It should be accounted for the observation that the given β − k e t o a c i d can be heated for the extended periods at temperature above its melting point without noticeable decarboxylation. Concept introduction: Carboxylic acids contain a carbonyl attached to a hydroxyl group as shown below, If carboxylic acid is heated to a very high temperature then of carbon dioxide will be eliminated from it this reaction is known as decarboxylation . Simple carboxylic acids do not decarboxylate readily. Decarboxylation of β − k e t o a c i d is shown below, The mechanism of thermal decarboxylation involves two processes, (i) Redistribution of electrons in a cyclic transition state. (ii) Cyclic transition state possesses keto-enol tautomerism.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17.9, Problem 17.6P

Interpretation Introduction

Interpretation: It should be accounted for the observation that the given β−ketoacid can be heated for the extended periods at temperature above its melting point without noticeable decarboxylation.

Concept introduction:

Carboxylic acids contain a carbonyl attached to a hydroxyl group as shown below,

If carboxylic acid is heated to a very high temperature then of carbon dioxide will be eliminated from it this reaction is known as decarboxylation. Simple carboxylic acids do not decarboxylate readily.

Decarboxylation of β−ketoacid is shown below,

The mechanism of thermal decarboxylation involves two processes,

(i) Redistribution of electrons in a cyclic transition state.

(ii) Cyclic transition state possesses keto-enol tautomerism.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Draw the major products of this SN1 reaction. Ignore any inorganic byproducts.

Draw the major elimination and substitution products formed in this reaction. Use a dash or wedge bond to indicate the stereochemistry of substituents on asymmetric centers, wehre applicable. Ignore and inorganic byproducts.

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Drawing Arrows THE Problem 33 of 35 N. C:0 Na + Submit Drag To Pan +

Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17.9, Problem 17.6P

Interpretation Introduction

Interpretation: It should be accounted for the observation that the given β−ketoacid can be heated for the extended periods at temperature above its melting point without noticeable decarboxylation.

Concept introduction:

Carboxylic acids contain a carbonyl attached to a hydroxyl group as shown below,

If carboxylic acid is heated to a very high temperature then of carbon dioxide will be eliminated from it this reaction is known as decarboxylation. Simple carboxylic acids do not decarboxylate readily.

Decarboxylation of β−ketoacid is shown below,

The mechanism of thermal decarboxylation involves two processes,

(i) Redistribution of electrons in a cyclic transition state.

(ii) Cyclic transition state possesses keto-enol tautomerism.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17.9, Problem 17.6P

Interpretation Introduction

Interpretation: It should be accounted for the observation that the given β−ketoacid can be heated for the extended periods at temperature above its melting point without noticeable decarboxylation.

Concept introduction:

Carboxylic acids contain a carbonyl attached to a hydroxyl group as shown below,

If carboxylic acid is heated to a very high temperature then of carbon dioxide will be eliminated from it this reaction is known as decarboxylation. Simple carboxylic acids do not decarboxylate readily.

Decarboxylation of β−ketoacid is shown below,

The mechanism of thermal decarboxylation involves two processes,

(i) Redistribution of electrons in a cyclic transition state.

(ii) Cyclic transition state possesses keto-enol tautomerism.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 17.9, Problem 17.6P

Interpretation Introduction