Chemistry: Structure and Properties
1st Edition
ISBN: 9780321834683
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 17, Problem 43E
Interpretation Introduction
To determine: the stronger base
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ
Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this
system:
?
rise
Under these conditions, will the pressure of N2 tend to rise or fall?
☐ x10
fall
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of N2 will tend to rise, can that be
changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of N2 will tend to fall, can that be changed to a tendency to rise
by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
☐
atm
☑
5
00.
18
Ar
i need help with the following
Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ
Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions
about this system:
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
atm
☑
18
Ar
Chapter 17 Solutions
Chemistry: Structure and Properties
Ch. 17 - Identify the conjugate base in the reaction shown...Ch. 17 - Which pair is a Bronsted-Lowry conjugate acid-base...Ch. 17 - Which acid has the largest Ka: HClO2(aq),...Ch. 17 - Consider the given acid ionization constants and...Ch. 17 - What is the OH- concentration in an aqueous...Ch. 17 - An HNO3(aq) solution has a pH of 1.75. What is the...Ch. 17 - Find the pH of a 0.350 M aqueous benzoic acid...Ch. 17 - Find the pH of a 0.155 M HClO2(aq) solution. For...Ch. 17 - 9. Calculate the percent ionization of 1.45 M...Ch. 17 - Consider two aqueous solutions of nitrous acid...
Ch. 17 - What is the [OH-] in a 0.200 M solution of...Ch. 17 - Which ion will be basic in aqueous solution? HSO4-...Ch. 17 - Which compound will form an acidic solution when...Ch. 17 - Find the pH of 0.175 M NaCN solution. For HCN,...Ch. 17 - What is the concentration of X2- in a 0.150 M...Ch. 17 - In the opening section of this chapter text, we...Ch. 17 - What are the general physical and chemical...Ch. 17 - What is a carboxylic acid? Give an example?Ch. 17 - What is the Arrhenius definition of an acid? Of a...Ch. 17 - What is a hydronium ion? Does H+ exist in solution...Ch. 17 - What is the Bronsted-Lowry definition of an acid?...Ch. 17 - Why is there more than one definition of acid-base...Ch. 17 - Describe amphoteric behavior and give an example.Ch. 17 - What is a conjugate acid-base pair? Provide an...Ch. 17 - Explain the difference between a strong acid and a...Ch. 17 - For a binary acid, H-Y, which factors affect the...Ch. 17 - Which factors affect the relative acidity of an...Ch. 17 - What are diprotic and triprotic acids? List an...Ch. 17 - Define the acid ionization constant and explain...Ch. 17 - Write an equation for the autoionization of water...Ch. 17 - What happens to the [OH-] of a solution when the...Ch. 17 - Define pH. What pH range is considered acidic?...Ch. 17 - Define pOH. What pOH range is considered acidic?...Ch. 17 - In most solutions containing a strong or weak...Ch. 17 - When calculating [H3O+] for weak acid solutions,...Ch. 17 - What is the percent ionization of an acid? Explain...Ch. 17 - In calculating [H3O+] for a mixture of a strong...Ch. 17 - Write a generic equation showing how a weak base...Ch. 17 - How can you identified if an anion will act as a...Ch. 17 - What is the relationship between the acid...Ch. 17 - What kinds of cations act as weak acids? List some...Ch. 17 - When calculating the [H3O+] for a polyprotic acid,...Ch. 17 - For a weak diprotic acid H2X, what is