Problem 1PS: Does the pH of the solution increase, decrease or stay the same when you (a) add solid ammonium... Problem 2PS: Does the pH of the solution increase, decrease, or stay the same when you (a) add solid sodium... Problem 3PS: What is the pH of a solution that consists of 0.20 M ammonia, NH3, and 0.20 M ammonium chloride,... Problem 4PS: What is the pH of 0.15 M acetic acid to which 1.56 g of sodium acetate, NaCH3CO2 has been added? Problem 5PS: What is the pH of the solution that results from adding 30.0 mL of 0.015 M KOH to 50.0 mL of 0.015 M... Problem 6PS: What is the pH of the solution that results from adding 25.0 mL of 0.12 M HCl to 25.0 mL of 0.43 M... Problem 7PS: What is the pH of the buffer solution that contains 2.2 g of NH4Cl in 250 mL of 0.12 M NH3? Is the... Problem 8PS: Lactic acid (CH3CHOHCO2H) is found in sour milk, in sauerkraut, and in muscles after activity. (Ka... Problem 9PS: What mass of sodium acetate, NaCH3CO2, must he added to 1.00 L of 0.10 M acetic acid to give a... Problem 10PS: What mass of ammonium chloride, NH4Cl, must be added to exactly 5.00 102 mL of 0.10 M NH3 solution... Problem 11PS: Calculate the pH of a solution that has an acetic acid concentration of 0.050 M and a sodium acetate... Problem 12PS: Calculate the pH of a solution that has an ammonium chloride concentration of 0.050 M and an ammonia... Problem 13PS: What must the ratio of acetic acid to acetate ion be to have a buffer with a pH value of 5.00? Problem 14PS: What must the ratio of H2PO4 to HPO42 be to have a buffer with a pH value of 7.00? Problem 15PS: A buffer is composed of formic acid and its conjugate base, the formate ion. (a) What is the pH of a... Problem 16PS: A buffer solution is composed of 1.360 g of KH2PO4 and 5.677 g of Na2HPO4. (a) What is the pH of the... Problem 17PS: Which of the following combinations would be the best to buffer the pH of a solution at... Problem 18PS: Which of the following combinations would be the best to buffer the pH of a solution at... Problem 19PS: Describe how to prepare a buffer solution from NaH2PO4 and Na2HPO4 to have a pH of 7.5. Problem 20PS: Describe how to prepare a buffer solution from NH3 and NH4Cl to have a pH of 9.5. Problem 21PS: Determine the volume (in mL) of 1.00 M NaOH that must be added to 250 mL of 0.50 M CH3CO2H to... Problem 22PS: Determine the volume (in mL) of 1.00 M HC1 that must be added to 750 mL of 0.50 M HPO42 to produce a... Problem 23PS: A buffer solution was prepared by adding 4.95 g of sodium acetate, NaCH3CO2, to 2.50 102 mL of... Problem 24PS: You dissolve 0.425 g of NaOH in 2.00 L of a buffer solution that has [H2PO4| = [HPO42] = 0.132 M.... Problem 25PS: A buffer solution is prepared by adding 0.125 mol of ammonium chloride to 5.00 102 mL of 0.500 M... Problem 26PS: What is the pH change when 20.0 mL of 0.100 M NaOH is added to 80.0 mL of a buffer solution... Problem 27PS: Phenol, C6H5OH, is a weak organic acid. Suppose 0.515 g of the compound is dissolved in enough water... Problem 28PS: Assume you dissolve 0.235 g of the weak acid benzoic acid, C6H5CO2H, in enough water to make 1.00 ... Problem 29PS: You require 36.78 mL of 0.0105 M HCl to reach the equivalence point in the titration of 25.0 mL of... Problem 30PS: A titration of 25.0 mL of a solution of the weak base aniline, C6H5NH2, requires 25.67 mL of 0.175 M... Problem 31PS: Without doing detailed calculations, sketch the curve for the titration of 30.0 mL of 0.10 M NaOH... Problem 32PS: Without doing detailed calculations, sketch the curve for the titration of 50 mL of 0.050 M... Problem 33PS: You titrate 25.0 mL of 0.10 M NH3 with 0.10 M HCl. (a) What is the pH of the NH3 solution before the... Problem 35PS: Using Figure 17.11, suggest an indicator to use in each of the following titrations: (a) The weak... Problem 36PS: