![Organic Chemistry, Binder Ready Version](https://www.bartleby.com/isbn_cover_images/9781118454312/9781118454312_largeCoverImage.gif)
(a)
Interpretation: For the given compounds, IUPAC name should be provided.
Concept introduction:
For naming and the polysubstituted benzene ring, following steps should be followed.
- 1. Identify and name the parent
- 2. Identify and name the substituent
- 3. Assign a locant to each substituent
- 4. Arrange the substituent alphabetically
(a)
![Check Mark](/static/check-mark.png)
Answer to Problem 28PP
- Name for the given compound
4-ethylbenzoic acid
Explanation of Solution
4-ethylbenzoic acid
From the structure of the compound it is clear that the parent group is benzoic acid.
The second step to name the structure of the polysubstituted benzene ring is
Identification of substituent and its locant at the lowest possible number, for the given compound an ethyl group is a substituent and it is placed to the 4th (
(b)
Interpretation: For the given compounds, IUPAC name should be provided.
Concept introduction:
For naming and the polysubstituted benzene ring, following steps should be followed.
- 5. Identify and name the parent
- 6. Identify and name the substituent
- 7. Assign a locant to each substituent
- 8. Arrange the substituent alphabetically
(b)
![Check Mark](/static/check-mark.png)
Answer to Problem 28PP
- Name for the given compound
b)
-
2-bromophenol
Explanation of Solution
The given compound b2-bromophenol
From the structure of the compound it is clear that the parent group is phenol.
The second step to name the structure of the polysubstituted benzene ring is
Identification of substituent and its locant at the lowest possible number. For the given compound bromine atom is a substituent and they are placed to the 2nd (
(c)
Interpretation: For the given compounds, IUPAC name should be provided.
Concept introduction:
For naming and the polysubstituted benzene ring, following steps should be followed.
- 9. Identify and name the parent
- 10. Identify and name the substituent
- 11. Assign a locant to each substituent
- 12. Arrange the substituent alphabetically
(c)
![Check Mark](/static/check-mark.png)
Answer to Problem 28PP
- Name for the given compound
2-chloro-4-nitrophenol
Explanation of Solution
The given compound c
2-chloro-4-nitrophenol
From the structure of the compound it is clear that the parent group is phenol.
The second step to name the structure of the polysubstituted benzene ring is
Identification of substituent and its locant at the lowest possible number. For the given compound a chlorine atom and nitro group are substituent and they are placed to the 2nd (
(d)
Interpretation: For the given compounds, IUPAC name should be provided.
Concept introduction:
For naming and the polysubstituted benzene ring, following steps should be followed.
- 13. Identify and name the parent
- 14. Identify and name the substituent
- 15. Assign a locant to each substituent
- 16. Arrange the substituent alphabetically
(d)
![Check Mark](/static/check-mark.png)
Answer to Problem 28PP
- Name for the given compound
d)
2-bromo-5-nitrobenzaldehyde
Explanation of Solution
The given compound d
2-bromo-5-nitrobenzaldehyde
From the structure of the compound it is clear that the parent group is benzaldehyde.
The second step to name the structure of the polysubstituted benzene ring is
Identification of substituent and its locant at the lowest possible number. For the given compound a bromine atom and nitro group are substituent and they are placed to the 2nd (
(e)
Interpretation: For the given compounds, IUPAC name should be provided.
Concept introduction:
For naming and the polysubstituted benzene ring, following steps should be followed.
- 17. Identify and name the parent
- 18. Identify and name the substituent
- 19. Assign a locant to each substituent
- 20. Arrange the substituent alphabetically
(e)
![Check Mark](/static/check-mark.png)
Answer to Problem 28PP
- Name for the given compound
-
1, 4-diisopropylbenzene
Explanation of Solution
The given compound e
1, 4-diisopropylbenzene
From the structure of the compound it is clear that the parent group is benzene.
The second step to name the structure of the polysubstituted benzene ring is
Identification of substituent and its locant at the lowest possible number. For the given compound there are two substituents, both isopropyl group it is placed to the 1st (
Want to see more full solutions like this?
Chapter 18 Solutions
Organic Chemistry, Binder Ready Version
- Nonearrow_forwardIn the solid state, oxalic acid occurs as a dihydrate with the formula H2C2O4 C+2H2O. Use this formula to calculate the formula weight of oxalic acid. Use the calculated formula weight and the number of moles (0.00504mol) of oxalic acid in each titrated unknown sample recorded in Table 6.4 to calculate the number of grams of pure oxalic acid dihydrate contained in each titrated unknown sample.arrow_forward1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)arrow_forward
- Write the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.arrow_forwardNonearrow_forward3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward
- 9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305957404/9781305957404_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781259911156/9781259911156_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305577213/9781305577213_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9780078021558/9780078021558_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781305079373/9781305079373_smallCoverImage.gif)
![Text book image](https://www.bartleby.com/isbn_cover_images/9781118431221/9781118431221_smallCoverImage.gif)