(a)
Interpretation:
Given reaction has to be draw completed.
Concept Introduction:
Acid anhydride can react with water, alcohol and
Amine, water and alcohol acts as a nucleophile and gets attached to the carbonyl carbon of the acid anhydride. The base takes the proton from the from the tetrahedral intermediate. The carboxylate ion gets eliminated from the tetrahedral intermediate to form carboxylic acid derivative.
(b)
Interpretation:
Given reaction has to be completed.
Concept Introduction:
Reaction of acid chloride with ammonia or amines:
The reaction of acid chlorides with ammonia and primary and secondary amines will yield amide.
The nucleophilic addition of ammonia or amine to the carbonyl carbon occurs which is followed by a proton transfer forming an addition intermediate that will eliminate chloride and lose a proton to give the amide compound.
(c)
Interpretation:
Given reaction has to be draw and completed.
Concept Introduction:
Reaction of an ester with ammonia or an amine:
Treatment of an ester with ammonia or a primary or secondary amine gives an amide.
The nucleophilic addition of the ammonia or amine to the carbonyl carbon occurs followed by a proton transfer and a tetrahedral addition intermediate is formed. The intermediate can directly alkoxide and lose a proton to the alkoxide to give products.
(d)
Interpretation:
Given reaction has to be draw and completed.
Concept Introduction:
Reaction of an ester with ammonia or an amine:
Treatment of an ester with ammonia or a primary or secondary amine gives an amide.
The nucleophilic addition of the ammonia or amine to the carbonyl carbon occurs followed by a proton transfer and a tetrahedral addition intermediate is formed. The intermediate can directly alkoxide and lose a proton to the alkoxide to give products.
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Chapter 18 Solutions
EP ORGANIC CHEMISTRY-OWL V2 ACCESS
- Fructose, present with glucose in honey, reacts with Benedicts reagent. Circle the structural features that enable fructose to react.arrow_forwardPlease complete the reactionsarrow_forward1. Alkene A is ___ stable than alkene B and will release ___ energy when it is hydrogenated to form 2,5-dimethylheptane.arrow_forward
- Name each aldehyde or ketone. CH, CH, c. CH3-C-CH-CH-CH-C-H ČH,arrow_forwardb). Use ethanol as the only ORGANIC carbon cource, along with any needed reagents to make 4-methylhexan-3-one 4-methylhexan-3-onearrow_forward1. Which functional group is found in aldehydes? a. CHO b. -CH;OH c. -COOH d. RCOR' 2. Which functional group is found in ketones? a. -CHO CH:OH c. -COOH RCOR' 3. Which structural feature is common to aldehydes and ketones? a, an oxygen atom bonded to both a carbon atom and a hydrogen atom b. an oxygen atom bonded to two carbon atoms c. an oxygen atom double bonded to a carbon atom d. two oxygen atoms bonded to the same carbon atom 4. What is the IUPAC name for the following compound? a. I-pentaldehyde b. l-pentanal c. pentanal d. pentanealdehyde Cetoa of Fiarrow_forward
- 6. Draw the following compounds. a. 2-pentanol b. ethylpropylamine c. methyl propyl ether d. butyl propyl ketone abayoqtheo ghidollo WHO H3--3 HO HO HO HO HOarrow_forward1. Give the product of this reaction A. Propanal B. Propanol C. Propan-2-olD. Acetic acid E. Propanoic acidarrow_forward1. Classify the molecule shown according to the location of its carbonyl group and the number of carbon atoms. CH₂OH C=O PIL a. Aldotriose b. Aldotetrose Aldopentose d., Ketotriose Ketotetrose HO-C-H L CH₂OHarrow_forward
- Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
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