Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
1st Edition
ISBN: 9780134024516
Author: Theodore E. Brown, H. Eugene LeMay, Bruce E. Bursten, Catherine Murphy, Patrick Woodward, Matthew E. Stoltzfus
Publisher: PEARSON
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Textbook Question
Chapter 17, Problem 2E
Give the electron-domain and molecular geometries for the following molecules and ions
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For each of the following molecules (in which the central atom is underlined),
classify it according to the AXnEm nomenclature of the VSEPR theory,
draw the 3-dimensional structure, showing all valence shell electrons of all atoms,
draw the net dipole moment vector (if one exists) on the structure diagram,
name the hybrid atomic orbitals used by the central atom for σ bonding and
name the orbitals used by the central atom for π bonding (if applicable).
Molecule or Ion
SbOCl3
ArOF4
a. AXE formula
b. 3-dimensional
structure
c. Indicate the net dipole moment vector (if any) on this diagram.
d. σ- bonding orbitals used by the central atom
e. π-bonding orbitals used by the central atom
What is a molecule with 3 single bonds and any number of lone pairs could have the following molecular geometries?
How can the VSEPR model be used to predict the hybridization of an atom in a molecule? Answer by selecting all true statements.
O The bonding orientation predicted by the VSEPR model matches the orientation predicted using hybrid orbitals.
O For a given atom in a molecule, the number of non-bonding electron domains predicted by the VSEPR model translates into
the same number of hybrid orbitals.
O The shape of the electron domains around the central atom is used to predict the hybridization of the atom.
O Once the number of electron domains has been correctly predicted from the VSEPR model, only one type of hybrid orbital
set will "match".
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Chapter 17 Solutions
Chemistry: The Central Science, Books a la Carte Edition & Solutions to Red Exercises for Chemistry & Mastering Chemistry with Pearson eText -- Access Card Package
Ch. 17.1 - Calculate the formal charge on the indicated atom...Ch. 17.1 - The hypochlorite ion, CIO- , is the active...Ch. 17.1 - Prob. 17.2.1PECh. 17.1 - a. Triazine, C3 H3N3, is like benzene except that...Ch. 17.2 - Prob. 17.3.1PECh. 17.2 - Prob. 17.3.2PECh. 17.2 - Prob. 17.4.1PECh. 17.2 - Prob. 17.4.2PECh. 17.2 - Prob. 17.5.1PECh. 17.2 - Prob. 17.5.2PE
Ch. 17.2 - Prob. 17.6.1PECh. 17.2 - Prob. 17.6.2PECh. 17.3 - Prob. 17.7.1PECh. 17.3 -
8.103 The compound chloral hydrate, known in...Ch. 17.3 - Barium azide is 62.04% Ba and 37.96% N. Each azide...Ch. 17.3 - Acetylene (C2H2) and nitrogen (N2) both contain a...Ch. 17.3 - Prob. 17.9.1PECh. 17.3 - Prob. 17.9.2PECh. 17.4 - Prob. 17.10.1PECh. 17.4 - Prob. 17.10.2PECh. 17.4 - Prob. 17.11.1PECh. 17.4 - A new compound is made that has a C-C bond length...Ch. 17.4 - A new compound is made that has an N-N bond length...Ch. 17.4 - Prob. 17.12.2PECh. 17.5 - Prob. 17.13.1PECh. 17.5 - An ionic substance of formula MX has a lattice...Ch. 17.5 - Prob. 17.14.1PECh. 17.5 - Prob. 17.14.2PECh. 17.5 - Prob. 17.15.1PECh. 17.5 - Consider the collection of nonmetallic elements 0,...Ch. 17.6 - The substance chlorine monoxide, CIO(g), is...Ch. 17.6 -
[8.87]
a. using the electronegativities of Br...Ch. 17.6 - Prob. 17.17.1PECh. 17.6 - Although I3- is a known ion, F3- is not. a. Draw...Ch. 17 - Prob. 1DECh. 17 -
9.13
