ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
2nd Edition
ISBN: 9781118872925
Author: Klein
Publisher: JOHN WILEY+SONS INC.CUSTOM
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Question
Chapter 17.2, Problem 2CC
Interpretation Introduction
Interpretation:
The reagents used for the given conversion should be identified, if cyclohexane is converting into 1,3-cyclohexadiene.
Concept introduction:
- In an Addition Reaction, the two given molecules combine and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions.
- Radical bromination reaction is an addition reaction, in which
alkane or alkene is added by bromine and forms alkyl bromide. - In an elimination reaction,
alkenes are formed whenalkyl halides are treated with bases via eliminating one proton and one halo group of the alkyl halide. - E2 reaction is a bimolecular elimination reaction in which only one step is involved and it is favored by the strong bases.
- Potassium tert-butoxide is a bulky base.
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Part V. Label ad match the carbons in compounds Jane and Diane
w/ the corresponding peak no.
in the
Spectra (Note: use the given peak no. To label the carbons, other peak
no are intentionally
omitted)
7 4 2
-0.13
-0.12
-0.11
-0.10
-0.08
8
CI
Jane
1
-0.09
5
210
200
190
180
170
160
150
140
130
120
110
100
-8
90
f1 (ppm)
11
8
172.4
172.0
f1 (ppr
HO
CI
NH
Diane
7
3
11
80
80
-80
-R
70
60
60
2
5
-8
50
40
8.
170
160
150
140
130
120
110
100
90
-0
80
70
20
f1 (ppm)
15
30
-20
20
-60
60
-0.07
-0.06
-0.05
-0.04
-0.03
-0.02
-0.01
-0.00
-0.01
10
-0.17
16
15
56
16
-0.16
-0.15
-0.14
-0.13
-0.12
-0.11
-0.10
-0.09
-0.08
-0.07
-0.06
-0.05
-0.04
17.8 17.6 17.4 17.2 17.0
f1 (ppm)
-0.03
-0.02
550
106
40
30
20
20
-0.01
-0.00
F-0.01
10
0
Chapter 17 Solutions
ORG.CHEM EBOOK W/BBWILEY PLUS>CUSTOM<
Ch. 17.1 - Prob. 1CCCh. 17.2 - Prob. 2CCCh. 17.2 - Prob. 3CCCh. 17.2 - Prob. 4CCCh. 17.2 - Prob. 5CCCh. 17.3 - Prob. 6CCCh. 17.4 - Prob. 1LTSCh. 17.4 - Prob. 7PTSCh. 17.4 - Prob. 8ATSCh. 17.4 - Prob. 9ATS
Ch. 17.5 - Prob. 2LTSCh. 17.5 - Prob. 10PTSCh. 17.5 - Prob. 11ATSCh. 17.5 - Prob. 12ATSCh. 17.5 - Prob. 13CCCh. 17.7 - Prob. 3LTSCh. 17.7 - Prob. 14PTSCh. 17.7 - Prob. 15ATSCh. 17.7 - Prob. 16ATSCh. 17.7 - Prob. 17CCCh. 17.7 - Prob. 18CCCh. 17.7 - Prob. 19CCCh. 17.8 - Prob. 20CCCh. 17.9 - Prob. 21CCCh. 17.9 - Prob. 4LTSCh. 17.9 - Prob. 22PTSCh. 17.9 - Prob. 23ATSCh. 17.9 - Prob. 24ATSCh. 17.10 - Prob. 25CCCh. 17.10 - Prob. 26CCCh. 17.10 - Prob. 27CCCh. 17.10 - Prob. 28CCCh. 17.11 - Prob. 5LTSCh. 17.11 - Prob. 29PTSCh. 17.11 - Prob. 30ATSCh. 17.12 - Prob. 31CCCh. 17 - Prob. 32PPCh. 17 - Prob. 33PPCh. 17 - Prob. 34PPCh. 17 - Prob. 35PPCh. 17 - Prob. 36PPCh. 17 - Prob. 37PPCh. 17 - Prob. 38PPCh. 17 - Prob. 39PPCh. 17 - Prob. 40PPCh. 17 - Prob. 41PPCh. 17 - Prob. 42PPCh. 17 - Prob. 43PPCh. 17 - Prob. 44PPCh. 17 - Prob. 45PPCh. 17 - Prob. 46PPCh. 17 - Prob. 47PPCh. 17 - Prob. 48PPCh. 17 - Prob. 49PPCh. 17 - Prob. 50PPCh. 17 - Prob. 51PPCh. 17 - Prob. 52PPCh. 17 - Prob. 53PPCh. 17 - Prob. 54PPCh. 17 - Prob. 55PPCh. 17 - Prob. 56PPCh. 17 - Prob. 57PPCh. 17 - Prob. 58PPCh. 17 - Prob. 59PPCh. 17 - Prob. 60IPCh. 17 - Prob. 61IPCh. 17 - Prob. 62IPCh. 17 - Prob. 63IPCh. 17 - Prob. 64IPCh. 17 - Prob. 65IPCh. 17 - Prob. 66IPCh. 17 - Prob. 67IPCh. 17 - Prob. 68IPCh. 17 - Prob. 69IP
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