark lines: the sun was acting as a continuum light source and metals in the ground state in its atmosphere were absorbing characteristic narrow regions of the spectrum. This discovery eventually spawned atomic absorption spectrometry, which became a routine technique for chemical analysis in the mid-20th century. Laboratory-based atomic absorption spectrometers differ from the original observation of the Fraunhofer lines because they have always employed a separate light source and atomizer. This article describes a novel atomic absorption device that employs a single source, the tungsten coil, as both the generator of continuum radiation and the atomizer of the analytes. A 25-μL aliquot of sample is placed on the tungsten filament removed from a commercially available 150-W light bulb. The…arrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- Explain the term “inductively coupled plasma.”arrow_forwardUsing Pauling electronegativity values and a Ketelaar triangle, what type of compound is brass, a CuZn alloy? Group of answer choices metallic ionic covalentarrow_forwardChallenging samples: 1. Metal complexes with low volatility are often difficult to analyze when performing atomic absorption measurements because the atomization efficiency is reduced to unacceptably low levels. Devise a strategy or strategies for eliminating the problem of a non-volatile metal complex? Explain how you would do that. 2. Devise a strategy to overcome unwanted ionization of the analyte? Explain what it would be. 3. Devise a general method that can be used to account for the presence of unknown matrix effects.arrow_forward
- Don't used hand raitingarrow_forwardDon't used hand raiting don't used Ai solutionarrow_forwardHomework: Atomic Structure This homework is due at the beginning of class next lecture period and is worth 6 points. Please place the number of protons and neutrons in the nucleus and then put the number of electrons in the correct shell. Also give the correct atomic mass. Also, state if the atom is an ion (cation or anion). H* 1. Number of protons Number of electrons Number of neutrons Atomic mass 2. 26 13AI +++ Number of protons Number of neutrons Number of electrons Atomic massarrow_forward
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- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
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