The factors that account for the greater acidity of amides in comparison to amines and greater acidity of imides in comparison to amides are to be discussed. Concept introduction: The strength of acid of acyl group depends on delocalization of negative charge by electron withdrawing effect. More is the delocalization of charge in the conjugate base, more stable is the anion and thus, stronger is the acid.

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Answer 1

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Chapter 17, Problem 20P

Interpretation Introduction

Interpretation:

The factors that account for the greater acidity of amides in comparison to amines and greater acidity of imides in comparison to amides are to be discussed.

Concept introduction:

The strength of acid of acyl group depends on delocalization of negative charge by electron withdrawing effect. More is the delocalization of charge in the conjugate base, more stable is the anion and thus, stronger is the acid.

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Answer 2

Question

Chapter 17, Problem 20P

Interpretation Introduction

Interpretation:

The factors that account for the greater acidity of amides in comparison to amines and greater acidity of imides in comparison to amides are to be discussed.

Concept introduction:

The strength of acid of acyl group depends on delocalization of negative charge by electron withdrawing effect. More is the delocalization of charge in the conjugate base, more stable is the anion and thus, stronger is the acid.

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Answer 3

Question

Chapter 17, Problem 20P

Interpretation Introduction

Interpretation:

The factors that account for the greater acidity of amides in comparison to amines and greater acidity of imides in comparison to amides are to be discussed.

Concept introduction:

The strength of acid of acyl group depends on delocalization of negative charge by electron withdrawing effect. More is the delocalization of charge in the conjugate base, more stable is the anion and thus, stronger is the acid.

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Answer 4

Question

Chapter 17, Problem 20P

Interpretation Introduction

Interpretation:

The factors that account for the greater acidity of amides in comparison to amines and greater acidity of imides in comparison to amides are to be discussed.

Concept introduction:

The strength of acid of acyl group depends on delocalization of negative charge by electron withdrawing effect. More is the delocalization of charge in the conjugate base, more stable is the anion and thus, stronger is the acid.

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Answer 5

Chapter 17, Problem 20P

Interpretation Introduction

Interpretation:

The factors that account for the greater acidity of amides in comparison to amines and greater acidity of imides in comparison to amides are to be discussed.

Concept introduction:

The strength of acid of acyl group depends on delocalization of negative charge by electron withdrawing effect. More is the delocalization of charge in the conjugate base, more stable is the anion and thus, stronger is the acid.

Answer 6

Chapter 17, Problem 20P

Interpretation Introduction

Interpretation:

The factors that account for the greater acidity of amides in comparison to amines and greater acidity of imides in comparison to amides are to be discussed.

Concept introduction:

The strength of acid of acyl group depends on delocalization of negative charge by electron withdrawing effect. More is the delocalization of charge in the conjugate base, more stable is the anion and thus, stronger is the acid.

Answer 7

Chapter 17, Problem 20P

Interpretation Introduction

Interpretation:

The factors that account for the greater acidity of amides in comparison to amines and greater acidity of imides in comparison to amides are to be discussed.

Concept introduction:

The strength of acid of acyl group depends on delocalization of negative charge by electron withdrawing effect. More is the delocalization of charge in the conjugate base, more stable is the anion and thus, stronger is the acid.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 17 - Practice Problem 17.1 Give an IUPAC systematic...Ch. 17 - Prob. 2PP Ch. 17 - Practice Problem 17.3 Write structural formulas...Ch. 17 - Practice Problem 17.4 Show how each of the...Ch. 17 - Practice Problem 17.5 Show how you could prepare...Ch. 17 - Practice Problem 17.6 (a) Which of the carboxylic...Ch. 17 - Prob. 7PP Ch. 17 - Prob. 8PP Ch. 17 - Practice Problem 17.9 Esters can also be...Ch. 17 - Prob. 10PP

Solution Summary: The author analyzes the factors that account for the greater acidity of amides in comparison to amines, and the strength of imides.

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Chapter 17 Solutions