(a) Interpretation: The direction in which equilibrium will shift on adding N 2 O 4 for the equilibrium system N 2 O 4 ( g ) ⇌ 2 NO 2 ( g ) is to be stated. Concept introduction: A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

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Answer 1

Question

Chapter 18, Problem 2PE

Interpretation Introduction

(a)

Interpretation:

The direction in which equilibrium will shift on adding N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(b)

Interpretation:

The direction in which equilibrium will shift on removal of N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(c)

Interpretation:

The direction in which equilibrium will shift on adding NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(d)

Interpretation:

The direction in which equilibrium will shift on removal of NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

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(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):

(c) SOCI Best Lewis Structure 2 e group arrangement: shape/molecular geometry:_ (d) PCls Best Lewis Structure polarity: e group geometry:_ shape/molecular geometry:_ (e) Ba(BrO2): Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):

Answer 2

Question

Chapter 18, Problem 2PE

Interpretation Introduction

(a)

Interpretation:

The direction in which equilibrium will shift on adding N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(b)

Interpretation:

The direction in which equilibrium will shift on removal of N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(c)

Interpretation:

The direction in which equilibrium will shift on adding NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(d)

Interpretation:

The direction in which equilibrium will shift on removal of NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

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See solution

Answer 3

Question

Chapter 18, Problem 2PE

Interpretation Introduction

(a)

Interpretation:

The direction in which equilibrium will shift on adding N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(b)

Interpretation:

The direction in which equilibrium will shift on removal of N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(c)

Interpretation:

The direction in which equilibrium will shift on adding NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(d)

Interpretation:

The direction in which equilibrium will shift on removal of NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

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Answer 4

Question

Chapter 18, Problem 2PE

Interpretation Introduction

(a)

Interpretation:

The direction in which equilibrium will shift on adding N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(b)

Interpretation:

The direction in which equilibrium will shift on removal of N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(c)

Interpretation:

The direction in which equilibrium will shift on adding NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(d)

Interpretation:

The direction in which equilibrium will shift on removal of NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

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Answer 5

Chapter 18, Problem 2PE

Interpretation Introduction

(a)

Interpretation:

The direction in which equilibrium will shift on adding N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(b)

Interpretation:

The direction in which equilibrium will shift on removal of N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(c)

Interpretation:

The direction in which equilibrium will shift on adding NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Interpretation Introduction

(d)

Interpretation:

The direction in which equilibrium will shift on removal of NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Answer 6

Chapter 18, Problem 2PE

Interpretation Introduction

(a)

Interpretation:

The direction in which equilibrium will shift on adding N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Answer 7

Chapter 18, Problem 2PE

Interpretation Introduction

(a)

Interpretation:

The direction in which equilibrium will shift on adding N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The direction in which equilibrium will shift on removal of N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The direction in which equilibrium will shift on removal of N2O4 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The direction in which equilibrium will shift on adding NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The direction in which equilibrium will shift on adding NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The direction in which equilibrium will shift on removal of NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The direction in which equilibrium will shift on removal of NO2 for the equilibrium system N2O4(g)⇌2NO2(g) is to be stated.

Concept introduction:

A reaction is said to be in equilibrium if the rate at which the forward reaction takes place becomes equal to the rate at which the backward reaction takes place. If any of the factors that affect the equilibrium changes, then the reaction shifts in either forward or backward direction so that the equilibrium condition is reestablished.

Answer 14

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Answer 15

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Answer 17

Ch. 18 - Prob. 1E Ch. 18 - Prob. 2E Ch. 18 - Prob. 3E Ch. 18 - Prob. 4E Ch. 18 - Prob. 5E Ch. 18 - Prob. 6E Ch. 18 - Prob. 7E Ch. 18 - Prob. 8E Ch. 18 - Prob. 9E Ch. 18 - Prob. 10E

Solution Summary: The author explains the Le Chatelier's principle that the change in concentration, volume, pressure, and temperature affects the equilibrium of the reaction.

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