Organic Chemistry, Binder Ready Version
Organic Chemistry, Binder Ready Version
2nd Edition
ISBN: 9781118454312
Author: David R. Klein
Publisher: WILEY
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Chapter 17.2, Problem 5CC
Interpretation Introduction

Interpretation:

For the given compounds, the most stable compound should be identified.

Concept introduction:

The compounds having two C=C π bonds are called dienes.

Based on the proximity of C=C bonds in dienes, they are classified into three.

  • Cumulated dienes: the C=C bonds are located adjacent carbons.
  • Conjugated dienes: the C=C bonds or C=C and C=O are separated by one σ-bond.
  • Isolated dienes: the C=C bonds are separated by two or more σ-bonds.

The conjugated dienes are more stable as compare to isolated dienes because the delocalization of π bonds is taking place, so this forms some stabilization energy in conjugated system.

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