ORGANIC CHEMISTRY BOOK& SG/SM
ORGANIC CHEMISTRY BOOK& SG/SM
6th Edition
ISBN: 9781264094493
Author: SMITH
Publisher: MCG
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Chapter 18.1, Problem 2P
Interpretation Introduction

Interpretation: An explanation for the less reactivity of benzaldehyde than cyclohexanecarbaldehyde towards nucleophilic attack is to be stated.

Concept introduction: Both aldehydes and ketones undergo nucleophilic addition reaction. The relative reactivity of carbonyl group, towards nucleophilic attack is inversely proportional to the number of R groups bonded to it. Aromatic compounds are less reactive towards nucleophilic attack, whereas nonaromatic compounds are highly reactive towards nucleophilic attack.

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19. Complete the following chart for the incorrect electron configurations shown in the left column. When drawing the correct electron configuration, assume the same number of electrons that were shown in the incorrect configuration. Incorrect Electron Configuration 2p ↑↓ ↑ 2s ↑↓ 1s ↑↓↓ ਵੇ ਵੇ ਵੇ 3p ↑ ↑ ↑ - 38 ↑ 2p 2s ↑↓ 1s 2p 2s 1s ** ↑↓ ↑↓ ↑↑ 리리리 Which principle or rule is violated? Explain the violated principle or rule in your own words Draw the correct electron configuration
14.36 Draw all reasonable resonance structures for each compound. a. + b. C. :O: d. :O: NH2 NH2 :O:
14.32 What diene and dienophile are needed to prepare each compound by a Diels-Alder reaction? a. b.

Chapter 18 Solutions

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