Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 17.13, Problem 28P
- a. Which would have the greatest percentage of polar amino acids: a spherical protein, a cigar-shaped protein, or a subunit of a hexamer?
- b. Which would have the smallest percentage of polar amino acids?
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Chapter 17 Solutions
Essential Organic Chemistry (3rd Edition)
Ch. 17.1 - a. Explain why, when the imidazole ring of...Ch. 17.2 - Prob. 2PCh. 17.3 - Prob. 3PCh. 17.3 - Prob. 4PCh. 17.3 - Prob. 6PCh. 17.4 - Calculate the pI of each of the following amino...Ch. 17.4 - a. Which amino acid has the lowest pI value? b....Ch. 17.5 - What aldehyde is formed when valine is treated...Ch. 17.5 - Prob. 10PCh. 17.5 - Prob. 11P
Ch. 17.5 - Prob. 12PCh. 17.6 - Prob. 13PCh. 17.6 - What amino acid would be formed using the...Ch. 17.6 - What amino acid would be formed when the aldehyde...Ch. 17.7 - Pig liver esterase is an enzyme that catalyzes the...Ch. 17.8 - Prob. 17PCh. 17.8 - Prob. 18PCh. 17.8 - Prob. 19PCh. 17.8 - Prob. 20PCh. 17.10 - Prob. 21PCh. 17.10 - Prob. 22PCh. 17.10 - Why does cyanogen bromide not cleave on the C-side...Ch. 17.10 - Prob. 24PCh. 17.10 - Prob. 26PCh. 17.12 - Prob. 27PCh. 17.13 - a. Which would have the greatest percentage of...Ch. 17 - Draw the predominant form of the following amino...Ch. 17 - What is the pI of serine?Ch. 17 - Prob. 31PCh. 17 - Prob. 32PCh. 17 - Which would have a higher percentage of negative...Ch. 17 - Draw the form of aspartate that predominates at...Ch. 17 - Prob. 35PCh. 17 - A professor was preparing a manuscript for...Ch. 17 - a. Why is the pKa of the glutamate side chain...Ch. 17 - Prob. 38PCh. 17 - Determine the amino acid sequence of a polypeptide...Ch. 17 - Prob. 40PCh. 17 - Prob. 41PCh. 17 - Three peptides were obtained from a trypsin...Ch. 17 - Prob. 43PCh. 17 - After the polypeptide shown here was treated with...Ch. 17 - The disulfide bridges of a polypeptide were...Ch. 17 - -Amino acids can be prepared by treating an...Ch. 17 - Reaction of a polypeptide with carboxypeptidase A...Ch. 17 - Prob. 48PCh. 17 - Prob. 49PCh. 17 - Show how valine can be prepared by a. a Strecker...Ch. 17 - Prob. 51PCh. 17 - Why is proline never found in an -helix?Ch. 17 - Determine the amino acid sequence of a polypeptide...Ch. 17 - Prob. 55PCh. 17 - A chemist wanted to test his hypothesis that the...Ch. 17 - A normal polypeptide and a mutant of the...
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- If I have 1-bromopropene and I want to obtain (1,1-dipropoxyethyl)benzene, indicate the compound that I should add in addition to NaOH.arrow_forwardDraw the major product of this reaction. Ignore inorganic byproducts. Ο HSCH2CH2CH2SH, BF3 Select to Draw I Submitarrow_forwardFeedback (7/10) Draw the major product of this reaction. Ignore inorganic byproducts. Assume that the water side product is continuously removed to drive the reaction toward products. Incorrect, 3 attempts remaining Ο (CH3CH2)2NH, TSOH Select to Draw V N. 87% Retryarrow_forward
- If I want to obtain (1,1-dipropoxyethyl)benzene from 1-bromopropene, indicate the product that I have to add in addition to NaOH.arrow_forwardIndicate the products obtained when fluorobenzene reacts with a sulfonitric acid mixture (HNO3 + H2SO4). Indicate the majority if necessary.arrow_forwardIndicate the products obtained when chlorobenzene acid reacts with a sulfonitric acid mixture (HNO3 + H2SO4). Indicate the majority if necessary.arrow_forward
- Indicate the products obtained by reacting benzenesulfonic acid with a sulfonitric acid mixture (HNO3 + H2SO4). Indicate the majority if necessary.arrow_forwardIndicate the products obtained by reacting ethylbenzene with a sulfonitric acid mixture (HNO3 + H2SO4). Indicate the majority if necessary.arrow_forwardIndicate the products obtained when tert-butylbenzene reacts with a sulfonitric acid mixture (HNO3 + H2SO4). Indicate the majority if necessary.arrow_forward
- Indicate the products obtained when acetophenone reacts with a sulfonitric acid mixture (HNO3 + H2SO4). Indicate the majority if necessary.arrow_forwardIndicate the products obtained from the reaction of N-(4-methylphenyl)acetamide with a sulfonitric acid mixture (H2SO4 + HNO3). Indicate the majority if necessary.arrow_forwardIndicate the products obtained from the reaction of 4-(trifluoromethyl)benzonitrile with a sulfonitric mixture (H2SO4 + HNO3). Indicate the majority if necessary.arrow_forward
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