For the each given reactions, the products and in which the predominated product are needed to be determined. Concept introduction: Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr . The allylic carbocation is formed as an intermediate by the addition of proton in the HBr . The Br − (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate. There are four carbons for addition of proton in a conjugated diene , but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr . Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same . The 1,2-adduct is kinetic product , because of the proximity of C2 carbon to attack by Br − . The 1,4-adduct is thermodynamic product , because the more substituted double bond is more stable.

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Answer 1

Question

Chapter 17.5, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(b)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(c)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

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Answer 2

Question

Chapter 17.5, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(b)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(c)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

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Answer 3

Question

Chapter 17.5, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(b)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(c)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 17.5, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(b)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(c)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 17.5, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(b)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

(c)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

Answer 6

Chapter 17.5, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

Answer 7

Chapter 17.5, Problem 10PTS

(a)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

Answer 10

(c)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

Answer 11

(c)

Interpretation Introduction

Interpretation:

For the each given reactions, the products and in which the predominated product are needed to be determined.

Concept introduction:

Conjugated Dienes undergoes addition reactions with HBr as similar to simple alkenes addition with HBr .

The allylic carbocation is formed as an intermediate by the addition of proton in the HBr .

The Br− (nucleophilic) can attacks in either of the two resonance stabilized carbocation’s in the in the allylic intermediate.

There are four carbons for addition of proton in a conjugated diene, but addition of proton at C1 and C4 carbons only form the allylic carbocation. The nucleophile can attack two positions of allylic carbocation. If it is C2 carbon, then the it is called 1,2-addition of HBr and if it is C4 carbon then it is called 1,4-addition of HBr .

Symmetrical diene like butadiene will produce only two products. Because the intermediates allylic carbocation formed are same.

The 1,2-adduct is kinetic product, because of the proximity of C2 carbon to attack by Br− .

The 1,4-adduct is thermodynamic product, because the more substituted double bond is more stable.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 17.1 - Prob. 1CC Ch. 17.2 - Prob. 2CC Ch. 17.2 - Prob. 3CC Ch. 17.2 - Prob. 4CC Ch. 17.2 - Prob. 5CC Ch. 17.3 - Prob. 6CC Ch. 17.4 - Prob. 1LTS Ch. 17.4 - Prob. 7PTS Ch. 17.4 - Prob. 8ATS Ch. 17.4 - Prob. 9ATS

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Chapter 17 Solutions