For the following half-reactions, answer these questions. Ce 4 + ( a q ) + e − → Ce 3 + ( a q ) E ° = + 1.61 V Ag + ( a q ) + e − → Ag ( s ) E ° = + 0.80 V Hg 2 2 + ( a q ) + 2 e − → 2 Hg ( l ) E ° = + 0.80 V Sn 2 + ( a q ) + 2 e − → Sn ( s ) E ° = − 0.14 V Ni 2 + ( a q ) + 2 e − → Ni ( s ) E ° = − 0.24 V Al 3 + ( a q ) + 3 e − → Al ( s ) E ° = − 1.68 V (a) Which is the weakest oxidizing agent? (b) Which is the strongest oxidizing agent? (c) Which is the strongest reducing agent? (d) Which is the weakest reducing agent? (e) Will Sn( s ) reduce Ag + ( aq ) to Ag( s )? (f) Will Hg( l ) reduce Sn 2 + ( aq ) to Sn( s )? (g) Which ion( s ) can be reduced by Sn( s )? (h) Which metal( s ) can be oxidized by Ag + ( aq )?
For the following half-reactions, answer these questions. Ce 4 + ( a q ) + e − → Ce 3 + ( a q ) E ° = + 1.61 V Ag + ( a q ) + e − → Ag ( s ) E ° = + 0.80 V Hg 2 2 + ( a q ) + 2 e − → 2 Hg ( l ) E ° = + 0.80 V Sn 2 + ( a q ) + 2 e − → Sn ( s ) E ° = − 0.14 V Ni 2 + ( a q ) + 2 e − → Ni ( s ) E ° = − 0.24 V Al 3 + ( a q ) + 3 e − → Al ( s ) E ° = − 1.68 V (a) Which is the weakest oxidizing agent? (b) Which is the strongest oxidizing agent? (c) Which is the strongest reducing agent? (d) Which is the weakest reducing agent? (e) Will Sn( s ) reduce Ag + ( aq ) to Ag( s )? (f) Will Hg( l ) reduce Sn 2 + ( aq ) to Sn( s )? (g) Which ion( s ) can be reduced by Sn( s )? (h) Which metal( s ) can be oxidized by Ag + ( aq )?
Solution Summary: The author explains that the weakest oxidizing agent needs to be identified by comparing the standard reduction potential of different half reactions.
For the following half-reactions, answer these questions.
Ce
4
+
(
a
q
)
+
e
−
→
Ce
3
+
(
a
q
)
E
°
=
+
1.61
V
Ag
+
(
a
q
)
+
e
−
→
Ag
(
s
)
E
°
=
+
0.80
V
Hg
2
2
+
(
a
q
)
+
2
e
−
→
2
Hg
(
l
)
E
°
=
+
0.80
V
Sn
2
+
(
a
q
)
+
2
e
−
→
Sn
(
s
)
E
°
=
−
0.14
V
Ni
2
+
(
a
q
)
+
2
e
−
→
Ni
(
s
)
E
°
=
−
0.24
V
Al
3
+
(
a
q
)
+
3
e
−
→
Al
(
s
)
E
°
=
−
1.68
V
(a) Which is the weakest oxidizing agent? (b) Which is the strongest oxidizing agent? (c) Which is the strongest reducing agent? (d) Which is the weakest reducing agent? (e) Will Sn(s) reduce Ag+(aq) to Ag(s)? (f) Will Hg(l) reduce Sn2+(aq) to Sn(s)? (g) Which ion(s) can be reduced by Sn(s)? (h) Which metal(s) can be oxidized by Ag+(aq)?
1) The isoamyl acetate report requires eight paragraphs - four for comparison of isoamyl alcohol and isoamyl acetate (one paragraph each devoted to MS, HNMR, CNMR and IR) and four for comparison of acetic acid and isoamyl acetate ((one paragraph each devoted to MS, HNMR, CNMR and IR.
2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too.
3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of…
№3
Fill in the below boxes.
HN
1. LAH
2. H3O+
NH2
For the photochemical halogenation reaction below, draw both propagation steps and include the mechanism arrows for each step.
H
CH
ot
CH3
CI-CI
MM
hv
of
CH
H-CI
CH3
2nd attempt
See Periodic Table See Hint
Draw only radical electrons; do not add lone pair electrons. Note that arrows cannot meet in "space," and must end at either bonds or at
atoms.
1
i Add the missing curved arrow notation to this propagation step.
20
H
ن
S
F
P
H
CI
Br
品
Chapter 17 Solutions
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell