Chemistry: The Central Science (14th Edition)
14th Edition
ISBN: 9780134414232
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Chapter 18, Problem 56E
Interpretation Introduction
To determine: The way by which a catalyst can make a process more energy efficient.
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The complex anion in Ba₂[Cr(CN)6] is a tetragonally distorted octahedral complex (Dan). Baz[Cr(CN)6] is
paramagnetic at room temperature with S = 1. Assume that the complex is a low-spin complex.
a) Identify if the [Cr(CN)6] anionic complex has 4 long and
2 short bonds (left side of figure) or if the complex has 4
short and 2 long bonds (right side of figure) with respect
to Oh symmetry. Use crystal field theory to answer this
question. Explain/rationalize your decision. Can the
provided information decide on the order of orbital
energies?
Dah
Tetragonal Distortion
ய
Dab
z-compression
z-elongation
x and y elongation
O symmetry
x and y compression
E
eg d² dx²-y²
t2g
dxy dxz dyz
Question 4 a) continued:
Provide your explanations in the space below.
b) At low temperatures Ba₂[Cr(CN)6] is ferromagnetically ordered with a phase transition to a paramagnetic
phase at Tc = 150K. Sketch the magnetic susceptibility vs. temperature in the diagram below. Indicate Tc
as well as the paramagnetic and…
a) Draw the octahedral mer-[FeCl3(CN)3] complex and determine its point group. Use proper wedges and
dashes in order to illustrate 3 dimensional details. Use the point group to determine if the complex has a
resulting net dipole moment and describe its allowed direction with respect to its symmetry elements (if
applicable).
ード
M
4-
b) Substitute one chlorido ligand in mer-[FeCl3(CN)3] 4 with one fluorido ligand. Determine all possible
isomers and their corresponding point groups. Use the point groups to determine if the complexes have
resulting net dipole moments and describe their allowed direction with respect to its symmetry elements (if
applicable). The number of complex sketches below is not necessarily indicative of the number of isomers.
4-
4-
☐☐☐
c) Substitute two chlorido ligands in mer-[FeCl3 (CN)3] 4 with two fluorido ligands. Determine all possible
isomers and their corresponding point groups.. Use the point groups to determine if the complexes have
resulting net dipole…
Show work. don't give Ai generated solution
Chapter 18 Solutions
Chemistry: The Central Science (14th Edition)
Ch. 18.1 - Prob. 18.1.1PECh. 18.1 - Prob. 18.1.2PECh. 18.1 - Prob. 18.2.1PECh. 18.1 - Practice Exercise 2 The bond energy in N2 is 941...Ch. 18.2 - Prob. 18.3.1PECh. 18.2 - Prob. 18.3.2PECh. 18 - Prob. 1DECh. 18 - Prob. 1ECh. 18 - Prob. 2ECh. 18 - The figure shows the three lowest regions of...
Ch. 18 - Prob. 4ECh. 18 - Where does the energy come from to evaporate the...Ch. 18 - Prob. 6ECh. 18 - Prob. 7ECh. 18 - The first stage of treatment at the reverse...Ch. 18 - Prob. 9ECh. 18 - Prob. 10ECh. 18 - Prob. 11ECh. 18 - How are the boundaries between the regions of the...Ch. 18 - Air pollution in the Mexico City metropolitan area...Ch. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 - Prob. 16ECh. 18 - Prob. 17ECh. 18 - Prob. 18ECh. 18 - Distinguish between photodissociation and...Ch. 18 - Prob. 20ECh. 18 - Prob. 21ECh. 18 - Prob. 22ECh. 18 - Do the reactions involved in ozone depletion...Ch. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Alcohol-based fuels for automobiles lead to the...Ch. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Although there are many ions in seawater, the...Ch. 18 - The Ogallala aquifer described in the Close Look...Ch. 18 - Prob. 45ECh. 18 - Prob. 46ECh. 18 - List the common products formed when an organic...Ch. 18 - Prob. 48ECh. 18 - Prob. 49ECh. 18 - Prob. 50ECh. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - Prob. 56ECh. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - Prob. 60ECh. 18 - Prob. 61AECh. 18 - Prob. 62AECh. 18 - Prob. 63AECh. 18 - Prob. 64AECh. 18 - Prob. 65AECh. 18 - Prob. 66AECh. 18 - Prob. 67AECh. 18 - Explain, using Le Châtelier’s principle, why the...Ch. 18 - Prob. 69AECh. 18 - Prob. 70AECh. 18 - Prob. 71AECh. 18 - Prob. 72AECh. 18 - Prob. 73AECh. 18 - Prob. 74AECh. 18 - Prob. 75AECh. 18 - Prob. 76AECh. 18 - Prob. 77AECh. 18 - Prob. 78IECh. 18 - Prob. 79IECh. 18 - Prob. 80IECh. 18 - Prob. 81IECh. 18 - Prob. 82IECh. 18 - Prob. 83IECh. 18 - Prob. 84IECh. 18 - 18.85 The main reason that distillation is a...Ch. 18 - Prob. 86IECh. 18 - Prob. 87IECh. 18 - Prob. 88IECh. 18 - Prob. 89IECh. 18 - Prob. 90IECh. 18 - Prob. 91IECh. 18 - Prob. 92IE
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