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Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134302386
Author: Nivaldo J. Tro
Publisher: PEARSON
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Question
Chapter 18, Problem 24E
Interpretation Introduction
Interpretation:
The examples and uses of common ethers.
Concept introduction:
The ethers are the organic compounds that contain an ether group, in which an oxygen atom is connected to two groups that can be alkyl groups or the aryl groups.
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Students have asked these similar questions
redraw the flowchart with boxes and molecules written in them
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Chapter 18 Solutions
Introductory Chemistry (6th Edition)
Ch. 18 - Prob. 1SAQCh. 18 - Q2. What is the correct formula for the alkane...Ch. 18 - Which structure is not an isomer of...Ch. 18 - Prob. 4SAQCh. 18 - Prob. 5SAQCh. 18 - Name the compound. a. 2-methyI-3-pentene b....Ch. 18 - Prob. 7SAQCh. 18 - Prob. 8SAQCh. 18 - Prob. 9SAQCh. 18 - Prob. 10SAQ
Ch. 18 - Prob. 1ECh. 18 - Prob. 2ECh. 18 - Prob. 3ECh. 18 - 4. What is vitalism? How was vitalism usurped?
Ch. 18 - Prob. 5ECh. 18 - Prob. 6ECh. 18 - Prob. 7ECh. 18 - Prob. 8ECh. 18 - Prob. 9ECh. 18 - Prob. 10ECh. 18 - 11. Explain the difference between n-alkanes and...Ch. 18 - Prob. 12ECh. 18 - Prob. 13ECh. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 - What are alkane substitution reactions? Provide an...Ch. 18 - 17. What is an alkene addition reaction? Provide...Ch. 18 - Prob. 18ECh. 18 - Prob. 19ECh. 18 - Prob. 20ECh. 18 - 21. What is the generic structure of alcohols?...Ch. 18 - Prob. 22ECh. 18 - Prob. 23ECh. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Prob. 33ECh. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Prob. 43ECh. 18 - Name each alkane.Ch. 18 - Prob. 45ECh. 18 - 46. Draw a structure for each alkane.
...Ch. 18 - Determine what is wrong with the name of each...Ch. 18 - Determine what is wrong with the name of each...Ch. 18 - Prob. 49ECh. 18 - Prob. 50ECh. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - 56. Name each alkane.
Ch. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - 60. Provide correct structures for each compound.
...Ch. 18 - Prob. 61ECh. 18 - Prob. 62ECh. 18 - Prob. 63ECh. 18 - Complete the table.Ch. 18 - Prob. 65ECh. 18 - Prob. 66ECh. 18 - Prob. 67ECh. 18 - Prob. 68ECh. 18 - What are the products of this alkene addition...Ch. 18 - Prob. 70ECh. 18 - Prob. 71ECh. 18 - Prob. 72ECh. 18 - Prob. 73ECh. 18 - Prob. 74ECh. 18 - Name each monosubstituted benzene.Ch. 18 - Prob. 76ECh. 18 - Prob. 77ECh. 18 - Prob. 78ECh. 18 - Prob. 79ECh. 18 - Prob. 80ECh. 18 - Prob. 81ECh. 18 - Prob. 82ECh. 18 - Based on its functional group, match the structure...Ch. 18 - Prob. 84ECh. 18 - Prob. 85ECh. 18 - Prob. 86ECh. 18 - Prob. 87ECh. 18 - Prob. 88ECh. 18 - Prob. 89ECh. 18 - Draw a structure for each alcohol. a. 1-hexanol b....Ch. 18 - Prob. 91ECh. 18 - Prob. 92ECh. 18 - Prob. 93ECh. 18 - For each compound, provide a name if the structure...Ch. 18 - Prob. 95ECh. 18 - Prob. 96ECh. 18 - Prob. 97ECh. 18 - Prob. 98ECh. 18 - Prob. 99ECh. 18 - Prob. 100ECh. 18 - Prob. 101ECh. 18 - Prob. 102ECh. 18 - Identify each organic compound as an alkane,...Ch. 18 - Prob. 104ECh. 18 - 105. Name each compound.
Ch. 18 - Name each compound.Ch. 18 - Prob. 107ECh. 18 - Prob. 108ECh. 18 - Prob. 109ECh. 18 - Prob. 110ECh. 18 - Prob. 111ECh. 18 - How many kilograms of CO2 are produced by the...Ch. 18 - Prob. 113ECh. 18 - Prob. 114ECh. 18 - Prob. 115ECh. 18 - Prob. 116ECh. 18 - Using complete sentences, compare and contrast...Ch. 18 - The octane rating for gasoline is a measurement of...Ch. 18 - Prob. 120QGWCh. 18 - Prob. 121DIA
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