(a) Interpretation: The number of stereogenic centers present in the product is to be determined. Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

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Answer 1

Question

Chapter 18, Problem 18.57P

Interpretation Introduction

(a)

Interpretation: The number of stereogenic centers present in the product is to be determined.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The product formed from the given reaction exhibit optical activity or not is to be predicted and explained.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

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5. Butylated hydroxy toluene (BHT) is an anti-oxidant added to many food products (e.g. breakfast cereals) to increase their shelf-life. BHT is synthesized from p-cresol by reaction with 2-methylpropene in the presence of phosphoric acid. a) What is the structure of BHT ? b) Account for the regioselectivity of tert-butyl group substitution in the synthesis of BHT. c) Propose a mechanism to explain the formation of the electrophile in the synthesis of BHT.

6. What is the product of the following reaction? .CI L2Pd CH:-B NaOH

Draw the structures of the products obtained from the reaction of each enantiomer of cis-1-chloro-2-isopropylcyclopentane with sodium methoxide in methanol. b. Are all the products optically active? c. How would the products differ if the starting material were the trans isomer? Are these products optically active? d. Will the cis enantiomers or the trans enantiomers form substitution products more rapidly? e. Will the cis enantiomers or the trans enantiomers form elimination products more rapidly?

Answer 2

Question

Chapter 18, Problem 18.57P

Interpretation Introduction

(a)

Interpretation: The number of stereogenic centers present in the product is to be determined.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The product formed from the given reaction exhibit optical activity or not is to be predicted and explained.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

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Answer 3

Question

Chapter 18, Problem 18.57P

Interpretation Introduction

(a)

Interpretation: The number of stereogenic centers present in the product is to be determined.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The product formed from the given reaction exhibit optical activity or not is to be predicted and explained.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

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Answer 4

Question

Chapter 18, Problem 18.57P

Interpretation Introduction

(a)

Interpretation: The number of stereogenic centers present in the product is to be determined.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The product formed from the given reaction exhibit optical activity or not is to be predicted and explained.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

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Answer 5

Chapter 18, Problem 18.57P

Interpretation Introduction

(a)

Interpretation: The number of stereogenic centers present in the product is to be determined.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Interpretation Introduction

(b)

Interpretation: The product formed from the given reaction exhibit optical activity or not is to be predicted and explained.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 6

Chapter 18, Problem 18.57P

Interpretation Introduction

(a)

Interpretation: The number of stereogenic centers present in the product is to be determined.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Answer 7

Chapter 18, Problem 18.57P

Interpretation Introduction

(a)

Interpretation: The number of stereogenic centers present in the product is to be determined.

Concept introduction: A carbon atom which is bonded to four different groups is termed as chiral center or stereogenic center. The groups around the stereogenic center are prioritized on the basis of atomic number of their atoms in order to find the configuration of compound.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product formed from the given reaction exhibit optical activity or not is to be predicted and explained.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product formed from the given reaction exhibit optical activity or not is to be predicted and explained.

Concept introduction: The replacement or substitution of one functional group with another different functional group in any chemical reaction is termed as substitution reaction. The electron deficient chemical species that contains positive charge are known as electrophile. In electrophilic aromatic substitution reaction, electrophile takes the position of hydrogen atom by attacking the electron rich carbon atom of benzene.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Problem 18.9 Draw the product of each reaction a....Ch. 18 - Prob. 18.10P

Solution Summary: The author explains the Friedel-Crafts alkylation reaction of benzene with ( R )- 2 -chlorobutane and AlCl

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Chapter 18 Solutions