Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 18, Problem 45PP
Interpretation Introduction

Interpretation: “Diphenyl methane achieve co-planarity in the highest energy conformation” – it should be explained

Concept introduction:

  • For a compound that bears two aromatic rings separated by one carbon atom, the single bond experiences free rotation at room temperature
  • Free rotation of the single bond enables the molecule to adopt different conformations
  • When two rings are co-planar, there is a significant steric interaction between two of the aromatic hydrogen atoms.
  • Steric interaction can be reduce by adopting a conformation in which the two rings are not coplanar

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43) 10.00 ml of vinegar (active ingredient is acetic acid) is titrated to the endpoint using 19.32 ml of 0.250 M sodium hydroxide. What is the molarity of acetic acid in the vinegar? YOU MUST SHOW YOUR WORK. NOTE: MA x VA = MB x VB
424 Repon Sheet Rates of Chemical Reactions : Rate and Order of 1,0, Deception B. Effect of Temperature BATH TEMPERATURE 35'c Yol of Oh نام Time 485 Buret rend ing(n) 12 194 16. 6 18 20 10 22 24 14 115 95 14738 2158235 8:26 CMS 40148 Total volume of 0, collected Barometric pressure 770-572 ml mm Hg Vapor pressure of water at bath temperature (see Appendix L) 42.2 Slope Compared with the rate found for solution 1, there is Using the ideal gas law, calculate the moles of O; collected (show calculations) times faster 10 Based on the moles of O, evolved, calculate the molar concentration of the original 3% 1,0, solution (sho calculations)
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Organic Chemistry, Binder Ready Version

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