Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
1st Edition
ISBN: 9780134024516
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 17, Problem 49E
For each statement, indicate whether it is true or false.
a. The greater the orbital overlap in a bond, the weaker the bond
b. The greater the orbital overlap in a bond, the shorter the bond
c. To create a hybrid orbital, you could use the s orbital on one atom with a p orbital on another atom.
d. Nonbonding electron pairs cannot occupy a hybrid orbital.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Which of the following correctly describes a pi bond according to valence
bond theory?
Select one:
O A. A pi bond is formed between adjacent atoms when two p orbitals, co-
linear with the bond axis, meet "head on".
OB. A pi bond is formed when an s orbital overlaps with a hybrid orbital.
OC. A pi bond is formed between adjacent atoms when hybrid orbitals, co-
linear with the bond axis, overlap.
OD. A pi bond is formed when two adjacent, parallel p orbitals overlap
along their sides.
Which of the following correctly describes a pi bond according to valence
bond theory?
Select one:
O A. A pi bond is formed between adjacent atoms when two p orbitals, co-
linear with the bond axis, meet "head on".
O B.
A pi bond is formed when an s orbital overlaps with a hybrid orbital.
O C. A pi bond is formed between adjacent atoms when hybrid orbitals, co-
linear with the bond axis, overlap.
O D. A pi bond is formed when two adjacent, parallel p orbitals overlap
along their sides.
a. What is hybridization of carbon atom labeled "hybridization 3"
b. Sigma (σ) bond between two carbon atoms (which DON'T have additional pi bond between them) is a combination of which two atomic orbitals according to the hybridization concept?
c. Pi (π) bond between two carbon atoms is a combination of which two atomic orbitals according to the hybridization concept?
d. Sigma (σ) bond between two carbon atoms (which are connected with pi bond as well) is a combination of which two atomic orbitals according to the hybridization concept?
e. What is hybridization of oxygen atom labeled "hybridization 1"
f. What is hybridization of carbon atom labeled "hybridization 2"
Chapter 17 Solutions
Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
Ch. 17.1 - Calculate the formal charge on the indicated atom...Ch. 17.1 - The hypochlorite ion, CIO- , is the active...Ch. 17.1 - Prob. 17.2.1PECh. 17.1 - a. Triazine, C3 H3N3, is like benzene except that...Ch. 17.2 - Prob. 17.3.1PECh. 17.2 - Prob. 17.3.2PECh. 17.2 - Prob. 17.4.1PECh. 17.2 - Prob. 17.4.2PECh. 17.2 - Prob. 17.5.1PECh. 17.2 - Prob. 17.5.2PE
Ch. 17.2 - Prob. 17.6.1PECh. 17.2 - Prob. 17.6.2PECh. 17.3 - Prob. 17.7.1PECh. 17.3 -
8.103 The compound chloral hydrate, known in...Ch. 17.3 - Barium azide is 62.04% Ba and 37.96% N. Each azide...Ch. 17.3 - Acetylene (C2H2) and nitrogen (N2) both contain a...Ch. 17.3 - Prob. 17.9.1PECh. 17.3 - Prob. 17.9.2PECh. 17.4 - Prob. 17.10.1PECh. 17.4 - Prob. 17.10.2PECh. 17.4 - Prob. 17.11.1PECh. 17.4 - A new compound is made that has a C-C bond length...Ch. 17.4 - A new compound is made that has an N-N bond length...Ch. 17.4 - Prob. 17.12.2PECh. 17.5 - Prob. 17.13.1PECh. 17.5 - An ionic substance of formula MX has a lattice...Ch. 17.5 - Prob. 17.14.1PECh. 17.5 - Prob. 17.14.2PECh. 17.5 - Prob. 17.15.1PECh. 17.5 - Consider the collection of nonmetallic elements 0,...Ch. 17.6 - The substance chlorine monoxide, CIO(g), is...Ch. 17.6 -
[8.87]
a. using the electronegativities of Br...Ch. 17.6 - Prob. 17.17.1PECh. 17.6 - Although I3- is a known ion, F3- is not. a. Draw...Ch. 17 - Prob. 1DECh. 17 -
9.13
a. An AB2 molecule is linear. How...Ch. 17 - Give the electron-domain and molecular geometries...Ch. 17 - Prob. 3ECh. 17 - Prob. 4ECh. 17 - Prob. 5ECh. 17 - Prob. 6ECh. 17 - Prob. 7ECh. 17 - Prob. 8ECh. 17 - Azo dyes are organic dyes that are used for many...Ch. 17 - Prob. 10ECh. 17 - 9.1 A certain AB4, molecule has a "seesaw" shape...Ch. 17 - Prob. 12ECh. 17 - Prob. 13ECh. 17 - Prob. 14ECh. 17 - Prob. 15ECh. 17 - In the hydrocarbon a. What is the hybridization at...Ch. 17 - The drawing below shows the overlap of two hybrid...Ch. 17 - Prob. 18ECh. 17 -
