Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 17.7, Problem 17CC
Interpretation Introduction

Interpretation:

The more reactive diene for a Diels-Alder reaction in the given two isomers of 2,4-hexadiene should be identified with explanation.

Concept introduction:

  • Diels-Alder reaction is a [4+2] cycloaddition reaction, in which a π-system having four atoms (diene) and a π-system having two atoms (dienophile) are undergoing in cycloaddition reaction and producing a substituted cyclohexene.
  • Only the diene in s-cis conformation will undergo Diels-Alder reaction with dienophile.
  • The more steric hindrance in the dienes will be less reactive for the Diels-Alder reaction.

To determine: the more reactive diene for a Diels-Alder reaction in the given two isomers of 2,4-hexadiene .

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Please answer 1, 2 and 3 on the end
In the box below, specify which of the given compounds are very soluble in polar aprotic solvents. You may select more than one compound. Choose one or more: NaCl NH4Cl CH3CH2CH2CH2CH2CN CH3CH2OH hexan-2-one NaOH CH3SCH3
On the following structure, select all of the atoms that could ACCEPT a hydrogen bond. Ignore possible complications of aromaticity. When selecting be sure to click on the center of the atom.

Chapter 17 Solutions

Organic Chemistry, Binder Ready Version

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