Introductory Chemistry (6th Edition)
6th Edition
ISBN: 9780134554525
Author: Tro
Publisher: PEARSON
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Chapter 18, Problem 104E
Interpretation Introduction
Interpretation: Each organic compound is to be identified as an
Concept introduction: Organic compounds which contains a benzene ring in their structure are called
Esters are the organic compounds which contains
Alcohols are the organic compounds which contains
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 18 Solutions
Introductory Chemistry (6th Edition)
Ch. 18 - Prob. 1SAQCh. 18 - Q2. What is the correct formula for the alkane...Ch. 18 - Which structure is not an isomer of...Ch. 18 - Prob. 4SAQCh. 18 - Prob. 5SAQCh. 18 - Name the compound. a. 2-methyI-3-pentene b....Ch. 18 - Prob. 7SAQCh. 18 - Prob. 8SAQCh. 18 - Prob. 9SAQCh. 18 - Prob. 10SAQ
Ch. 18 - Prob. 1ECh. 18 - Prob. 2ECh. 18 - Prob. 3ECh. 18 - 4. What is vitalism? How was vitalism usurped?
Ch. 18 - Prob. 5ECh. 18 - Prob. 6ECh. 18 - Prob. 7ECh. 18 - Prob. 8ECh. 18 - Prob. 9ECh. 18 - Prob. 10ECh. 18 - 11. Explain the difference between n-alkanes and...Ch. 18 - Prob. 12ECh. 18 - Prob. 13ECh. 18 - Prob. 14ECh. 18 - Prob. 15ECh. 18 - What are alkane substitution reactions? Provide an...Ch. 18 - 17. What is an alkene addition reaction? Provide...Ch. 18 - Prob. 18ECh. 18 - Prob. 19ECh. 18 - Prob. 20ECh. 18 - 21. What is the generic structure of alcohols?...Ch. 18 - Prob. 22ECh. 18 - Prob. 23ECh. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Prob. 27ECh. 18 - Prob. 28ECh. 18 - Prob. 29ECh. 18 - Prob. 30ECh. 18 - Prob. 31ECh. 18 - Prob. 32ECh. 18 - Prob. 33ECh. 18 - Prob. 34ECh. 18 - Prob. 35ECh. 18 - Prob. 36ECh. 18 - Prob. 37ECh. 18 - Prob. 38ECh. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Prob. 41ECh. 18 - Prob. 42ECh. 18 - Prob. 43ECh. 18 - Name each alkane.Ch. 18 - Prob. 45ECh. 18 - 46. Draw a structure for each alkane.
...Ch. 18 - Determine what is wrong with the name of each...Ch. 18 - Determine what is wrong with the name of each...Ch. 18 - Prob. 49ECh. 18 - Prob. 50ECh. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - Prob. 53ECh. 18 - Prob. 54ECh. 18 - Prob. 55ECh. 18 - 56. Name each alkane.
Ch. 18 - Prob. 57ECh. 18 - Prob. 58ECh. 18 - Prob. 59ECh. 18 - 60. Provide correct structures for each compound.
...Ch. 18 - Prob. 61ECh. 18 - Prob. 62ECh. 18 - Prob. 63ECh. 18 - Complete the table.Ch. 18 - Prob. 65ECh. 18 - Prob. 66ECh. 18 - Prob. 67ECh. 18 - Prob. 68ECh. 18 - What are the products of this alkene addition...Ch. 18 - Prob. 70ECh. 18 - Prob. 71ECh. 18 - Prob. 72ECh. 18 - Prob. 73ECh. 18 - Prob. 74ECh. 18 - Name each monosubstituted benzene.Ch. 18 - Prob. 76ECh. 18 - Prob. 77ECh. 18 - Prob. 78ECh. 18 - Prob. 79ECh. 18 - Prob. 80ECh. 18 - Prob. 81ECh. 18 - Prob. 82ECh. 18 - Based on its functional group, match the structure...Ch. 18 - Prob. 84ECh. 18 - Prob. 85ECh. 18 - Prob. 86ECh. 18 - Prob. 87ECh. 18 - Prob. 88ECh. 18 - Prob. 89ECh. 18 - Draw a structure for each alcohol. a. 1-hexanol b....Ch. 18 - Prob. 91ECh. 18 - Prob. 92ECh. 18 - Prob. 93ECh. 18 - For each compound, provide a name if the structure...Ch. 18 - Prob. 95ECh. 18 - Prob. 96ECh. 18 - Prob. 97ECh. 18 - Prob. 98ECh. 18 - Prob. 99ECh. 18 - Prob. 100ECh. 18 - Prob. 101ECh. 18 - Prob. 102ECh. 18 - Identify each organic compound as an alkane,...Ch. 18 - Prob. 104ECh. 18 - 105. Name each compound.
Ch. 18 - Name each compound.Ch. 18 - Prob. 107ECh. 18 - Prob. 108ECh. 18 - Prob. 109ECh. 18 - Prob. 110ECh. 18 - Prob. 111ECh. 18 - How many kilograms of CO2 are produced by the...Ch. 18 - Prob. 113ECh. 18 - Prob. 114ECh. 18 - Prob. 115ECh. 18 - Prob. 116ECh. 18 - Using complete sentences, compare and contrast...Ch. 18 - The octane rating for gasoline is a measurement of...Ch. 18 - Prob. 120QGWCh. 18 - Prob. 121DIA
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