9.10 The following is part of a molecular...Ch. 17 - a. Methane (CH4) and the perchlorate ion (C104-)...Ch. 17 - Prob. 21ECh. 17 - Prob. 22ECh. 17 - Prob. 23ECh. 17 - Prob. 24ECh. 17 - In which of these molecules or ions does the...Ch. 17 - Prob. 26ECh. 17 - How many nonbonding electron pairs are there in...Ch. 17 - Prob. 28ECh. 17 - Prob. 29ECh. 17 - Prob. 30ECh. 17 - Prob. 31ECh. 17 - Prob. 32ECh. 17 - Prob. 33ECh. 17 - Prob. 34ECh. 17 - Ammonia, NH3 reacts with incredibly strong bases...Ch. 17 - In which of the following AFn molecules or ions is...Ch. 17 - a. Explain why BrF4 is square planar, whereas...Ch. 17 -
9.34 Name the proper three-dimensional molecule...Ch. 17 - Prob. 39ECh. 17 - Prob. 40ECh. 17 - a. (a) Is the molecule BF3 polar or nonpolar? b....Ch. 17 - Prob. 42ECh. 17 - Predict whether each of the following molecules is...Ch. 17 - Prob. 44ECh. 17 - Prob. 45ECh. 17 - Prob. 46ECh. 17 - For each statement, irldicate whether it is true...Ch. 17 - Draw sketches illustrating the overlap between the...Ch. 17 - For each statement, indicate whether it is true or...Ch. 17 - Consider the SC12 molecule. a. What IS the...Ch. 17 - Prob. 51ECh. 17 - Prob. 52ECh. 17 - Prob. 53ECh. 17 - Prob. 54ECh. 17 - Prob. 55ECh. 17 - Prob. 56ECh. 17 - a. Draw Lewis structures for ethane (C2He),...Ch. 17 - a. Draw Lewis structures for ethane (C2He),...Ch. 17 - Prob. 59ECh. 17 - Prob. 60ECh. 17 - Prob. 61ECh. 17 - Prob. 62ECh. 17 - In the formate ion, HC02- , the carbon atom is the...Ch. 17 - Prob. 64ECh. 17 - Prob. 65ECh. 17 - Prob. 66ECh. 17 - Prob. 67ECh. 17 - a. If you combine two atomic orbitals on two...Ch. 17 - Prob. 69ECh. 17 - Indicate whether each statement is true or false....Ch. 17 - Prob. 71ECh. 17 - Prob. 72ECh. 17 - Prob. 73ECh. 17 - Prob. 74ECh. 17 - Prob. 75ECh. 17 - Prob. 76ECh. 17 - Determine the electron configurations for CN+, CN,...Ch. 17 - Prob. 78ECh. 17 - Consider the molecular orbitals of the P2...Ch. 17 - Prob. 80ECh. 17 - Consider the following XF4 ions: PF4, BrF4-,...Ch. 17 -
9.88 Consider the molecule PF4Cl....Ch. 17 - Prob. 83AECh. 17 - Fill in the blank spaces in the following chart....Ch. 17 - Prob. 85AECh. 17 - Prob. 86AECh. 17 - Prob. 87AECh. 17 - Prob. 88AECh. 17 - Prob. 89AECh. 17 - Prob. 90AECh. 17 - Prob. 91AECh. 17 - Prob. 92AECh. 17 - In ozone, 03, the two oxygen atoms on the ends Of...Ch. 17 - Butadiene, C4H6, is a planar molecule that has the...Ch. 17 - The structure of borazine, B3N3H6, is a...Ch. 17 - Prob. 96AECh. 17 - Prob. 97AECh. 17 - Prob. 98AECh. 17 - Prob. 99AECh. 17 - Prob. 100AECh. 17 - Prob. 101AECh. 17 - Consider the following AB3 molecules and ions-...Ch. 17 - Prob. 103AECh. 17 - Prob. 104AECh. 17 - Prob. 105AECh. 17 - Prob. 106AECh. 17 - Prob. 107AECh. 17 - Prob. 108AECh. 17 - Determine whether the following molecules are...Ch. 17 - Prob. 110IECh. 17 - Prob. 111IECh. 17 - Prob. 112IECh. 17 - Prob. 113IECh. 17 - Prob. 114IECh. 17 - Prob. 115IECh. 17 - Prob. 116IECh. 17 - Prob. 117IECh. 17 - Prob. 118IECh. 17 - Prob. 119IECh. 17 - Prob. 120IE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Lets look more closely at the process of hybridization. (a) What is the relationship between the number of hybrid orbitals produced and the number of atomic orbitals used to create them? (b) Do hybrid atomic orbitals form between different p orbitals without involving 5 orbitals? (c) What is the relationship between the energy of hybrid atomic orbitals and the atomic orbitals from which they are formed?arrow_forward7.59 What type of hybrid orbital is generated by combining the valence s orbital and all three valence p orbitals of an atom? How many hybrid orbitals result?arrow_forwardGive the shape that describes each hybrid orbital set: (a) sp2 (b) sp3d (c) sp (d) sp3d2arrow_forward
- Methylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is (a) How many sigma bonds are in the molecule? (b) How many pi bonds are in the molecule? (c) What is the hybridization of the carbon atom bonded to nitrogen? (d) What is the hybridization of the carbon atom bonded to oxygen? (e) What is the hybridization of the double-bonded oxygen?arrow_forwardNumerous molecules are detected in deep space. Three of them are illustrated here. (a) Are these compounds isomers? (b) Indicate the hybridization of each C atom in each molecule. (c) What is the value of the HCH angle in each of the three molecules? (d) Which of these molecules is/are polar? (e) Which molecule should have the strongest carbon-carbon bond? The strongest carbon-oxygen bond?arrow_forward7.96 Consider the hydrocarbons whose structures are shown below. Which of these molecules would be planar, meaning that all of the atoms must lie in the same plane? Explain your answer in terms of orbital hybridizations.arrow_forward
- Allene (1,2-propadicne), a gas, has the following structure: What is the hybridization at each carbon atom? What is the geometry about each carbon atom? Using valencebond theory, describe the bonding about the center carbon atom. 1,3-dichloroallene is a derivative of allene with the following structure: Is this a polar molecule? (If you have difficulty visualizing the structure of this molecule, you might build a molecular model of it.)arrow_forward28. This is the most ideal bond angle of hybrid orbitals in methane. A. 109.5° В. 120° С. 180° D. 90°0 29. If two sp? hybridized orbitals are going to overlap, what is the expected molecular geometry? A. Linear B. Tetrahedral C. Trigonal planar D. Cuboidal 30. Type of orbitals which result from destructive interference A. Piorbitals B. Sigma orbitals C. Bonding orbitals D. Antibonding orbitals 31. A triple bond is composed of: A. One pi bond and two sigma bonds B. Three pi bonds C. Three sigma bonds. D. One sigma bond and two pi bonds 32. Which hybrid orbital has the greatest "p character?" A. sp3 B. sp2 C. sp D. sptarrow_forwardAnalyze the structure of the molecule below. 1. Carbon 6 is _________________ A. sp hybridized B. sp2 hybridized C. sp3 hybridized D. sp4 hybridized E. not hybridized 2. carbon 3’s hybridized orbitals have a _________________ geometry. A. linear B. trigonal planar C. tetrahedral D. spherical E. can not tell 3. Oxygen 14 has _________________ lone pairs of electrons. A.1 B. 2 C. 3 D. 4 E. 0arrow_forward
- 3. For the given molecule, identify the hybridization for atoms labeled (a, b) and indicate the orbitals used for the bonds labeled (c,d). Orbitals used to make the Hybridization of labeled atom Geometry about the atom labeled bonds a H d b a. b. a. b. C. d.arrow_forwardWhich statement is true concerning molecular orbital (MO) theory? A. Atomic orbitals overlap to form bonds B. Atomic orbitals combine to form both bonding and anti-bonding orbitals C. Atomic orbitals through VSEPR can determine the geometric shapes of molecules D. Atomic orbitals on the same atom combine with each other to make hybrid orbitals.arrow_forward29. If two sp? hybridized orbitals are going to overlap, what is the expected molecular geometry? A. Linear B. Tetrahedral C. Trigonal planar D. Cuboidal 30. Type of orbitals which result from destructive interference A. Piorbitals B. Sigma orbitals C. Bonding orbitals D. Antibonding orbitals 31. A triple bond is composed of: A. One pi bond and two sigma bonds B. Three pi bonds C. Three sigma bonds D. One sigma bond and two pi bonds 32. Which hybrid orbital has the greatest "p character?" A. sp B. sp2 C. sp D. spt 33. Which among the following compounds has the greatest net dipole moment? A. CH F В. CHil C. CH CI D. CHarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry for Engineering StudentsChemistryISBN:9781337398909Author:Lawrence S. Brown, Tom HolmePublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Chemistry for Engineering Students
Chemistry
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY