If you calculate a value for ∆ G ° for a reaction using the values of Δ G f ∘ in Appendix 4 and get a negative number, is it correct to say that the reaction is always spontaneous? Why or why not? Free energy changes also depend on concentration. For gases, how is G related to the pressure of the gas? What are standard pressures for gases and standard concentrations for solutes? How do you calculate ∆ G for a reaction at nonstandard conditions? The equation to determine ∆G at nonstandard conditions has Q in it: What is Q ? A reaction is spontaneous as long as ∆ G is negative; that is, reactions always proceed as long as the products have a lower free energy than the reactants. What is so special about equilibrium? Why don’t reactions move away from equilibrium?
If you calculate a value for ∆ G ° for a reaction using the values of Δ G f ∘ in Appendix 4 and get a negative number, is it correct to say that the reaction is always spontaneous? Why or why not? Free energy changes also depend on concentration. For gases, how is G related to the pressure of the gas? What are standard pressures for gases and standard concentrations for solutes? How do you calculate ∆ G for a reaction at nonstandard conditions? The equation to determine ∆G at nonstandard conditions has Q in it: What is Q ? A reaction is spontaneous as long as ∆ G is negative; that is, reactions always proceed as long as the products have a lower free energy than the reactants. What is so special about equilibrium? Why don’t reactions move away from equilibrium?
Solution Summary: The author explains that thermodynamics is associated with heat, temperature, and its relation with energy and work. It helps predict whether a process will take place or not.
If you calculate a value for ∆G° for a reaction using the values of
Δ
G
f
∘
in Appendix 4 and get a negative number, is it correct to say that the reaction is always spontaneous? Why or why not? Free energy changes also depend on concentration. For gases, how is G related to the pressure of the gas? What are standard pressures for gases and standard concentrations for solutes? How do you calculate ∆G for a reaction at nonstandard conditions? The equation to determine ∆G at nonstandard conditions has Q in it: What is Q? A reaction is spontaneous as long as ∆G is negative; that is, reactions always proceed as long as the products have a lower free energy than the reactants. What is so special about equilibrium? Why don’t reactions move away from equilibrium?
(f) SO:
Best Lewis Structure
3
e group geometry:_
shape/molecular geometry:,
(g) CF2CF2
Best Lewis Structure
polarity:
e group arrangement:_
shape/molecular geometry:
(h) (NH4)2SO4
Best Lewis Structure
polarity:
e group arrangement:
shape/molecular geometry:
polarity:
Sketch (with angles):
Sketch (with angles):
Sketch (with angles):
1.
Problem Set 3b
Chem 141
For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing
bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the
molecule is polar or non-polar (iv)
(a) SeF4
Best Lewis Structure
e group arrangement:_
shape/molecular geometry:
polarity:
(b) AsOBr3
Best Lewis Structure
e group arrangement:_
shape/molecular geometry:
polarity:
Sketch (with angles):
Sketch (with angles):
(c) SOCI
Best Lewis Structure
2
e group arrangement:
shape/molecular geometry:_
(d) PCls
Best Lewis Structure
polarity:
e group geometry:_
shape/molecular geometry:_
(e) Ba(BrO2):
Best Lewis Structure
polarity:
e group arrangement:
shape/molecular geometry:
polarity:
Sketch (with angles):
Sketch (with angles):
Sketch (with angles):
Chapter 17 Solutions
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