Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
8th Edition
ISBN: 9781305095236
Author: Maria Cecilia D. De Mesa, Thomas D. Mcgrath
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Textbook Question
Chapter 17, Problem 41QAP
Use Table 17.1 to answer the following questions:
(a) Will chlorate ions in acidic solution oxidize Cl- to Cl2 or F- to F2?
(b) What is the product when Fe reduces Cr3+?
(c) Oxygen is reduced to water in acidic medium and to OH- in basic medium. If ClO3- (oxidized to ClO4-) is the reducing agent, in which medium will oxygen be reduced spontaneously? (
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 17 Solutions
Student Solutions Manual For Masterton/hurley's Chemistry: Principles And Reactions, 8th
Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Balance the following half-equations. Balance (a)...Ch. 17 - Prob. 3QAPCh. 17 - Balance the following reactions in acid: (a)...Ch. 17 - Write balanced equations for the following...Ch. 17 - Write balanced equations for the following...Ch. 17 - Prob. 7QAPCh. 17 - Write balanced net ionic equations for the...Ch. 17 - Write balanced net ionic equations for the...Ch. 17 - Prob. 10QAP
Ch. 17 - Write a balanced chemical equation for the overall...Ch. 17 - Write a balanced net ionic equation for the...Ch. 17 - Draw a diagram for a salt bridge cell for each of...Ch. 17 - Follow the directions in Question 13 for the...Ch. 17 - Consider a voltaic salt bridge cell represented by...Ch. 17 - Consider a salt bridge voltaic cell represented by...Ch. 17 - Consider a salt bridge cell in which the anode is...Ch. 17 - Follow the directions in Question 17 for a salt...Ch. 17 - Prob. 19QAPCh. 17 - Which species in each pair is the stronger...Ch. 17 - Using Table 17.1, arrange the following reducing...Ch. 17 - Use Table 17.1 to arrange the following oxidizing...Ch. 17 - Consider the following species. Cr3+ Hg(l) H2...Ch. 17 - Follow the directions of Question 23 for the...Ch. 17 - For the following half-reactions, answer these...Ch. 17 - For the following half-reactions, answer the...Ch. 17 - Use Table 17.1 to select (a) a reducing agent in...Ch. 17 - Use Table 17.1 to select (a) an oxidizing agent in...Ch. 17 - Calculate E° for the following voltaic cells: (a)...Ch. 17 - Calculate E° for the following voltaic cells: (a)...Ch. 17 - Using Table 17.1, calculate E° for the reaction...Ch. 17 - Using Table 17.1, calculate E° for the reaction...Ch. 17 - Calculate E° for the following cells: (a)...Ch. 17 - Calculate E° for the following cells: (a)...Ch. 17 - Suppose Ered for Ag+Ag were set equal to zero...Ch. 17 - Suppose Ered for H+H2 were taken to be 0.300 V...Ch. 17 - Which of the following reactions is/are...Ch. 17 - Which of the following reactions is(are)...Ch. 17 - Use the following half-equations to write three...Ch. 17 - Follow the directions of Question 39 for the...Ch. 17 - Use Table 17.1 to answer the following questions:...Ch. 17 - Use Table 17.1 to answer the following questions....Ch. 17 - Write the equation for the reaction, if any, that...Ch. 17 - Write the equation for the reaction, if any, that...Ch. 17 - Prob. 45QAPCh. 17 - Prob. 46QAPCh. 17 - Use Table 17.1 to predict what reaction, if any,...Ch. 17 - Use Table 17.1 to predict what reaction, if any,...Ch. 17 - Consider a cell reaction at 25°C where n=2 . Fill...Ch. 17 - Consider a cell reaction at 25°C where n=4 . Fill...Ch. 17 - For a certain cell, G=25.0 kJ. Calculate E° if n...Ch. 17 - For a certain cell, E=1.08 V. Calculate G° if n is...Ch. 17 - Calculate E°, G°, and K at 25°C for the reaction...Ch. 17 - Calculate E°, G°, and K at 25°C for the reaction...Ch. 17 - Calculate G° at 25°C for each of the reactions...Ch. 17 - Calculate G° at 25°C for each of the reactions...Ch. 17 - Calculate K at 25°C for each of the reactions...Ch. 17 - Calculate K at 25°C for each of the reactions...Ch. 17 - Prob. 59QAPCh. 17 - Use Table 17.1 to find Kffor AuCl4- (aq) at 25°C.Ch. 17 - Prob. 61QAPCh. 17 - What is E° at 25°C for the following reaction?...Ch. 17 - Consider a voltaic cell at 25°C in which the...Ch. 17 - Consider a voltaic cell at 25°C in which the...Ch. 17 - Consider a voltaic cell in which the following...Ch. 17 - Consider a voltaic cell in which the following...Ch. 17 - Calculate the voltages of the following cells at...Ch. 17 - Calculate the voltages of the following cells at...Ch. 17 - Consider the reaction...Ch. 17 - Consider the reaction at 25°C:...Ch. 17 - Complete the following cell notation....Ch. 17 - Complete the following cell notation....Ch. 17 - Consider the reaction below at 25°C:...Ch. 17 - Consider the reaction low at 25°C:...Ch. 17 - Consider a cell in which the reaction is...Ch. 17 - Consider a cell in which the reaction is...Ch. 17 - An electrolytic cell produces aluminum from Al2O3...Ch. 17 - Prob. 78QAPCh. 