the...Ch. 17 - Prob. 29ECh. 17 - Prob. 30ECh. 17 - Identify each substance as an acid or a base and...Ch. 17 - Identify each substance as an acid or a base and...Ch. 17 - In each reaction, identify the Bronsted-Lowry...Ch. 17 - In each reaction, identify the Bronsted-Lowry...Ch. 17 - Write the formula for the conjugate base of each...Ch. 17 - Write the formula for the conjugate acid of each...Ch. 17 - Both H2O and H2PO4 are amphoteric. Write an...Ch. 17 - Both HCO3 and HS are amphoteric. Write an equation...Ch. 17 - Prob. 39ECh. 17 - Based on molecular structure, arrange the binary...Ch. 17 - Based on their molecular structure, pick the...Ch. 17 - Based on molecular structure, arrange the oxyacids...Ch. 17 - Prob. 43ECh. 17 - Which is a stronger base, PO43 or AsO43 ? Explain.Ch. 17 - Classify each acid as strong or weak. If the acid...Ch. 17 - Classify each acid as strong or weak. If the acid...Ch. 17 - The three diagrams represent three different...Ch. 17 - Rank the solutions in order of decreasing [H3O+] :...Ch. 17 - Calculate [OH-] in each aqueous solution at 25°C,...Ch. 17 - Calculate [H3O+] in each aqueous solution at 25°C,...Ch. 17 - Calculate the pH and pH of each solution....Ch. 17 - Calculate [H3O+] and [OH-] for each solution. pH =...Ch. 17 - Complete the table. (All solutions are at 25°C.)...Ch. 17 - Prob. 54ECh. 17 - all equilibrium constants, the value of Kw depends...Ch. 17 - The value of KWincreases with temperature. Is the...Ch. 17 - Calculate the pH of each acid solution. Explain...Ch. 17 - Find the concentration of H3O+, to the correct...Ch. 17 - For each strong acid solution, determine [H3O+],...Ch. 17 - Prob. 60ECh. 17 - What mass of HI should be present in 0.250 L of...Ch. 17 - Prob. 62ECh. 17 - What is the pH of solution in which 224 mL of...Ch. 17 - What volume of a concentrated HCl solution, which...Ch. 17 - Determine the [H3O+] and pH of a 0.100 M solution...Ch. 17 - Prob. 66ECh. 17 - Determine the pH of an HNO2 solution of each...Ch. 17 - Determine the pH of an HF solution of each...Ch. 17 - If 15.0 mL of glacial acetic acid (pure HC2H3O2)...Ch. 17 - Calculate the pH of a formic acid solution that...Ch. 17 - A 0.185 M solution of a weak acid (HA) has a pH of...Ch. 17 - Prob. 72ECh. 17 - Determine the percent ionization of a 0.125 M HCN...Ch. 17 - Determine the percent ionization of a 0.225 M...Ch. 17 - Calculate the percent ionization of an acetic acid...Ch. 17 - Calculate the percent ionization of a formic acid...Ch. 17 - A 0.148 M solution of a monoprotic acid has a...Ch. 17 - Prob. 78ECh. 17 - Prob. 79ECh. 17 - Prob. 80ECh. 17 - Find the pH of each mixture of acids. 0.115 M in...Ch. 17 - Find the pH of each mixture of acids. 0.075 M in...Ch. 17 - For each strong base solution, determine [OH-],...Ch. 17 - Prob. 84ECh. 17 - Prob. 85ECh. 17 - Prob. 86ECh. 17 - Prob. 87ECh. 17 - Prob. 88ECh. 17 - Prob. 89ECh. 17 - Prob. 90ECh. 17 - Determine the [OH-], pH, and pOH of a 0.15 ammonia...Ch. 17 - Determine the [OH-], pH, and pOH of a solution...Ch. 17 - Prob. 93ECh. 17 - Prob. 94ECh. 17 - Prob. 95ECh. 17 - Prob. 96ECh. 17 - Determine if each anion is basic or neutral. For...Ch. 17 - Determine whether each anion is basic or neutral....Ch. 17 - Prob. 99ECh. 17 - Determine the [OH-] and pH of a solution is 0.250...Ch. 17 - Determine whether each cation is acidic or...Ch. 17 - Prob. 102ECh. 17 - Determine if each salt will form a solution that...Ch. 17 - Prob. 104ECh. 17 - Prob. 105ECh. 17 - Prob. 106ECh. 17 - Prob. 107ECh. 