Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134414232
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Textbook Question
Chapter 18, Problem 23E
Do the reactions involved in ozone depletion involve changes in oxidation state of the O atoms? Explain.
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Q6: Using acetic acid as the acid, write the balanced chemical equation for the protonation of
the two bases shown (on the -NH2). Include curved arrows to show the mechanism.
O₂N-
O₂N.
-NH2
-NH2
a) Which of the two Bronsted bases above is the stronger base? Why?
b) Identify the conjugate acids and conjugate bases for the reactants.
c) Identify the Lewis acids and bases in the reactions.
Q5: For the two reactions below:
a) Use curved electron-pushing arrows to show the mechanism for the reaction in the
forward direction. Redraw the compounds to explicitly illustrate all bonds that are broken
and all bonds that are formed.
b) Label Bronsted acids and bases in the left side of the reactions.
c) For reaction A, which anionic species is the weakest base? Which neutral compound is
the stronger acid? Is the forward or reverse reaction favored?
d) Label Lewis acids and bases, nucleophiles and electrophiles in the left side of the
reactions.
A.
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CH3OH
я хон
CH3O
OH
B. HBr
CH3ONa
NaBr
CH3OH
potential energy
Br
b) Translate the Newman projection below to its wedge-and-dash drawing.
F
H.
OH
CH3
CI
c) Isopentane (2-methylbutane) is a compound containing a branched carbon chain. Draw
a Newman projection of six conformations about the C2-C3 bond of isopentane. On the
curve of potential energy versus angle of internal rotation for isopentane, label each
energy maximum and minimum with one of the conformations.
0°
。
F
A
B
D
C
angle of internal rotation
E
F
360° (=0°)
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Chapter 18 Solutions
Chemistry: The Central Science (14th Edition)
Ch. 18.1 - Prob. 18.1.1PECh. 18.1 - Prob. 18.1.2PECh. 18.1 - Prob. 18.2.1PECh. 18.1 - Practice Exercise 2 The bond energy in N2 is 941...Ch. 18.2 - Prob. 18.3.1PECh. 18.2 - Prob. 18.3.2PECh. 18 - Prob. 1DECh. 18 - Prob. 1ECh. 18 - Prob. 2ECh. 18 - The figure shows the three lowest regions of...
Ch. 18 - Prob. 4ECh. 18 - Where does the energy come from to evaporate the...Ch. 18 - Prob. 6ECh. 18 - Prob. 7ECh. 18 - The first stage of treatment at the reverse...Ch. 18 - Prob. 9ECh. 18 - Prob. 10ECh. 18 - Prob. 11ECh. 18 - How are the boundaries between the regions of the...Ch. 18 - Air pollution in the Mexico City metropolitan area...Ch. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 - Prob. 16ECh. 18 - Prob. 17ECh. 18 - Prob. 18ECh. 18 - Distinguish between photodissociation and...Ch. 18 - Prob. 20ECh. 18 - Prob. 21ECh. 18 - Prob. 22ECh. 18 - Do the reactions involved in ozone depletion...Ch. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Alcohol-based fuels for automobiles lead to the...Ch. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Although there are many ions in seawater, the...Ch. 18 - The Ogallala aquifer described in the Close Look...Ch. 18 - Prob. 45ECh. 18 - Prob. 46ECh. 18 - List the common products formed when an organic...Ch. 18 - Prob. 48ECh. 18 - Prob. 49ECh. 18 - Prob. 50ECh. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - Prob. 56ECh. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - Prob. 60ECh. 18 - Prob. 61AECh. 18 - Prob. 62AECh. 18 - Prob. 63AECh. 18 - Prob. 64AECh. 18 - Prob. 65AECh. 18 - Prob. 66AECh. 18 - Prob. 67AECh. 18 - Explain, using Le Châtelier’s principle, why the...Ch. 18 - Prob. 69AECh. 18 - Prob. 70AECh. 18 - Prob. 71AECh. 18 - Prob. 72AECh. 18 - Prob. 73AECh. 18 - Prob. 74AECh. 18 - Prob. 75AECh. 18 - Prob. 76AECh. 18 - Prob. 77AECh. 18 - Prob. 78IECh. 18 - Prob. 79IECh. 18 - Prob. 80IECh. 18 - Prob. 81IECh. 18 - Prob. 82IECh. 18 - Prob. 83IECh. 18 - Prob. 84IECh. 18 - 18.85 The main reason that distillation is a...Ch. 18 - Prob. 86IECh. 18 - Prob. 87IECh. 18 - Prob. 88IECh. 18 - Prob. 89IECh. 18 - Prob. 90IECh. 18 - Prob. 91IECh. 18 - Prob. 92IE
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- Q7: Identify the functional groups in these molecules a) CH 3 b) Aspirin: HO 'N' Capsaicin HO O CH3 CH 3arrow_forwardQ2: Name the following alkanesarrow_forward1. Complete the following table in your laboratory notebook. Substance Formula Methanol CH3OH Ethanol C2H5OH 1-Propanol C3H7OH 1-Butanol C4H9OH Pentane C5H12 Hexane C6H14 Water H₂O Acetone C3H60 Structural Formula Molecular Weight (g/mol) Hydrogen Bond (Yes or No)arrow_forward
- Q1: Compare the relative acidity in each pair of compounds. Briefly explain. (a) CH3OH vs NH 3 (b) HF vs CH3COOH (c) NH3 vs CH4 (d) HCI vs HI (e) CH3COOH vs CH3SH (f) H₂C=CH2 vs CH3 CH3 (g) compare the acidity of the two bolded hydrogens O. H N- (h) compare the acidity of the two bolded hydrogens, draw resonance structures to explain H H Harrow_forwardQ3: Rank the following molecules in order of decreasing boiling point: (a) 3-methylheptane; (b) octane; (c) 2,4-dimethylhexane; (d) 2,2,4-trimethylpentane.arrow_forwardQ5: Conformations of Alkanes a) Draw a Newman Projection of the compound below about the C2-C3 bond. H3C Cli... H IIIH Br CH3arrow_forward
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