17 - A solution containing a metal ion (M2+(aq)) is...Ch. 17 - A solution containing a metal ion (M2+(aq)) is...Ch. 17 - A baby's spoon with an area of 6.25 cm2 is plated...Ch. 17 - A metallurgist wants to gold-plate an object with...Ch. 17 - A lead storage battery delivers a current of 6.00...Ch. 17 - Calcium metal can be obtained by the direct...Ch. 17 - Given the following data:...Ch. 17 - In a nickel-cadmium battery (Nicad), cadmium is...Ch. 17 - Hydrogen gas is produced when water is...Ch. 17 - Consider the electrolysis of NiCl2 to Ni(s) and...Ch. 17 - An electrolysis experiment is performed to...Ch. 17 - Prob. 90QAPCh. 17 - Prob. 91QAPCh. 17 - Prob. 92QAPCh. 17 - Atomic masses can be determined by electrolysis....Ch. 17 - Consider the following reaction at 25°C:...Ch. 17 - Given the standard reduction potential for...Ch. 17 - Choose the figure that best represents the results...Ch. 17 - For the cell: Cr|Cr3+Co2+|Co E° is 0.46 V. The...Ch. 17 - Which of the changes below will increase the...Ch. 17 - The standard potential for the reduction of AgSCN...Ch. 17 - Consider the following standard reduction...Ch. 17 - Use Table 17.1 to answer the following questions....Ch. 17 - Consider three metals, X, Y, and Z, and their...Ch. 17 - An alloy made up of tin and copper is prepared by...Ch. 17 - In a fully charged lead storage battery, the...Ch. 17 - Consider a voltaic cell in which the following...Ch. 17 - In biological systems, acetate ion is converted to...Ch. 17 - Consider the cell Pt|H2|H+H+|H2|Pt In the anode...Ch. 17 - Prob. 108QAPCh. 17 - Prob. 109QAP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
- Part V. Choose which isomer would give the 1H-NMR spectrum below. Justify your reasoning by assigning important signals to the Corresponding protons of the correct molecule. A D on of of of H H 88 2 90 7.8 7.6 7.4 80 5 6 [ppm] 7.2 6.8 6.6 6.4 ō [ppm]arrow_forwardShow work with explanation. don't give Ai generated solutionarrow_forwardQ7. a. Draw the line-bond structure of the major product for the following reaction, if a reaction occurs, assume monohalogenation. b. Calculate the product ratios using the following information (hint: use the number of hydrogens in each category present to calculate the ratios). Chlorination: 1° Reactivity=1 2° Reactivity=4 Heat + Cl2 3° Reactivity=5arrow_forward
- Please correct answer and don't use hand rating and don't use Ai solutionarrow_forwardQ10: Alkane halogenation a. Give the name and structures of the five isomeric hexanes. Page 4 of 5 Chem 0310 Organic Chemistry 1 Recitations b. For each isomer, give all the free radical monochlorination and monobromination products that are structurally isomeric.arrow_forwardQ9. The insecticide DDT (in the box below) is useful in controlling mosquito populations and has low toxicity to humans, but is dangerous to birds and fish. Hoping to alleviate the dangers, little Johnny Whizbang, an aspiring chemist, proposes a new version of DDT ("Bromo-DDT") and shows his synthesis to his boss. Will Johnny Whizbang's synthesis work? Or will he be fired? Assume there is an excess of bromine and polybrominated products can be separated. Explain why. CH3 Br2, light CBR3 ok-ok Br Br Br Br CI "Bromo-DDT" CCl 3 DDT (dichlorodiphenyltrichloroethane) CIarrow_forward
- Differentiate the terms Monotectic, Eutectic, Eutectoid, Peritectic, Peritectoid.arrow_forwardQ5. Predict the organic product(s) for the following transformations. If no reaction will take place (or the reaction is not synthetically useful), write "N.R.". Determine what type of transition state is present for each reaction (think Hammond Postulate). I Br₂ CH3 F2, light CH3 Heat CH3 F₂ Heat Br2, light 12, light CH3 Cl2, lightarrow_forwarda. For the following indicated bonds, rank them in order of decreasing AH° for homolytic cleavage. Based on your answer, which bond would be most likely to break homolytically? (a) (c) H3C CH3 .CH3 CH3 CH3 (b) Page 1 of 5 Chem 0310 Organic Chemistry 1 Recitations b. Draw all the possible radical products for 2-methylbutane, and determine which bond is most likely to be broken.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Electrolysis; Author: Tyler DeWitt;https://www.youtube.com/watch?v=dRtSjJCKkIo;License: Standard YouTube License, CC-BY