(a) Interpretation: The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined. Concept introduction: Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.82P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

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14 Question (1 point) Disiamylborane adds to a triple bond to give an alkenylborane. Upon oxidation with OH, H2O2, the alkenylborane will form an enol that tautomerizes to an aldehyde. In the first box below, draw the mechanism arrows for the reaction of disiamylborane with the alkyne, and in the last box draw the structure of the aldehyde. 4th attempt Feedback i > 3rd attempt OH, H2O2 i See Periodic Table See Hint

answer with mechanisms and steps. handwritten please!

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.82P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Expert Solution & Answer

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.82P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Expert Solution & Answer

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.82P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Expert Solution & Answer

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Answer 5

Chapter 18, Problem 18.82P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Answer 6

Chapter 18, Problem 18.82P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Answer 7

Chapter 18, Problem 18.82P

Interpretation Introduction

(a)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The complete, detailed mechanism for the given reaction is to be drawn and the major product of the given reaction is to be determined.

Concept introduction:

Enamines are inherently less reactive than their enolate ion analogs, it is necessary to treat them with highly reactive alkylating agents in order to effect a reaction. Enamines are not as nucleophilic as their enolate ion equivalents.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

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Chapter 18 Solutions