ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
ORGANIC CHEMISTRY (LL)-W/SOLN.>CUSTOM<
10th Edition
ISBN: 9781259972348
Author: Carey
Publisher: MCG CUSTOM
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Chapter 18, Problem 47P
Interpretation Introduction

Interpretation:

The structure of the compound according to the given molecular formula (C7H14O) and distinct peak values that are observed in both the IR spectrum and H1 NMR spectrum is to be identified.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations.

Infra-red (IR) spectroscopy is used for the detection of the functional group present in the compound.

Proton NMR spectroscopy identifies the total number of hydrogen atoms present in a molecule and the nature of the functional group.

The value of chemical peaks in NMR depends upon the chemical environment around the hydrogen atom.

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2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11

Chapter 18 Solutions

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NMR Spectroscopy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=SBir5wUS3Bo;License: Standard YouTube License, CC-BY