a. An AB2 molecule is linear. How...Ch. 17 - Give the electron-domain and molecular geometries...Ch. 17 - Prob. 3ECh. 17 - Prob. 4ECh. 17 - Prob. 5ECh. 17 - Prob. 6ECh. 17 - Prob. 7ECh. 17 - Prob. 8ECh. 17 - Azo dyes are organic dyes that are used for many...Ch. 17 - Prob. 10ECh. 17 - 9.1 A certain AB4, molecule has a "seesaw" shape...Ch. 17 - Prob. 12ECh. 17 - Prob. 13ECh. 17 - Prob. 14ECh. 17 - Prob. 15ECh. 17 - In the hydrocarbon a. What is the hybridization at...Ch. 17 - The drawing below shows the overlap of two hybrid...Ch. 17 - Prob. 18ECh. 17 -
9.10 The following is part of a molecular...Ch. 17 - a. Methane (CH4) and the perchlorate ion (C104-)...Ch. 17 - Prob. 21ECh. 17 - Prob. 22ECh. 17 - Prob. 23ECh. 17 - Prob. 24ECh. 17 - In which of these molecules or ions does the...Ch. 17 - Prob. 26ECh. 17 - How many nonbonding electron pairs are there in...Ch. 17 - Prob. 28ECh. 17 - Prob. 29ECh. 17 - Prob. 30ECh. 17 - Prob. 31ECh. 17 - Prob. 32ECh. 17 - Prob. 33ECh. 17 - Prob. 34ECh. 17 - Ammonia, NH3 reacts with incredibly strong bases...Ch. 17 - In which of the following AFn molecules or ions is...Ch. 17 - a. Explain why BrF4 is square planar, whereas...Ch. 17 -
9.34 Name the proper three-dimensional molecule...Ch. 17 - Prob. 39ECh. 17 - Prob. 40ECh. 17 - a. (a) Is the molecule BF3 polar or nonpolar? b....Ch. 17 - Prob. 42ECh. 17 - Predict whether each of the following molecules is...Ch. 17 - Prob. 44ECh. 17 - Prob. 45ECh. 17 - Prob. 46ECh. 17 - For each statement, irldicate whether it is true...Ch. 17 - Draw sketches illustrating the overlap between the...Ch. 17 - For each statement, indicate whether it is true or...Ch. 17 - Consider the SC12 molecule. a. What IS the...Ch. 17 - Prob. 51ECh. 17 - Prob. 52ECh. 17 - Prob. 53ECh. 17 - Prob. 54ECh. 17 - Prob. 55ECh. 17 - Prob. 56ECh. 17 - a. Draw Lewis structures for ethane (C2He),...Ch. 17 - a. Draw Lewis structures for ethane (C2He),...Ch. 17 - Prob. 59ECh. 17 - Prob. 60ECh. 17 - Prob. 61ECh. 17 - Prob. 62ECh. 17 - In the formate ion, HC02- , the carbon atom is the...Ch. 17 - Prob. 64ECh. 17 - Prob. 65ECh. 17 - Prob. 66ECh. 17 - Prob. 67ECh. 17 - a. If you combine two atomic orbitals on two...Ch. 17 - Prob. 69ECh. 17 - Indicate whether each statement is true or false....Ch. 17 - Prob. 71ECh. 17 - Prob. 72ECh. 17 - Prob. 73ECh. 17 - Prob. 74ECh. 17 - Prob. 75ECh. 17 - Prob. 76ECh. 17 - Determine the electron configurations for CN+, CN,...Ch. 17 - Prob. 78ECh. 17 - Consider the molecular orbitals of the P2...Ch. 17 - Prob. 80ECh. 17 - Consider the following XF4 ions: PF4, BrF4-,...Ch. 17 -
9.88 Consider the molecule PF4Cl....Ch. 17 - Prob. 83AECh. 17 - Fill in the blank spaces in the following chart....Ch. 17 - Prob. 85AECh. 17 - Prob. 86AECh. 17 - Prob. 87AECh. 17 - Prob. 88AECh. 17 - Prob. 89AECh. 17 - Prob. 90AECh. 17 - Prob. 91AECh. 17 - Prob. 92AECh. 17 - In ozone, 03, the two oxygen atoms on the ends Of...Ch. 17 - Butadiene, C4H6, is a planar molecule that has the...Ch. 17 - The structure of borazine, B3N3H6, is a...Ch. 17 - Prob. 96AECh. 17 - Prob. 97AECh. 17 - Prob. 98AECh. 17 - Prob. 99AECh. 17 - Prob. 100AECh. 17 - Prob. 101AECh. 17 - Consider the following AB3 molecules and ions-...Ch. 17 - Prob. 103AECh. 17 - Prob. 104AECh. 17 - Prob. 105AECh. 17 - Prob. 106AECh. 17 - Prob. 107AECh. 17 - Prob. 108AECh. 17 - Determine whether the following molecules are...Ch. 17 - Prob. 110IECh. 17 - Prob. 111IECh. 17 - Prob. 112IECh. 17 - Prob. 113IECh. 17 - Prob. 114IECh. 17 - Prob. 115IECh. 17 - Prob. 116IECh. 17 - Prob. 117IECh. 17 - Prob. 118IECh. 17 - Prob. 119IECh. 17 - Prob. 120IE