Using Figure 17.11, suggest an indicator to use in each of the following titrations. (a) NaHCO3 is... Problem 37PS: Name two insoluble salts of each of the following ions. (a) Cl (b) Zn2+ (c) Fe2+ Problem 38PS Problem 39PS: Using the solubility guidelines (Figure 3.10), predict whether each of the following is insoluble or... Problem 40PS: Predict whether each of the fallowing is insoluble or soluble in water. (a) Pb(NO3)2 (b) Fe(OH)3 (c)... Problem 41PS: For each of the following insoluble salts, (1) write a balanced equation showing the equilibrium... Problem 42PS Problem 43PS: When 1.55 g of solid thallium(I) bromide is added to 1.00 L of water, the salt dissolves to a small... Problem 44PS: At 20 C, a saturated aqueous solution of silver acetate, AgCH3CO2, contains 1.0 g of the silver... Problem 45PS: When 250 mg of SrF2, strontium fluoride, is added to 1.00 L of water, the salt dissolves to a very... Problem 46PS: Calcium hydroxide, Ca(OH)2, dissolves in water to the extent of 1.78 g per liter. What is the value... Problem 47PS: You add 0.979 g of Pb(OH)2 to 1.00 L of pure water at 25 C. The pH is 9.15. Estimate the value of... Problem 48PS: You place 1.234 g of solid Ca(OH)2 in 1.00 L of pure water at 25 C. The pH of the solution is found... Problem 49PS: Estimate the solubility of silver iodide in pure water at 25 C (a) in moles per liter and (b) in... Problem 50PS: What is the molar concentration of Au+(aq) in a saturated solution of AuCl in pure water at 25 C?... Problem 51PS Problem 52PS: Estimate the solubility of lead(II) bromide (a) in moles per liter and (b) in grams per liter of... Problem 53PS: The Ksp value for radium sulfate, RaSO4, is 4.2 1011. If 25 mg of radium sulfate is placed in 1.00 ... Problem 54PS: If 55 mg of lead(II) sulfate is placed in 250 mL of pure water, does all of it dissolve? If not, how... Problem 55PS Problem 56PS Problem 57PS: Calculate the molar solubility of silver thiocyanate, AgSCN, in pure water and in water containing... Problem 58PS: Calculate the solubility of silver bromide, AgBr, in moles per liter, in pure water. Compare this... Problem 59PS: Compare the solubility, in milligrams per milliliter, of silver iodide, AgI, (a) in pure water and... Problem 60PS: What is the solubility, in milligrams per milliliter, of BaF2, (a) in pure water and (b) in water... Problem 61PS: Calculate the solubility, in moles per liter, of iron(II) hydroxide, Fe(OH)2, in a solution buffered... Problem 62PS: Calculate the solubility, in moles per liter, of calcium hydroxide, Ca(OH)2, in a solution buffered... Problem 63PS: Which insoluble compound in each pair should be more soluble in nitric acid than in pure water? (a)... Problem 64PS: Which compound in each pair is more soluble in water than is predicted by a calculation from Ksp?... Problem 65PS: You have a solution that has a lead(II) ion concentration of 0.0012 M. If enough soluble... Problem 66PS: Sodium carbonate is added to a solution in which the concentration of Ni2+ ion is 0.0024 M. Will... Problem 67PS: If the concentration of Zn2+ in 10.0 mL of water is 1.63 104 M, will zinc hydroxide, Zn(OH)2,... Problem 68PS: You have 95 mL of a solution that has a lead(II) concentration of 0.0012 M. Will PbCl2 precipitate... Problem 69PS Problem 70PS: Will a precipitate of Mg(OH)2 form when 25.0 mL of 0.010 M NaOH is combined with 75.0 mL of a 0.10 M... Problem 71PS: Zinc hydroxide is amphoteric (Section 16.10). Use equilibrium constants to show that, given... Problem 72PS: Solid silver iodide, AgI, can be dissolved by adding aqueous sodium cyanide. Calculate Knet the... Problem 73PS: What amount of ammonia (moles) must be added to dissolve 0.050 mol of AgCl suspended in 1.0 L of... Problem 74PS: Can you dissolve 15.0 mg of AuCl in 100.0 mL of water if you add 15.0 mL of 6.00 M NaCN? Problem 75PS: What is the solubility of AgCl (a) in pure water and (b) in 1.0 M NH3? Problem 76PS Problem 77GQ Problem 78GQ Problem 79GQ Problem 80GQ: Calculate the hydronium ion concentration and the pH of the solution that results when 20.0 mL of... Problem 81GQ: Calculate the hydronium ion concentration and the pH of the solution that results when 50.0 mL of... Problem 82GQ: For each of the following cases, decide whether the pH is less than 7, equal to 7, or greater than... Problem 83GQ Problem 84GQ: A sample of hard water contains about 2.0 103 M Ca2+. A soluble fluoride-containing salt such as... Problem 85GQ: What is the pH of a buffer solution prepared from 5.15 g of NH4NO3 and 0.10 L of 0.15 M NH3? What is... Problem 86GQ Problem 87GQ: Describe the effect on the pH of the following actions or explain why there is not an effect: (a)... Problem 88GQ: What volume of 0.120 M NaOH must be added to 100. mL of 0.100 M NaHC2O4 to reach a pH of 4.70? Problem 89GQ: A buffer solution is prepared by dissolving 1.50 g each of benzoic acid, C6H5CO2H, and sodium... Problem 90GQ: What volume of 0.200 M HCl must be added to 500.0 mL of 0.250 M NH3 to have a buffer with a pH of... Problem 91GQ: What is the equilibrium constant for the following reaction? AgCl(s)+I(aq)AgI(s)+Cl(aq) Does the... Problem 92GQ: Calculate the equilibrium constant for the following reaction. Zn(OH)2(s)+2CN(aq)Zn(CN)2(s)+2OH(aq)... Problem 93GQ Problem 94GQ: The solubility product constant for calcium oxalate is estimated to be 4 109. What is its... Problem 95GQ: In principle, the ions Ba2+ and Ca2+ can be separated by the difference in solubility of their... Problem 96GQ: A solution contains 0.10 M iodide ion, I, and 0.10 M carbonate ion, CO32. (a) If solid Pb(NO3)2 is... Problem 97GQ: A solution contains Ca2+ and Pb2+ ions, both at a concentration of 0.010 M. You wish to separate the... Problem 98GQ Problem 99GQ Problem 100GQ Problem 101IL: Each pair of ions below is found together in aqueous solution. Using the table of solubility product... Problem 102IL: Each pair of ions below is found together in aqueous solution. Using the table of solubility product... Problem 103IL: The cations Ba2+ and Sr2+ can be precipitated as very insoluble sulfates. (a) If you add sodium... Problem 104IL: You will often work with salts of Fe3+, Pb2+, and Al3+ in the laboratory. (All are found in nature,... Problem 105IL: Aniline hydrochloride, (C6H5NH3)Cl, is a weak acid. (Its conjugate base is the weak base aniline,... Problem 106IL: The weak base ethanolamine. HOCH2CH2NH2, can be titrated with HCl.... Problem 107IL: For the titration of 50.0 mL of 0.150 M ethylamine. C2H5NH2, with 0.100 M HCl, find the pH at each... Problem 108IL: A buffer solution with it pH of 12.00 consists of Na3PO4 and Na2HPO4. The volume of solution is... Problem 109IL: To have a buffer with a pH of 2.50, what volume of 0.150 M NaOH must be added to 100. mL of 0.230 M... Problem 110IL: What mass of Na3PO4 must be added to 80.0 mL of 0.200 M HCl to obtain a buffer with a pH of 7.75? Problem 111IL: You have a solution that contains AgNO3, Pb(NO3)2, and Cu(NO3)2. Devise a separation method that... Problem 112IL Problem 113SCQ: Suggest a method for separating a precipitate consisting of a mixture of solid CuS and solid... Problem 114SCQ Problem 115SCQ Problem 116SCQ: Two acids, each approximately 0.01 M in concentration, are titrated separately with a strong base.... Problem 117SCQ: Composition diagrams, commonly known as alpha plots, are often used to visualize the species in a... Problem 118SCQ: The composition diagram, or alpha plot, for the important acid-base system of carbonic acid, H2CO3,... Problem 119SCQ: The chemical name for aspirin is acetylsalicylic acid. It is believed that the analgesic and other... Problem 120SCQ format_list_bulleted