The synthesis of the given aromatic derivative, p − t e r t − butylnitrobenzene from benzene is to be predicted. Concept introduction: Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

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Answer 1

Question

Chapter 17.10, Problem 17.19P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−tert−butylnitrobenzene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−toluenesulfonic acid from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−chlorotoluene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

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In the Thermo Fisher application note about wine analysis (Lesson 3), the following chromatogram was collected of nine components of wine. If peak 3 has a retention time of 3.15 minutes and a peak width of 0.070 minutes, and peak 4 has a retention time of 3.24 minutes and a peak width of 0.075 minutes, what is the resolution factor between the two peaks? [Hint: it will help to review Lesson 2 for this question.] MAU 300 200 T 34 5 100- 1 2 CO 6 7 8 9 0 2.4 2.6 2.8 3.0 3.2 3.4 3.6 3.8 4.0 4.2 4.4 4.6 4.8 5.0 5.2 Minutes 3.22 0.62 1.04 O 1.24

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Answer 2

Question

Chapter 17.10, Problem 17.19P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−tert−butylnitrobenzene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−toluenesulfonic acid from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−chlorotoluene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

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Answer 3

Question

Chapter 17.10, Problem 17.19P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−tert−butylnitrobenzene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−toluenesulfonic acid from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−chlorotoluene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

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Answer 4

Question

Chapter 17.10, Problem 17.19P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−tert−butylnitrobenzene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−toluenesulfonic acid from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−chlorotoluene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

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Answer 5

Chapter 17.10, Problem 17.19P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−tert−butylnitrobenzene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−toluenesulfonic acid from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−chlorotoluene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 6

Chapter 17.10, Problem 17.19P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−tert−butylnitrobenzene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 7

Chapter 17.10, Problem 17.19P

(a)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−tert−butylnitrobenzene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−toluenesulfonic acid from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−toluenesulfonic acid from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−chlorotoluene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The synthesis of the given aromatic derivative, p−chlorotoluene from benzene is to be predicted.

Concept introduction:

Friedel-Crafts alkylation permits the synthesis of alkylated products by the reaction of arenes with alkyl chlorides in the presence of aluminium chloride. This alkylation reaction comes under the category of electrophilic aromatic substitution.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 17.1 - Prob. 17.1P Ch. 17.2 - Prob. 17.2P Ch. 17.3 - Prob. 17.3P Ch. 17.4 - Use resonance forms to show that the dipolar sigma...Ch. 17.6A - Prob. 17.5P Ch. 17.6A - Prob. 17.6P Ch. 17.6B - Propose a mechanism for the brommation of...Ch. 17.6B - Prob. 17.8P Ch. 17.6B - Prob. 17.9P Ch. 17.7 - Prob. 17.10P

Solution Summary: The author explains how Friedel-Crafts alkylation permits the synthesis of benzene products by the reaction of arenes with tertiary butyl chlorides in the presence of aluminium chlor

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Chapter 17 Solutions