ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
6th Edition
ISBN: 9781266633973
Author: SMITH
Publisher: MCG
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Chapter 1.7, Problem 18P
Interpretation Introduction

(a)

Interpretation: The geometry around all second-row atoms in CH3COCH3 is to be predicted with the help of its given Lewis structure.

Concept introduction: The geometry and hybridisation of an atom is determined by the number of groups around it. If the number of groups attached to an atom is 2, then the geometry will be linear. If the number of groups attached to an atom is 3, then the geometry will be trigonal planar. If the number of groups attached to an atom is 4, then the geometry will be tetrahedral.

Interpretation Introduction

(b)

Interpretation: The geometry around all second-row atoms in CH3OCH3 is to be predicted with the help of its given Lewis structure.

Concept introduction: The geometry and hybridisation of an atom is determined by the number of group around it. If the number of groups attached to an atom is 2, then the geometry will be linear. If the number of groups attached to an atom is 3, then the geometry will be trigonal planar. If the number of groups attached to an atom is 4, then the geometry will be tetrahedral.

Interpretation Introduction

(c)

Interpretation: The geometry around all second-row atoms in NH2 is to be predicted with the help of its given Lewis structure.

Concept introduction: The geometry and hybridisation of an atom is determined by the number of group around it. If the number of groups attached to an atom is 2, then the geometry will be linear. If the number of groups attached to an atom is 3, then the geometry will be trigonal planar. If the number of groups attached to an atom is 4, then the geometry will be tetrahedral.

Interpretation Introduction

(d)

Interpretation: The geometry around all second-row atoms in CH3CN is to be predicted with the help of its given Lewis structure.

Concept introduction: The geometry and hybridisation of an atom is determined by the number of group around it. If the number of groups attached to an atom is 2, then the geometry will be linear. If the number of groups attached to an atom is 3, then the geometry will be trigonal planar. If the number of groups attached to an atom is 4, then the geometry will be tetrahedral.

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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to glucose, C6H12O6, and fructose C6H12O6, in acidic solution: C12H22O11 + H2O → C6H12O6 + C6H12O6 [sucrose]/mol dm³ t/min 0 0.316 14 0.300 39 0.274 60 0.256 80 0.238 110 0.211 (i) Graphically prove the order of the reaction and determine the rate constant of the reaction. (ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent (b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous solution was examined. The adsorption was modelled using a modified Langmuir isotherm, yielding the following values of Kat pH = 6.5: (ii) T/K 10-10 K 280 2.505 295 1.819 310 1.364 325 1.050 Determine the enthalpy of adsorption, AadsHⓇ. If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above conditions, determine Aads Gº.
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