ORGANIC CHEMISTRY BOOK& SG/SM
ORGANIC CHEMISTRY BOOK& SG/SM
6th Edition
ISBN: 9781264094493
Author: SMITH
Publisher: MCG
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Chapter 18, Problem 67P
Interpretation Introduction

Interpretation: The structure of the product formed from the given reaction is to be drawn, and an explanation for its formation is to be stated.

Concept introduction: The OH groups are poor leaving groups. Therefore, they do not undergo substitution reaction until they are converted into good leaving group. The conversion of OH into good leaving group is possible, if reaction is acid catalyzed.

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19. Complete the following chart for the incorrect electron configurations shown in the left column. When drawing the correct electron configuration, assume the same number of electrons that were shown in the incorrect configuration. Incorrect Electron Configuration 2p ↑↓ ↑ 2s ↑↓ 1s ↑↓↓ ਵੇ ਵੇ ਵੇ 3p ↑ ↑ ↑ - 38 ↑ 2p 2s ↑↓ 1s 2p 2s 1s ** ↑↓ ↑↓ ↑↑ 리리리 Which principle or rule is violated? Explain the violated principle or rule in your own words Draw the correct electron configuration
14.36 Draw all reasonable resonance structures for each compound. a. + b. C. :O: d. :O: NH2 NH2 :O:
14.32 What diene and dienophile are needed to prepare each compound by a Diels-Alder reaction? a. b.

Chapter 18 Solutions

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