Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 18, Problem 22E
Interpretation Introduction

Interpretation:

The age of the artifact, when carbon -14 radioactivity of an ancient wooden artifact is 6.25% that of a reference sample is to be estimated.

Concept introduction:

For all the radioactive samples, the level of radioactivity decreases with time. For the activity of the sample, the amount of time that is required to reduce it by half is known as the half life. The half-life is represented by the symbol t1/2.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³
fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

Chapter 18 Solutions

Introductory Chemistry: Concepts and Critical Thinking (8th Edition)

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