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- Use MO theory to predict the bond order and the number of unpaired electrons in the super-oxide ion, , and the peroxide ion, .arrow_forwardDetermine the hybridization of the labeled atom in attached species ?arrow_forwardThe concept of valence-shell electron-pair repulsion (VSEPR) is presented in introductory organic chemistry as a way to predict molecular geometries. The idea be- hind VSEPR is that areas of electron density repel each other so that the geometry of bonds and/or lone pairs of electrons around any one atom places these areas as far apart as possible. For four areas of electron density, a tetrahedral geometry is predicted. For three areas of electron density, a trigonal planar geometry is predicted. Two areas of electron density lead to a linear geometry. VSEPR is simply a predictive tool, but in some cases, it gives an incorrect prediction. In these instances, additional insights into bonding are necessary, such as resonance. Interestingly, several important situations are critical to biochemistry where VSEPR breaks down. Two examples are shown here. :O: CH3 H,N H3N CH3 H :0: :0: Histidine The circled nitrogen atoms are predicted by VSEPR to be tetrahedral in geometry because each…arrow_forward
- The electron-domain and molecular geometries around the three central atoms of acetic acid, CH3COOH?arrow_forwardCarbon dioxide, dinitrogen monoxide, the azide ion N3-, and cynate ion OCN- have the same arrangement of atoms and the ame number of valence shell electrons. Howeer, there are significant differences in the electronic structures. What hybridization should be assigned to the central atom in each species? Are there any resonance structures associated with these molecules and/or ions? If so, descrie them. Estimate the bond lengths and bond orders of each atom in these molecules and ions.arrow_forwardThe basis of the VSEPR model of molecular bonding is A atomic orbitals of the bonding atoms must overlap for a bond to form B electron domains in the valence shell of an atom will arrange themselves so as to minimize repulsions regions of electron density in the valence shell of an atom will arrange themselves so as to maximize overlap hybrid orbitals will form as necessary to, as closely as possible, achieve spherical symmetry E regions of electron density on an atom will organize themselves so as to maximize s-characterarrow_forward
- Provide the hybridization for the following atoms in the compound below.arrow_forwardPiperine, the active ingredient in black pepper, has this Lewis structure. (a) Give the values for the indicated bond angles. (b) What is the hybridization of the nitrogen? (c) What is the hybridization of the oxygens?arrow_forwardIf you have three electron regions around a central atom, how can you have a triangular planar molecule? An angular molecule? What bond angles are predicted in each case?arrow_forward
- Aspartame is a compound that is 200 times sweeter than sugar and is used extensively (under the trade name NutraSweet) in diet soft drinks. The skeleton structure of the atoms in aspartame is (a) Complete the Lewis structure and give the number of and bonds in aspartame. (b) What is the hybridization about each carbon atom that forms a double bond with an oxygen atom? (c) What is the hybridization about each nitrogen atom?arrow_forward• explain how hybridization reconciles observed molecular shapes with the orbital overlap model.arrow_forwardWhat hybrid orbitals would be expected for the central atom in each of the following molecules or ions?arrow_forward
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