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Chapter 17, Problem 40E

Consider the evaporation of methanol at 25.0 °C

CH 3 OH l CH 3 OH g

a Find Δ G at 25.0 °C
b Find Δ G at 25.0 °C under these nonstandard conditions:

i. PCH3OH = 150.0 mmHg
ii. PCH3OH = 100.0 mmHg
iii. PCH3OH = 10.0 mmHg
c. Explain why methanol spontaneously evaporates in open air at 25.0 °C.

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For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
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Chapter 17 Solutions

Principles of Chemistry: A Molecular Approach Plus Mastering Chemistry with eText -- Access Card Package (3rd Edition) (New Chemistry Titles from Niva Tro)

Ch. 17 - Prob. 17.9PCh. 17 - Prob. 17.10PCh. 17 - Prob. 1SAQCh. 17 - Prob. 2SAQCh. 17 - Prob. 3SAQCh. 17 - Prob. 4SAQCh. 17 - Prob. 5SAQCh. 17 - Prob. 6SAQCh. 17 - Prob. 7SAQCh. 17 - Prob. 8SAQCh. 17 - Prob. 9SAQCh. 17 - Prob. 10SAQCh. 17 - Prob. 11SAQCh. 17 - Q12. Which distribution of six particles into...Ch. 17 - Prob. 13SAQCh. 17 - Prob. 14SAQCh. 17 - Prob. 15SAQCh. 17 - Prob. 1ECh. 17 - Which processes are nonspontaneous? Are the...Ch. 17 - Prob. 3ECh. 17 - Prob. 4ECh. 17 - Prob. 5ECh. 17 - Prob. 6ECh. 17 - Prob. 7ECh. 17 - Prob. 8ECh. 17 - Prob. 9ECh. 17 - Prob. 10ECh. 17 - Prob. 11ECh. 17 - Prob. 12ECh. 17 - Prob. 13ECh. 17 - Prob. 14ECh. 17 - Prob. 15ECh. 17 - Prob. 16ECh. 17 - Fill in the blanks in the table. Both H and S...Ch. 17 - Prob. 18ECh. 17 - Prob. 19ECh. 17 - Prob. 20ECh. 17 - Prob. 21ECh. 17 - Prob. 22ECh. 17 - Prob. 23ECh. 17 - Prob. 24ECh. 17 - Prob. 25ECh. 17 - Prob. 26ECh. 17 - Prob. 27ECh. 17 - Prob. 28ECh. 17 - Prob. 29ECh. 17 - Prob. 30ECh. 17 - 31. For each reaction, calculate ,and at 25 °C and...Ch. 17 - Prob. 32ECh. 17 - Prob. 33ECh. 17 - Use standard free energies of formation to...Ch. 17 - Consider the reaction. 2NOg+O2g2NO2g Estimate G...Ch. 17 - Prob. 36ECh. 17 - Prob. 37ECh. 17 - Prob. 38ECh. 17 - Prob. 39ECh. 17 - Consider the evaporation of methanol at 25.0 °C...Ch. 17 - Consider the reaction. CH3OHgCOg+2H2g Calculate G...Ch. 17 - Consider the reaction. CO2g+CCl4g2COCl2g Calculate...Ch. 17 - Prob. 43ECh. 17 - Prob. 44ECh. 17 - Prob. 45ECh. 17 - Prob. 46ECh. 17 - Prob. 47ECh. 17 - 48. Estamate the value of the equilibrium constant...Ch. 17 - 49. Predict the sign of in each process. a. water...Ch. 17 - Prob. 50ECh. 17 - Prob. 51ECh. 17 - Prob. 52ECh. 17 - Prob. 53ECh. 17 - Prob. 54ECh. 17 - Prob. 55ECh. 17 - 56. Consider this reaction occurring at 298...Ch. 17 - Prob. 57ECh. 17 - The standard tree energy charge for the hydrolysis...Ch. 17 - Prob. 59ECh. 17 - Prob. 60ECh. 17 - Prob. 61ECh. 17 - Prob. 62ECh. 17 - The hydrolys s of ATP, shown in Problem 57, is...Ch. 17 - Prob. 64ECh. 17 - Prob. 65ECh. 17 - Prob. 66ECh. 17 - Prob. 67ECh. 17 - Prob. 68ECh. 17 - Prob. 69ECh. 17 - Prob. 70ECh. 17 - Prob. 71ECh. 17 - Prob. 72ECh. 17 - Prob. 73ECh. 17 - Prob. 74ECh. 17 - Prob. 75ECh. 17 - Prob. 76ECh. 17 - Prob. 77E
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