17 - Prob. 108ECh. 17 - Prob. 109ECh. 17 - Prob. 110ECh. 17 - Prob. 111ECh. 17 - Prob. 112ECh. 17 - Write chemical equations and corresponding...Ch. 17 - Prob. 114ECh. 17 - Prob. 115ECh. 17 - Calculate the [H3O+] and pH of each polyprotic...Ch. 17 - Calculate the concentration of each species in a...Ch. 17 - Calculate the concentration of each species in a...Ch. 17 - Calculate the [H3O+] and pH of each H2S04...Ch. 17 - Consider a 0.10 M solution of a weak polyprotic...Ch. 17 - Classify each species as a Lewis acid or a Lewis...Ch. 17 - Prob. 122ECh. 17 - Prob. 123ECh. 17 - Prob. 124ECh. 17 - Prob. 125ECh. 17 - Based on these molecular views, determine whether...Ch. 17 - The binding of oxygen by hemoglobin in the blood...Ch. 17 - Carbon dioxide dissolves in water according to the...Ch. 17 - People often take Milk of Magnesia to reduce the...Ch. 17 - Lakes that have been acidified by acid rain (which...Ch. 17 - Acid rain over the Great lakes has a pH of about...Ch. 17 - White wines tend to be more acidic than red wines....Ch. 17 - Common aspirin is acetylsalicylic acid, which has...Ch. 17 - The AIDS drug zalcitabine (also known as ddC) is a...Ch. 17 - Determine the pH of each solution. 0.0100MHCIO4...Ch. 17 - Determine the pH of each solution. 0.0650M HNO3...Ch. 17 - Determine the pH of each two-component solution....Ch. 17 - Determine the pH of each two-component solution....Ch. 17 - Write net ionic equations for the reactions that...Ch. 17 - Prob. 140ECh. 17 - The pH of a 1.00 M solution of urea, a weak...Ch. 17 - Prob. 142ECh. 17 - Lactic acid is a weak acid found in milk. Its...Ch. 17 - Prob. 144ECh. 17 - A student mistakenly calculates the pH of a 1.0107...Ch. 17 - When 2.55 g of an unknown weak acid (HA) with a...Ch. 17 - Prob. 147ECh. 17 - To what volume should you dilute 1 L of a solution...Ch. 17 - HA, a weak acid, with Ka=1.0108 , also forms the...Ch. 17 - Prob. 150ECh. 17 - Prob. 151ECh. 17 - To 1.0 L of a 0.30 M solution of HCIO2 is added...Ch. 17 - A mixture of Na2CO3 and NaHCO3 has a mass of 82.2...Ch. 17 - Prob. 154ECh. 17 - Prob. 155ECh. 17 - Prob. 156ECh. 17 - Prob. 157E
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- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HCN is a weak acid. acids: 0.29 mol of NaOH is added to 1.0 L of a 1.2M HCN solution. bases: ☑ other: 0.09 mol of HCl is added to acids: 1.0 L of a solution that is bases: 0.3M in both HCN and KCN. other: 0,0,... ? 00. 18 Ar 日arrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1arrow_forward
- Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?arrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. 2.2 mol of NaOH is added to 1.0 L of a 1.4M HF solution. acids: П bases: Х other: ☐ ப acids: 0.51 mol of KOH is added to 1.0 L of a solution that is bases: 1.3M in both HF and NaF. other: ☐ 00. 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: N2O4 (g) 2NO2 (g) AG⁰ = 5.4 kJ Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of N2O4 tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO2? In other words, if you said the pressure of N2O4 will tend to rise, can that be changed to a tendency to fall by adding NO2? Similarly, if you said the pressure of N2O4 will tend to fall, can that be changed to a tendency to rise by adding NO2? If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO 2 needed to reverse it. Round your answer to 2 significant digits. yes no 0.42 atm ☑ 5 0/5 ? مله Ararrow_forward
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