The stronger acid among the given pairs is to be identified. Concept introduction: The strength of an acid depends on delocalization of negative charge by electron withdrawing effect, that is, more the delocalization of charge in the conjugate base, more stable is the anion, and thus, stronger the acid becomes.

Question

3. Titanium(III) chloride can be used to catalyze the polymerization of ethylene. It is prepared by hydrogen reduction of Titanium(IV) chloride. Reaction of hydrogen gas with titanium(IV) chloride gas produces solid titanium(III) chloride and hydrogen chloride gas. (a) Write a BALANCED chemical reaction for the preparation of titanium(III) chloride (b) A 250 L reaction vessel at 325°C is filled with hydrogen gas to a pressure of 1.3 atm. Titanium(IV) chloride is then added to bring the total pressure to 3.00 atm. How many grams of titanium(III) chloride will be produced after completion of the reaction? (c) What will be the pressure of the resulting hydrogen chloride gas that is also produced?

Answer 1

Question

Chapter 17, Problem 2PP

Interpretation Introduction

Interpretation:

The stronger acid among the given pairs is to be identified.

Concept introduction:

The strength of an acid depends on delocalization of negative charge by electron withdrawing effect, that is, more the delocalization of charge in the conjugate base, more stable is the anion, and thus, stronger the acid becomes.

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