Interpretation: The given following transformations should be determined.
Concept Introduction:
Electrophile: It is positively charged species which seeks for negative charge and hence accepts pair of electrons from negatively charged species (Nucleophiles) which results in the formation of
Electrophilic substitution reactions are

Answer to Problem 38PP
Explanation of Solution
Chlorination of benzene.
Benzene reacts with Chlorine in an electrophilic substitution reaction, other than only in the presence of a catalyst. These compounds act as the catalyst and perform precisely like Aluminium chloride in these reactions.
Bromination of benzene.
Explanation: Benzene reacts with Bromine in an electrophilic substitution reaction, other than only in the presence of a catalyst. These compounds act as the catalyst and perform precisely like Aluminium bromide in these reactions.
Nitration followed by nitro reduction.
Nitration is a universal group of chemical procedure for the opening of a nitro group keen on an organic chemical compound. Extra loosely the term as well is applied imperfectly to the different process of forming nitrate esters between alcohols and nitric acid. Nitro group is converted into
Sulfonation of benzene.
Sulfonation is a reversible reaction so as to produces Benzene sulfonic acid by adding fuming Sulfuric acid.
Friedel-Crafts acyation followed by Clemmensen reduction.
Friedel-Crafts acyation of benzene linking an electrophilic substitution reaction between benzene and alkyl chloride in the presence of an Aluminium chloride catalyst.
Clemmensen reduction is a chemical reaction explain because a reduction of
Friedel Crafts alkylation followed by Oxidation.
Friedel Crafts alkylation involves the alkylation of an
The given following transformations should be determined.
Want to see more full solutions like this?
Chapter 18 Solutions
ORGANIC CHEMISTRY (LL)-W/WILEYPLUS
- Rank the compounds below from lowest to highest melting point.arrow_forward18 Question (1 point) Draw the line structure form of the given partially condensed structure in the box provided. :ÖH HC HC H2 ΙΩ Н2 CH2 CH3 CH3 partially condensed formarrow_forwardsomeone else has already submitted the same question on here and it was the incorrect answer.arrow_forward
- The reaction: 2NO2(g) ⇌ N2O4(g) is an exothermic reaction, ΔH=-58.0 kJ/molrxn at 0°C the KP is 58.If the initial partial pressures of both NO2(g) and N2O4(g) are 2.00 atm:A) Is the reaction at equilibrium? If not, what is the value of Q? B) Which direction will the reaction go to reach equilibrium? C) Use an ICE table to find the equilibrium pressures.arrow_forwardThe dissociation of the weak acid, nitrous acid, HNO2, takes place according to the reaction: HNO2 (aq) ⇌ H+(aq) + NO2–(aq) K=7.2 X 10-4 When 1.00 mole of HNO2 is added to 1.00 L of water, the H+ concentration at equilibrium is 0.0265 M.A) Calculate the value of Q if 1.00 L of water is added? B) How will reaction shift if 1.00 L of water is added?arrow_forwardSuppose a certain copolymer elastomeric material “styrene-butadiene rubber”) contains styrene ("S") monomers –(C8H8)– and butadiene ("B") monomers –(C4H6)– and that their numerical ratio S:B = 1:8. What is the mass ratio mS:mB of the two monomers in the material? What is the molecular mass M of a macromolecule of this copolymer with degree of polymerization n = 60,000? Data: AC = 12.01 u, AH = 1.008 u.arrow_forward
- Lab Questions from Lab: Gravimetric Determination of Calcium as CaC2O4•H2O What is the purpose of the methyl red indicator? Why does a color change to yellow tell you that the reaction is complete? Why is the precipitate rinsed with ice-cold water in step 4? Why not room temperature or hot water? Why is it important that the funnels be placed in a desiccator before weighing (steps 1 and 5)?arrow_forwardWhat mass of ethylene glycol, HOCH2CH2OH, Mustbe added to 5.50 kg of water to antifreeze that would work for the car radiator to -10.0 degrees celcius? MM (g/mol): 62.07arrow_forwardWhat is the molarity of a 0.393 m glucose solution if its density is 1.16 g/mL? MM glucose 180.2 g/molarrow_forward
- The rate constant for the decay of a radioactive element is 2.28 × 10⁻³ day⁻¹. What is the half-life of this element in days?arrow_forwardHandwritten pleasearrow_forwardChoose the best reagents to complete the following reaction. i H A B 1. CH3CH2Na 2. H3O+ 1. CH3CH2MgBr 2. H3O+ 1. CH3MgBr Q C 2. H3O+ 1. H3O+ D 2. CH3MgBr 00 OH Q E CH³MgBrarrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY





