ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
4th Edition
ISBN: 9781119659556
Author: Klein
Publisher: WILEY
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Question
Chapter 18, Problem 82IP
(a)
Interpretation Introduction
Interpretation:
Product and optical activity given following reaction has to be predicted.
Concept Introduction:
- Electrophiles are electron deficient species. In Electrophilic substitution reaction a group or atom in a compound is replaced by electrophile. This kind of reaction occurs predominantly in
aromatic compounds . Electrophilic substitution reactions of aromatic compounds are known as aromatic electrophilic substitution reactions.
- Benzene is an electron rich Aromatic compound. It undergoes aromatic electrophilic substitution reaction.
- The delocalized nature of pi electrons in benzene attributes a special property to benzene called resonance.
- Enantiomers are chiral molecules to be mirror imagery of one another. In addition, the molecules are non-super imposable on one a new. This resource that the molecules cannot be placed on tops of one a further and give the similar molecule.
- Diastereomers are stereoisomer’s that are not mirror images of one another and are non-super imposable on one another.
- Friedel-Crafts Alkylation: This Lewis acid-catalyzed electrophilic aromatic replacement allows the synthesis of alkylated products by means of the reaction of arenes through
alkyl halides oralkenes.
(b)
Interpretation Introduction
Interpretation:
Product and optical activity given following reaction has to be predicted.
Concept Introduction:
- Electrophiles are electron deficient species. In Electrophilic substitution reaction a group or atom in a compound is replaced by electrophile. This kind of reaction occurs predominantly in aromatic compounds. Electrophilic substitution reactions of aromatic compounds are known as aromatic electrophilic substitution reactions.
- Benzene is an electron rich Aromatic compound. It undergoes aromatic electrophilic substitution reaction.
- The delocalized nature of pi electrons in benzene attributes a special property to benzene called resonance.
- Enantiomers are chiral molecules to be mirror imagery of one another. In addition, the molecules are non-super imposable on one a new. This resource that the molecules cannot be placed on tops of one a further and give the similar molecule.
- Diastereomers are stereoisomer’s that are not mirror images of one another and are non-super imposable on one another.
- Friedel-Crafts Alkylation: This Lewis acid-catalyzed electrophilic aromatic replacement allows the synthesis of alkylated products by means of the reaction of arenes through alkyl halides or alkenes.
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Students have asked these similar questions
A student proposes the transformation below in one step of an organic synthesis. There may be one or more reactants missing from the left-hand side, but there
are no products missing from the right-hand side. There may also be catalysts, small inorganic reagents, and other important reaction conditions missing from
the arrow.
• Is the student's transformation possible? If not, check the box under the drawing area.
. If the student's transformation is possible, then complete the reaction by adding any missing reactants to the left-hand side, and adding required catalysts,
inorganic reagents, or other important reaction conditions above and below the arrow.
• You do not need to balance the reaction, but be sure every important organic reactant or product is shown.
+
T
X
O
O
лет-ле
HO
OH
HO
OH
This transformation can't be done in one step.
Determine the structures of the missing organic molecules in the following reaction:
X+H₂O
H*
H+
Y
OH
OH
Note: Molecules that share the same letter have the exact same structure.
In the drawing area below, draw the skeletal ("line") structures of the missing organic molecules X and Y. You may draw the structures in any arrangement
that you like, so long as they aren't touching.
Click and drag to start drawing a structure.
X
S
Predict the major products of this organic reaction.
If there aren't any products, because nothing will happen, check the box under the drawing area instead.
No reaction.
HO.
O
:☐
+
G
Na O.H
Click and drag to start
drawing a structure.
XS
xs H₂O
Chapter 18 Solutions
ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
Ch. 18.2 - Prob. 1CCCh. 18.3 - Prob. 2CCCh. 18.3 - Prob. 3CCCh. 18.4 - Prob. 4CCCh. 18.5 - Prob. 5CCCh. 18.5 - Prob. 6CCCh. 18.5 - Prob. 7CCCh. 18.6 - Prob. 8CCCh. 18.6 - Prob. 9CCCh. 18.6 - Prob. 10CC
Ch. 18.7 - Prob. 11CCCh. 18.7 - Prob. 12CCCh. 18.8 - Prob. 13CCCh. 18.9 - Prob. 14CCCh. 18.9 - Prob. 15CCCh. 18.10 - Prob. 1LTSCh. 18.10 - Prob. 16PTSCh. 18.10 - Prob. 17ATSCh. 18.11 - Prob. 2LTSCh. 18.11 - Prob. 18PTSCh. 18.12 - Prob. 24CCCh. 18.12 - Prob. 25CCCh. 18.12 - Prob. 5LTSCh. 18.12 - Prob. 26PTSCh. 18.12 - Prob. 6LTSCh. 18.12 - Prob. 28PTSCh. 18.13 - Prob. 30CCCh. 18.13 - Prob. 31CCCh. 18.13 - Prob. 32CCCh. 18.14 - Prob. 33CCCh. 18.14 - Prob. 34CCCh. 18.15 - Prob. 7LTSCh. 18.15 - Prob. 35PTSCh. 18.15 - Prob. 36PTSCh. 18 - Prob. 38PPCh. 18 - Prob. 39PPCh. 18 - Prob. 40PPCh. 18 - Prob. 41PPCh. 18 - Prob. 42PPCh. 18 - Prob. 43PPCh. 18 - Prob. 45PPCh. 18 - Prob. 46PPCh. 18 - Prob. 47PPCh. 18 - Prob. 48PPCh. 18 - Prob. 49PPCh. 18 - Prob. 50PPCh. 18 - Prob. 51PPCh. 18 - Prob. 52PPCh. 18 - Prob. 53PPCh. 18 - Prob. 54PPCh. 18 - Prob. 55PPCh. 18 - Prob. 56PPCh. 18 - Prob. 57PPCh. 18 - Prob. 58PPCh. 18 - Prob. 59PPCh. 18 - Prob. 60PPCh. 18 - Prob. 61PPCh. 18 - Prob. 62PPCh. 18 - Prob. 63PPCh. 18 - Prob. 64PPCh. 18 - Prob. 80IPCh. 18 - Prob. 81IPCh. 18 - Prob. 82IPCh. 18 - Prob. 83IPCh. 18 - Prob. 84IPCh. 18 - Prob. 85IPCh. 18 - Prob. 86IPCh. 18 - Prob. 87IPCh. 18 - Prob. 88IPCh. 18 - Prob. 89IP
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